ABSTRACT This contribution is concerned with the debated origin of the impact melt rock in the central uplift of the world’s largest confirmed impact structure—Vredefort (South Africa). New major- and trace-element abundances, including those of selected highly siderophile elements (HSEs), Re-Os isotope data, as well as the first Se isotope and Se-Te elemental systematics are presented for the felsic and mafic varieties of Vredefort impact melt rock known as “Vredefort Granophyre.” In addition to the long-recognized “normal” (i.e., felsic, >66 wt% SiO 2) granophyre variety, a more mafic (<66 wt% SiO 2) impact melt variety from Vredefort has been discussed for several years. The hypothesis that the mafic granophyre was formed from felsic granophyre through admixture (assimilation) of a mafic country rock component that then was melted and assimilated into the superheated impact melt has been pursued here by analysis of the two granophyre varieties, of the Dominion Group lava (actually meta-lava), and of epidiorite mafic country rock types. Chemical compositions, including high-precision isotope dilution–derived concentrations of selected highly siderophile elements (Re, Os, Ir, Pt, Se, Te), and Re-Os and Se isotope data support this hypothesis. A first-order estimate, based on these data, suggests that some mafic granophyre may have resulted from a significant admixture (assimilation) of epidiorite to felsic granophyre. This is in accordance with the findings of an earlier investigation using conventional isotope (Sr-Nd-Pb) data. Moreover, these outcomes are in contrast to a two-stage emplacement model for Vredefort Granophyre, whereby a mafic phase of impact melt, derived by differentiation of a crater-filling impact melt sheet, would have been emplaced into earlier-deposited felsic granophyre. Instead, all chemical and isotopic evidence so far favors formation of mafic granophyre by local assimilation of mafic country rock—most likely epidiorite—by a single intrusive impact melt phase, which is represented by the regionally homogeneous felsic granophyre.

ABSTRACT Early Archean spherule layers, widely accepted to represent distal ejecta deposits from large-scale impact events onto the early Earth, have been described from several stratigraphic levels of the Barberton greenstone belt in South Africa. Recently, exploration drilling at the Fairview Gold Mine (25°43′53″S, 31°5′59″E) in the northern domain of the belt resulted in the discovery of a new set of spherule layer intersections. The Fairview spherule layers in drill cores BH5901, BH5907, BH5911, and BH5949 were intersected just a few meters apart, at about the same stratigraphic position within the transition from the Onverwacht Group to the Fig Tree Group. The Fairview spherule layers have petrographic and chemical similarities to at least three other well-known Barberton spherule layers (S2–S4), and multiple spherule layer bed intersections in drill cores BARB5 and CT3, all from about the same stratigraphic position. They are not uniform in composition, in particular with respect to abundances of highly siderophile elements. The highest concentrations of moderately (Cr, Co, Ni) and highly siderophile (Ir) elements are within the range of concentrations for chondrites and, thus, reinforce the impact hypothesis for the generation of the Fairview spherule layers. Iridium peak concentrations and Cr/Ir interelement ratios for spherule layer samples from drill cores BH5907, BH5911, and BH5949 suggest admixtures of 50%–60% chondritic material, whereas for the BH5901 spherule layer, only an admixture of 1% chondritic material is indicated. We discuss whether these four Fairview spherule layers represent the same impact event, and whether they can be correlated to any of the S2–S4, CT3, and BARB5 intersections.

ABSTRACT A combined petrographic and chemical study of ejecta particles from the Cretaceous-Paleogene boundary sequence of El Guayal, Tabasco, Mexico (520 km SW of Chicxulub crater), was carried out to assess their formation conditions and genetic relation during the impact process. The reaction of silicate ejecta particles with hot volatiles during atmospheric transport may have induced alteration processes, e.g., silicification and cementation, observed in the ejecta deposits. The various microstructures of calcite ejecta particles are interpreted to reflect different thermal histories at postshock conditions. Spherulitic calcite particles may represent carbonate melts that were quenched during ejection. A recrystallized microstructure may indicate short, intense thermal stress. Various aggregates document particle-particle interactions and intermixing of components from lower silicate and upper sedimentary target lithologies. Aggregates of recrystallized calcite with silicate melt indicate the consolidation of a hot suevitic component with sediments at ≳750 °C. Accretionary lapilli formed in a turbulent, steam-condensing environment at ~100 °C by aggregation of solid, ash-sized particles. Concentric zones with smaller grain sizes of accreted particles indicate a recurring exchange with a hotter environment. Our results suggest that during partial ejecta plume collapse, hot silicate components were mixed with the fine fraction of local surface-derived sediments, the latter of which were displaced by the preceding ejecta curtain. These processes sustained a hot, gas-driven, lateral basal transport that was accompanied by a turbulent plume at a higher level. The exothermic back-reaction of CaO from decomposed carbonates and sulfates with CO 2 to form CaCO 3 may have been responsible for a prolonged release of thermal energy at a late stage of plume evolution.

The Chesapeake Bay impact structure, which is 85 km in diameter and 35.5 Ma old, was drilled and cored in a joint International Continental Scientific Drilling Program (ICDP) and U.S. Geological Survey (USGS) drilling project at Eyreville Farm, Virginia, U.S.A. In the Eyreville drill core, 154 m of impact breccia were recovered from the depth interval 1397–1551 m. Major- and trace-element concentrations were determined in 75 polymict impactite samples, 10 samples of cataclastic gneiss blocks, and 24 clasts from impactites. The chemical composition of the polymict impactites does not vary much in the upper part of the section (above ~1450 m), whereas in the lower part, larger differences occur. Polymict impactites show a decrease of SiO 2 content, and slight increases of TiO 2 , Al 2 O 3 , and Fe 2 O 3 abundances, with depth. This is in agreement with an increase of the schist/gneiss component with depth. Concentrations of siderophile elements (Co, Ni) are lower in the polymict impactites than in the basement-derived schists and do not indicate the presence of an extraterrestrial component. The five petrographically determined types of melt particles, i.e., clear glass, altered melt, recrystallized silica melt, melt with microlites, and dark-brown melt, have distinct chemical compositions. Mixing calculations of the proportions of rocks involved in the formation of various polymict impactites and melt particles were carried out using the Harmonic least-squares MiXing (HMX) calculation program. The calculations suggest that the metamorphic basement rocks (i.e., gneiss and schist) constitute the main component of the polymict impactites, together with significant sedimentary and possible minor pegmatite/granite and amphibolite components. The sedimentary component is derived mostly from a sediment characterized by a composition similar to that of the Cretaceous Potomac Formation. Compositions of the melt particles were modeled as mixtures of target rocks or major rock-forming minerals. However, the results of the mixing calculations for the melt particles are not satisfactory, and the composition of the particles could have been modified by hydrothermal alteration. Carbon isotope ratios were determined for 18 samples. The results imply a hydrothermal origin for the carbonate veins from the basement-derived core section; carbon-rich sedimentary clasts from the Exmore breccia and suevite have a δ 13 C range typical for organic matter in sediments.