Between 1984 and 1993, MgCl2 brine was used to suppress dust on unpaved roads at a radioactive waste subsurface disposal area. Because Cl might enhance corrosion of buried metals in the waste, we investigated the distribution and fate of Cl in the vadose zone using pore water samples collected from suction lysimeters and soluble salt concentrations extracted from sediment samples. The Cl/Br mass ratio and the total dissolved Cl concentration of pore water show that brine contamination occurs primarily within 13 m of treated roads, but can extend as much as 30 m laterally in near-surface sedimentary deposits. Within the deep vadose zone, which consists of interlayered basalt lava flows and sedimentary interbeds, brine has moved up to 110 m laterally. This lateral migration suggests formation of perched water and horizontal transport during periods of high recharge. In a few locations, brine migrated to depths of 67 m within 3 to 5 yr. Elevated Cl concentrations were found to depths of 2 m in roadbed material. In drainage ditches along roads, where runoff accumulates and recharge of surface water is high, Cl was flushed from the sediments in 3 to 4 yr. In areas of lower recharge, Cl remained in the sediments after 5 yr. Vertical brine movement is directly related to surface recharge through sediments. The distribution of Cl in pore water and sediments is consistent with estimates of vadose zone residence times and spatial distribution of surface water recharge from other investigations at the subsurface disposal area.

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