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Calibration of redox thresholds in black shale: Insight from a stratified Mississippian basin with warm saline bottom waters
Environmental and trilobite diversity changes during the middle-late Cambrian SPICE event
Implications of an integrated late Ediacaran to early Cambrian stratigraphy of the Siberian Platform, Russia
Origin of the Neoarchean VMS-BIF Metallogenic Association in the Qingyuan Greenstone Belt, North China Craton: Constraints from Geology, Geochemistry, and Iron and Multiple Sulfur ( δ 33 S, δ 34 S, and δ 36 S) Isotopes
Secular variation in seawater redox state during the Marinoan Snowball Earth event and implications for eukaryotic evolution
No effect of thermal maturity on the Mo, U, Cd, and Zn isotope compositions of Lower Jurassic organic-rich sediments
A template for an improved rock-based subdivision of the pre-Cryogenian timescale
The Ediacaran ‘Miaohe Member’ of South China: new insights from palaeoredox proxies and stable isotope data
Ocean euxinia and climate change “double whammy” drove the Late Ordovician mass extinction
A continental-weathering control on orbitally driven redox-nutrient cycling during Cretaceous Oceanic Anoxic Event 2
Phosphorus sources for phosphatic Cambrian carbonates
Stability of the nitrogen cycle during development of sulfidic water in the redox-stratified late Paleoproterozoic Ocean
Anoxia in the terrestrial environment during the late Mesoproterozoic
Green rust formation controls nutrient availability in a ferruginous water column
Does the Paleoproterozoic Animikie Basin record the sulfidic ocean transition?: COMMENT
Ferruginous Conditions: A Dominant Feature of the Ocean through Earth's History
Characterization of Iron Partitioning in Cretaceous Oceanic Red Beds of the Chuangde Section, South Tibet
Abstract Oceanic red beds were widespread during the Late Cretaceous in association with major climate perturbations. Despite their relevance to the debate concerning the effects of climate change on ocean redox, the detailed geochemistry (particularly with regard to Fe mineralogy) and the mechanism of formation of Cretaceous oceanic red beds remain poorly understood. Here we present a detailed examination of Fe partitioning in Cretaceous oceanic red beds. Our focus is on a transition from gray-black shales (the Barremian-Santonian Gyabula Formation) to overlying oceanic red beds (the Late Santonian-Campanian Chuangde Formation) from the Chuangde section, Gyangtze, South Tibet. A chemical sequential extraction method was applied to these two distinct rock types to acquire burial records for different operationally defined iron fractions. Carbonate-associated iron and pyrite are relatively enriched in the Gyabula Formation. When combined with total Fe-Al relationships, REE data, and trace-fossil occurrences, this implies deposition under conditions of relatively reduced dissolved oxygen. In contrast, pyrite was below detection limits and carbonate-associated iron was much lower in the red beds of the Chuangde Formation. Here, ferric iron oxides (largely hematite) are relatively enriched, and this enrichment likely occurred during deposition to early diagenesis. The ratio of ferric oxides to total iron (Feox/FeT) indicates an oxic depositional environment for the red beds. A comparison of records of reactive iron burial with proxies for paleo-productivity suggests that productivity decreased with increased Feox/FeT in the red beds. This implies that a feedback between oceanic redox and productivity (i.e., lower productivity under more oxic oceanic conditions), might be responsible for the prolonged formation of Cretaceous oceanic red beds in South Tibet. This feedback mechanism could have been fostered by increased ventilation of the ocean due to global cooling and a deep connection between the North and South Atlantic Ocean during Late Santonian-Early Campanian times. Key words:iron speciation, oceanic red beds, Cretaceous, Chuangde section, South Tibet