A study of carbon and oxygen isotope ratios in fine-grained sedimentary dolomite in the Barney Creek Formation of the McArthur basin demonstrates the presence of an extensive isotope halo surrounding the giant stratiform HYC Zn-Pb-Ag deposit. Dolomite within the halo shows an 18O-enriched and 13C-depleted isotope signature (δ18O = 23 to 26‰ SMOW, δ13C = –2 to –3.5‰ PDB), relative to normal Proterozoic sedimentary dolomite beyond the halo (δ18O = 20–23‰ and δ13C = 0 to –2‰). The C-O isotope halo within the dolomitic siltstones extends at least 15 km southwest of the HYC deposit and approximately coincides with a previously defined lithogeochemical halo of elevated Fe, Mn, Zn, Pb, and Tl. Dolomitic siltstone lamellae within the stratiform Zn-Pb-Ag ores at HYC exhibit an isotopic range similar to that of the halo dolomites, suggesting that the ore and halo equilibrated with the same hydrothermal fluid.
Modeling of isotopic exchange accompanying fluid-rock
interaction suggests that the halo dolomites equilibrated with
low-temperature fluids (50°–120°C),
which were enriched in 18O (δ18O
= 5 ± 5‰)
but with an average crustal carbon isotope signature (δ13C
= –6 ±
preferred interpretation is that the oxygen and carbon isotope halo at HYC
is related to the development of an extensive brine pool. This pool was
deepest in the vicinity of the HYC deposit adjacent to the Emu fault, and it
became shallower to the southwest away from the fault. Using the carbon
isotope fractionation equation between dolomite and HC
Based on our work at HYC and Lady Loretta, strata-bound 18O-enriched carbonate lithogeochemical halos may be a characteristic of the Proterozoic stratiform Zn-Pb-Ag deposits of northern Australia. These halos are more extensive than the narrow 18O-depletion halos recorded in dolomites surrounding skarn, Mississippi Valley-type and Irish-style Zn-Pb deposits. This fundamental difference in the isotopic halo characteristics of these groups of zinc deposits is probably related to the low-temperature, synsedimentary brine pool origin of the North Australian SEDEX deposits in contrast to the various replacement and open space fill origins of skarn, Mississippi Valley-type, and Irish-style deposits.