The problem of predicting the change in seismic velocities (P-wave and S-wave) upon the change in pore-fill material properties is commonly known as substitution. For isotropic rocks, P- and S-wave velocities are fundamentally linked to the effective P-wave and shear moduli. The change in the S-wave velocity or shear modulus upon fluid substitution can be predicted with Gassmann’s equations starting only with the initial S-wave velocity. However, predicting changes in P-wave velocity or the P-wave modulus requires knowledge of the initial P- and S-wave velocities. We initiated a rigorous derivation of the P-wave modulus for fluid and solid substitution in monomineralic isotropic rocks for cases in which an estimate of the S-wave velocity or shear modulus is not available. For the general case of solid substitution, the exact equation for the P-wave modulus depends on parameters that are usually unknown. However, for fluid substitution, fewer parameters are required. As Poisson’s ratio increases for the mineral in the rock frame, the dependence of exact substitution on these unknown parameters decreases. As a result, in the absence of shear velocity, P-wave modulus fluid substitution can, for example, be performed with higher confidence for rocks with a calcite or dolomite frame than it can for rocks with quartz frame. We evaluated a recipe for applying the new P-wave modulus fluid substitution. This improves on existing work and is recommended for practice.

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