The Northwest Hawaiian Ridge is a classic example of a large igneous province. The morphology and geology of the ridge is poorly characterized, although it constitutes the longest segment (~47%) of the Hawaiian-Emperor Chain. Here we present a new bathymetric compilation, petrographic and X-ray fluorescence (XRF) data for lavas from 12 volcanoes along the Northwest Hawaiian Ridge, and review literature data for the age and isotopic variation of the ridge. The bathymetric compilation revealed that the Northwest Hawaiian Ridge consists of at least 51 volcanoes. The 45 new XRF analyses show that the Northwest Hawaiian Ridge contains tholeiitic and alkalic lavas with compositions typical of lavas from the Hawaiian Islands. The absolute ages and duration of volcanism of individual Northwest Hawaiian Ridge volcanoes are poorly known, with modern 40 Ar/ 39 Ar ages for only 10 volcanoes, mostly near the bend in the chain. We infer the initiation age of the Hawaiian-Emperor Bend to be ca. 49–48 Ma, younger than the age for the onset of island arc volcanism in the western Pacific (52–51 Ma). Thus, the kink in the Hawaiian-Emperor Chain and the onset of arc volcanism were not synchronous. Isotopic data are sparse for the Northwest Hawaiian Ridge, especially for Pb and Hf. Two transitional lavas from just south of the bend have Loa trend type Pb and Sr isotopic ratios. Otherwise, the available chemistry for Northwest Hawaiian Ridge lavas indicates Kea-trend source compositions. The dramatic increase in melt flux along the Hawaiian Ridge (~300%) may be related to changes in melting conditions, source fertility, or plate stresses.

We report new 40 Ar/ 39 Ar ages on submarine lavas from the Azores Plateau that yield ages of 6–4.9 Ma and 1.5 Ma to Holocene. An additional sample from the eastern plateau gives an age of 39 Ma. Thus, at least two, possibly even three eruptive phases occurred in the past 39 m.y. The lava compositions range from slightly incompatible trace element–enriched tholeiites to highly enriched alkali basalts similar to those erupted on the Azores islands. The less enriched tholeiitic lavas occur in the westernmost plateau and formed by relatively high degrees of partial melting. The highly enriched alkali basalts appear to be restricted to local volcanic structures, implying different phases of intraplate volcanism that are possibly related to the jump of the ultraslow-spreading Terceira Rift within the Azores Plateau. The abundance and widespread spatial distribution of volcanism with ages of 6–4.9 Ma in subaerial and submarine lavas implies the presence of a thermal or chemical melting anomaly and a period of enhanced volcanism that led to tholeiitic volcanism following, and being followed by, alkali-basaltic volcanism. The small-scale (Sr-)Nd-Pb isotopic heterogeneity of the Azores plume source implies limited mixing in the mantle, in contrast to observations made on other plume-related settings such as the Galapagos. We suggest that the Azores Plateau initially formed from interaction between geochemically and thermally anomalous mantle, possibly a small mantle plume, arriving underneath the lithosphere, and the local plate tectonics, i.e., the Terceira Rift axis, provided ascent paths for the generated magmas.

The Shatsky Rise is an oceanic plateau consisting of three main massifs that were constructed in the Pacific Ocean by intense volcanism during the Late Jurassic to Early Cretaceous. In order to explore the sources of this oceanic plateau, we present noble gas compositions from fresh quenched glasses cored by ocean drilling at Integrated Ocean Drilling Program Site U1347 on the Tamu Massif and Site U1350 on the Ori Massif. The studied glasses are normal-type basalts, the most abundant of four types of basalts defined by trace element compositions. Possible disturbances of noble gas compositions by posteruption radiogenic ingrowth in aged glasses are assessed by extraction of gases from glass vesicles by stepwise crushing. The 3 He/ 4 He ratios in glasses from Site U1347 are lower than atmospheric 3 He/ 4 He, presumably owing to magma degassing coupled with radiogenic ingrowth of 4 He. In contrast, glasses from Site U1350 exhibit a limited range of 3 He/ 4 He (5.5–5.9 Ra). Uniform 3 He/ 4 He cannot be achieved if gases in glass vesicles have been affected by secondary contamination or posteruption radiogenic ingrowth. Therefore, the uniform 3 He/ 4 He in the normal-type basalts from Site U1350 is ascribed to their source characteristics. Relatively low 3 He/ 4 He among oceanic basalts suggests the involvement of recycled slab material in the source of the normal-type basalts. However, the depleted radiogenic isotope signatures are inconsistent with recycled slab being a distinct melting component. Instead, we propose that the normal-type basalts of the Shatsky Rise were sourced from a domain where subducted fertile material is dispersed in the mantle.

Oceanic plateaus are formed by a large volume of basaltic rocks on top of the oceanic lithosphere. Alteration of these basalt lava piles leads to significant chemical element exchanges between mantle and oceans that can strongly influence chemical budget. Here we report boron (B), chlorine (Cl), and other element concentrations in basalt samples from the Shatsky Rise to define alteration processes and to estimate the significance of oceanic plateaus in storing these elements. Sampling includes 121 basaltic lavas and 92 fresh glasses collected at various depths from Holes U1346A, U1347A, U1349A, and U1350A during Integrated Ocean Drilling Program Expedition 324. Loss on ignition (LOI) results indicate that alteration affected basalts from the summit sites (U1346 and U1349) more deeply than those from the flank sites (U1347 and U1350). The positive correlations between B, K, and LOI observed in the basalts indicate that low-temperature seawater-derived alteration was the predominant process affecting Shatsky Rise basalts. This is confirmed by the elevated B/K and modest Cl/K ratios of these altered basalts relative to the fresh glasses. In addition, B concentrations in the summit basalts (~132 ppm) are significantly higher than those in normal altered oceanic crust and are likely related to the presence of illite. This suggests that the Shatsky Rise oceanic plateau may be an important sink for B in the Pacific oceanic crust.

It has been suggested that the Shatsky Rise oceanic plateau formation began simultaneously with a reorganization of spreading at a triple junction bordering the northern Pacific plate, and this coincidence has led to speculation about the connections between the two events. We present new marine geophysical data that constrain the seafloor spreading history of the Pacific-Izanagi-Farallon triple junction just before the birth of the Shatsky Rise. Bathymetric data reveal en echelon, abandoned spreading centers trending northwest-southeast located adjacent to the southwest flank of the Shatsky Rise. Magnetic anomalies and bathymetry are interpreted to indicate that segments of the Pacific-Farallon Ridge near the triple junction propagated northwest from chron M23 (153 Ma) to chron M22 (151 Ma) during a spreading ridge reorganization at the edge of a likely microplate. Our detailed examination of bathymetric and magnetic anomaly lineations also shows that the strike of the Pacific-Izanagi Ridge changed gradually on the west side of the triple junction around chron M22. Our observations indicate that the plate boundary reorganization began several million years before the formation of the Shatsky Rise, implying that the eruption of the plateau did not cause the reorganization.

The Shatsky Rise is one of the largest oceanic plateaus, a class of volcanic features whose formation is poorly understood. It is also a plateau that was formed near spreading ridges, but the connection between the two features is unclear. The geologic structure of the Shatsky Rise can help us understand its formation. Deeply penetrating two-dimensional (2-D) multichannel seismic (MCS) reflection profiles were acquired over the southern half of the Shatsky Rise, and these data allow us to image its upper crustal structure with unprecedented detail. Synthetic seismograms constructed from core and log data from scientific drilling sites crossed by the MCS lines establish the seismic response to the geology. High-amplitude basement reflections result from the transition between sediment and underlying igneous rock. Intrabasement reflections are caused by alternations of lava flow packages with differing properties and by thick interflow sediment layers. MCS profiles show that two of the volcanic massifs within the Shatsky Rise are immense central volcanoes. The Tamu Massif, the largest (~450 km × 650 km) and oldest (ca. 145 Ma) volcano, is a single central volcano with a rounded shape and shallow flank slopes (<0.5°–1.5°), characterized by lava flows emanating from the volcano center and extending hundreds of kilometers down smooth, shallow flanks to the surrounding seafloor. The Ori Massif is a large volcano that is similar to, but smaller than, the Tamu Massif. The morphology of the massifs implies formation by extensive and far-ranging lava flows emplaced at small slope angles. The relatively smooth flanks of the massifs imply that the volcanoes were not greatly affected by rifting due to spreading ridge tectonics. Deep intrabasement reflectors parallel to the upper basement surface imply long-term isostasy with the balanced addition of material to the surface and subsurface. No evidence of subaerial erosion is found at the summits of the massifs, suggesting that they were never highly emergent.

The Shatsky Rise, located in the northwest Pacific Ocean, is one of the largest oceanic plateaus. The origin and evolution of the oceanic plateaus are unclear because these features are remote and poorly imaged with geophysical data. Marine multi-channel seismic (MCS) data were collected over the Shatsky Rise to image its upper crustal structure. These data have the potential to improve understanding of the processes of basaltic volcanism and the formation and evolution of oceanic plateaus by providing direct insights into the geometry and distribution of igneous eruptions. In contrast to sedimentary settings, it is often difficult to interpret deeper layers within basaltic crust because of rugged layering and scattering. Reflections in igneous crust are characterized by poor lateral continuity compared with marine sediments and often by weak impedance contrasts, resulting in a lower signal-to-noise ratio and a more challenging interpretation. In this paper we apply the two-dimensional (2-D) anisotropic continuous wavelet transform (CWT) method to improve interpretations of MCS data from the Shatsky Rise oceanic plateau. Applying the transform to the time domain MCS profiles with appropriate values of wavelength and period produces new images with enhanced continuity of reflectors and reduced amplitudes of incoherent noise at different periods. The analysis of the results obtained by using 2-D CWT on the MCS data over the Tamu massif part of the Shatsky Rise also helps reveal features such as dome-like bulges possibly associated with lava intrusion and faults in the deeper part of the crust associated with volcanic rock. These were not readily seen in the original seismic images, but the suppression of random noise and other signals with low coherence makes their interpretation possible. These and similar results provide new insights into the complexity of the igneous processes forming the Tamu massif.

The eruptive history of the Shatsky Rise, a large oceanic plateau in the northwestern Pacific Ocean, is poorly understood. Although it has been concluded that the Shatsky Rise volcanic edifices erupted rapidly, there are few solid chronological data to support this conclusion. Similarly, the Shatsky Rise is thought to have formed near the equator, but paleolatitude data from the plateau are few, making it difficult to assess its plate tectonic drift with time. To understand the formation history of this oceanic plateau, paleomagnetic measurements were conducted on a total of 362 basaltic lava samples cored from the Shatsky Rise at 4 sites (U1346, U1347, U1349, and U1350) during Integrated Ocean Drilling Program Expedition 324. Examining changes in paleomagnetic inclinations, we gain a better understanding of eruptive rates by comparison of observed shifts in inclination with expected paleosecular variation. At three sites (U1346, U1347, and U1349) little change in paleomagnetic directions was observed, implying that the cored sections were mostly erupted rapidly over periods of <~100–200 yr. Only Site U1350 displayed directional changes consistent with significant paleosecular variation, implying emplacement over a period of ~1000 yr. The paleomagnetic data are consistent with the idea that the Shatsky Rise igneous sections were mostly emplaced rapidly, but there were some time gaps and some fl ank locations built up more slowly. Because paleosecular variation was inadequately sampled at all the Shatsky Rise sites, paleolatitudes have large uncertainties, and because of the equatorial location, magnetic polarity is also uncertain. All sites yield low paleolatitudes and indicate that the Shatsky Rise stayed near the equator during its formation. Given that the locus of magmatism moved northward relative to the Pacific plate while staying near the equator, the Pacific plate must have drifted southward relative to the spin axis during the emplacement of the plateau.

Fresh basalts from the Ontong Java Plateau (OJP) and the Shatsky Rise show lithium enrichments comparable to those of mid-oceanic ridge basalts (MORBs) and ocean island basalts (OIBs), with Li contents being significantly higher at a given MgO content. The Li isotopic compositions of the Shatsky Rise basalts (δ 7 Li = +6‰ to +7‰) are at the higher end of the range exhibited by OIBs, whereas OJP basalts (δ 7 Li = +3‰ to +5‰) have Li isotopic compositions similar to MORBs. Among all the basalts from the two oceanic large igneous provinces (LIPs), one sample from the Shatsky Rise is isotopically enriched (e.g., low 143 Nd/ 144 Nd and 176 Hf/ 177 Hf) and has higher K/Ti and lower La/Nb than the other samples. Relationships between δ 7 Li and K/Ti, La/Nb, and Rb/Nb of this sample indicate that it may have been affected by mantle that was metasomatized by slab-derived fluids. Apart from this isotopically enriched sample, δ 7 Li values of basalts from the two oceanic LIPs are positively correlated with K/Ti and Rb/Nb. Obvious linear relationships exist between δ 7 Li and Yb/Li, Y/Li, and Dy/Li for samples from the Shatsky Rise. These geochemical relationships can be explained by magmatic assimilation of hydrothermally influenced crust. The high δ 7 Li values of the Shatsky Rise basalts imply that the degree of assimilation is high because shallow magma chambers allow greater assimilation of hydrothermally influenced crust. In contrast, the low δ 7 Li values of the OJP samples may indicate they have undergone little assimilation as compared with the Shatsky Rise basalts.

A substantial portion of the Pacific basin is composed of seafloor formed during the Cretaceous Normal Superchron (CNS). Because this region lacks the magnetic lineations typically required to constrain tectonic reconstructions, we employ additional methods for interpreting CNS Pacific history, involving seafloor fabric, basement paleolatitudes, and age data. We utilize seafloor fabric, including fracture zones and the rift margins of large igneous provinces, to derive quantitative rotations. The timing of such rotations is constrained using rock ages, bounding magnetic isochrons, and estimates of interactions with surrounding terrains. The method relies on high-resolution shipboard bathymetry and rock ages, as much fine-scale seafloor fabric useful for reconstructions is not visible in satellite altimetry data. We show that the Ontong Java, Manihiki, and Hikurangi oceanic plateaus likely originated as one large superplateau, the Ontong Java Nui (OJN). Reconstructions of OJN at 123 Ma reveal large offsets between observed and predicted paleolatitudes. Observed paleolatitudes exhibit a systematic bias, which may be attributed to large-scale rotation of the entire plateau. Such a rotation would imply either that OJN was initially decoupled from the Pacific plate and able to rotate independently or that the orientation of the Pacific plate at 123 Ma differed from conventional model predictions. However, large uncertainties in absolute plate motion models prior to ca. 80 Ma preempt a conclusive interpretation for OJN formation. Given an ~10 km resolution limit for satellite altimetry, continued investments in seagoing research will be needed to investigate tectonic events in magnetic quiet zones.

The Manihiki Plateau in the western equatorial Pacific Ocean is a Cretaceous Large Igneous Province. Several studies have proposed that the Manihiki Plateau was formed by the same mantle plume that formed the Ontong Java and Hikurangi plateaus ca. 125 Ma. Recent multibeam bathymetric surveys of the Manihiki Plateau reveal the morphology of the Danger Islands Troughs (DIT), Suvarov Trough, which are systems of deep troughs within the plateau. The troughs divide the Manihiki Plateau into three distinct provinces, the North Plateau, the Western Plateaus, and the High Plateau. The DIT between the High Plateau and Western Plateaus comprises four en echelon troughs. With one exception, all segments of the DIT are bordered by steep escarpments, to 1500 m high. The basins of the DIT are smooth. Elongated northeast-southwest–striking scarps are common in the southernmost DIT and at the junction between the DIT and Suvarov Trough. The features revealed by the new bathymetric data indicate that a sinistral strike-slip tectonic environment formed the DIT during the break-up into the Manihiki and Hikurangi plateaus, whereas the Suvarov Trough developed after the formation of the DIT.

High-Mg Kroenke-type basalts containing 9–11 wt% MgO from the Ontong Java Plateau (OJP) include spinels. These spinels have nearly identical Cr/(Cr + Al) ratios (0.45–0.54), and are generally hosted by olivine phenocrysts with relatively primitive compositions, with Fo contents [100 × Mg/(Mg + Fe 2+ ) in atomic ratios] as high as 88. This implies that the primary OJP magmas were in equilibrium with refractory peridotites (i.e., harzburgites) and were homogenized by large-scale melting and magmatic evolutionary processes. Oxygen geobarometry indicates that the OJP primary magmas record uniform oxygen fugacity ( f O 2 ) conditions and are slightly more oxidized (0.6 log units) than normal mid-ocean ridge basalts, but record less-oxidized f O 2 conditions than ocean island basalts. These data are consistent with previous studies that suggest the OJP primary magmas were generated by large-scale and extensive melting of a mantle source region under relatively oxidized conditions.

The Lyra Basin is believed to be a contiguous part of the Ontong Java Plateau (OJP), based on geophysical studies. Volcaniclastic rocks dredged at two sites in the Lyra Basin document another post-plateau episode of magmatism on the OJP; they are olivine-titanaugite-phyric alkali basalts with as much as ~30% modal phenocrysts. Lyra Basin basalts have compositions that vary from picritic (MgO ~22 wt%) to more evolved (MgO ~5 wt%) and have low SiO 2 (41–46 wt%), high TiO 2 (2–4 wt%), and high Na 2 O + K 2 O (1–5 wt%) contents that are distinctly different from tholeiites that compose the main OJP. The 40 Ar- 39 Ar weighted mean age of Lyra Basin basalts is 65.3 ± 1.1 Ma, determined using a single-grain laser fusion method of the ground-mass from the least altered alkali basalt and of biotite separates from differentiated samples. This age is interesting because it is much younger than the main stage of OJP formation (122 Ma) and no ca. 65 Ma alkaline basalts have been found previously near or on the OJP. Incompatible trace element modeling suggests that the volcanic rocks of the Lyra Basin may have been formed by a low degree of partial melting (~3%), predominantly at the garnet-lherzolite stability field from the same OJP mantle source preserved in its thick lithospheric root. However, major and trace elements and isotopic compositions can be better explained by magma mixing of Rarotongan alkali magma and magma derived from OJP-source mantle melting (12% partial melting at garnet stability field) in the ratio of 1:2. Although the trace element compositions of Lyra basalts can be reproduced by OJP-source mantle melting with or without contribution from the Rarotongan hotspot, the lower potassium content of the calculated Rarotongan hotspot-influenced melt is more compatible with that of an average composition of Lyra basalt. These results are consistent with previous reconstruction of the OJP path from 120 Ma to its present position, indicating that it may have passed over the Rarotongan hotspot at 65 Ma. In either case, the petrogenesis of Lyra Basin basalts highlights the role of the thick lithospheric root of the OJP in the late-stage development of the plateau. Additional evidence for episodic late-stage magmatic activity on the OJP helps to elucidate the magmatic evolution of the plateau and may provide insights into the origins of other large igneous provinces.

The few geological and geophysical studies of the Lyra Basin at the western margin of the Ontong Java Plateau (OJP; Pacific Ocean) revealed that it is underlain by thicker than normal oceanic crust. The unusually thick oceanic crust is attributed to the emplacement of massive lava flows from the OJP. Dredging was conducted to sample the inferred OJP crust on the Lyra Basin but instead recovered younger extrusives that may have covered the older plateau lavas in the area. The Lyra Basin extrusives are alkalic basalts with ( 87 Sr/ 86 Sr) t = 0.704513–0.705105, ( 143 Nd/ 144 Nd) t = 0.512709–0.512749, ε Nd (t) = +3.0 to +3.8, ( 206 Pb/ 204 Pb) t = 18.488–18.722, ( 207 Pb/ 204 Pb) t = 15.558–15.577, and ( 208 Pb/ 204 Pb) t = 38.467–38.680 that are distinct from those of the OJP tholeiites. They have age-corrected ( 187 Os/ 188 Os) t = 0.1263–0.1838 that overlap with the range of values determined for the Kroenke-type and Kwaimbaita-type OJP basalts, but their ( 176 Hf/ 177 Hf) t = 0.28295–0.28299 and ε Hf (t) = +7.9 to +9.3 values are lower. These isotopic compositions do not match those of any Polynesian ocean island volcanics. Instead, the Lyra Basin basalts have geochemical affinity and isotopic compositions that overlap with those of some alkalic suite and alnöites in the island of Malaita, Solomon Islands. Although not directly related to the main plateau volcanism at 120 Ma, the geochemical data and modeling suggest that the origin of the Lyra Basin alkalic rocks may be genetically linked to the mantle preserved in the OJP thick lithospheric root, with magmatic contribution from the Rarotongan hotspot.

The mid-Cretaceous was marked by emplacement of large igneous provinces (LIPs) that formed gigantic oceanic plateaus, affecting ecosystems on a global scale, with biota forced to face excess CO 2 resulting in climate and ocean perturbations. Volcanic phases of the Ontong Java Plateau (OJP) and the southern Kerguelen Plateau (SKP) are radiometrically dated and correlate with paleoenvironmental changes, suggesting causal links between LIPs and ecosystem responses. Aptian biocalcification crises and recoveries are broadly coeval with C, Pb, and Os isotopic anomalies, trace metal influxes, global anoxia, and climate changes. Early Aptian greenhouse or super-greenhouse conditions were followed by prolonged cooling during the late Aptian, when OJP and SKP developed, respectively. Massive volcanism occurring at equatorial versus high paleolatitudes and submarine versus subaerial settings triggered very different climate responses but similar disruptions in the marine carbonate system. Excess CO 2 arguably induced episodic ocean acidification that was detrimental to marine calcifiers, regardless of hot or cool conditions. Global anoxia was reached only under extreme warming, whereas cold conditions kept the oceans well oxygenated even at times of intensified fertility. The environmental disruptions attributed to the OJP did not trigger a mass extinction: rock-forming nannoconids and benthic communities underwent a significant decline during Oceanic Anoxic Event (OAE) 1a, but recovered when paroxysmal volcanism finished. Extinction of many planktonic foraminiferal and nannoplankton taxa, including most nannoconids, and most aragonitic rudists in latest Aptian time was likely triggered by severe ocean acidification. Upgraded dating of paleoceanographic events, improved radiometric ages of the OJP and SKP, and time-scale revision are needed to substantiate the links between magmatism and paleoenvironmental perturbations.

We present a comprehensive data set of organic and inorganic geochemistry from a lower Cretaceous pelagic bedded chert succession of the Shimanto accretionary belt in the Yokonami Peninsula (Kochi, Japan). Based on stable isotopic composition of total organic carbon (δ 13 C org ), in conjunction with radiolarian biostratigraphic data, we propose that a 1.3-m-thick interval within the examined section is correlative with Tethyan Selli Level (Apennines, Italy), a sedimentary expression of oceanic anoxic event (OAE) 1a. Specifically, the δ 13 C org record illustrates a discernible negative shift and subsequent positive excursions upsection, a pattern that resembles the typical δ 13 C org pattern across OAE 1a reported from various sites such as the Mediterranean Tethys and Pacific seamount flanks. Our δ 13 C org record from the deep Pacific basin supports the idea that the δ 13 C variation across OAE 1a was induced by a significant perturbation of global carbon cycle. The slight increase in total organic carbon contents of sediment deposited during OAE 1a suggests slight or no expansion of oxygen-deficient water mass in the overlying water column. Rare earth elements and lead isotopic compositions indicate relatively higher contributions of volcanic or hydrothermally altered components before and after OAE 1a. The volcanic or hydrothermal source may be associated with emplacement of the Ontong Java Plateau during the early Aptian, or tectonically induced hydrothermal alteration associated with the formation of the accretionary complex.

Among various paleoenvironmental proxy records across the lower Aptian Selli Level (Umbria-Marche basin, Italy) and its equivalents (i.e., sedimentary expressions of oceanic anoxic event [OAE] 1a), one very intriguing feature is a prominent negative δ 13 C excursion at the base of this sedimentary unit, generally by as much as a few per mil in marine carbonates. This early Aptian δ 13 C event has received special attention as an important clue to the genesis of OAE 1a, but the exact amplitude of this relatively short lived δ 13 C variation is not precisely constrained, and this fact has been an obstacle in paleoenvironmental modeling. Particularly enigmatic is the large amplitude, by −7‰, in pelagic limestones at the central Pacific Deep Sea Drilling Project (DSDP) Site 463; it may be a primary δ 13 C signal, considering its deposition in a fully open-ocean setting and a conservative burial diagenetic environment. Nevertheless, new Sr isotope data help identify a peculiar diagenetic overprint on the lower Aptian interval of this site. While the majority of examined samples represent slightly shifted, but acceptable, 87 Sr/ 86 Sr ratios for marine carbonates of this age, markedly unradiogenic 87 Sr/ 86 Sr ratios are recorded within and just below the Selli Level–equivalent interval. In particular, extremely unradiogenic 87 Sr/ 86 Sr ratios (0.70623–0.70642) are detected at exactly the same interval as the most negative δ 13 C values and a smectite-rich lithology. It is therefore proposed that hitherto unknown diagenetic process, or processes, under peculiar interstitial-water geochemistry, resulting from volcanic ash alteration, played a role for the paired δ 13 C- 87 Sr/ 86 Sr anomaly at DSDP Site 463. By removing the δ 13 C data from samples that possess the highly unradiogenic 87 Sr/ 86 Sr ratios, the amplitude of early Aptian negative δ 13 C excursion is reevaluated to be −2.7‰ or −3.3‰, facilitating comparison with published δ 13 C records from other sections. The refined Site 463 δ 13 C profile further implies that the early Aptian negative δ 13 C event is better described as a twin excursion.