The Eyreville B core from the Chesapeake Bay impact structure, Virginia, USA, contains a lower basement-derived section (1551.19 m to 1766.32 m deep) and two megablocks of dominantly (1) amphibolite (1376.38 m to 1389.35 m deep) and (2) granite (1095.74 m to 1371.11 m deep), which are separated by an impactite succession. Metasedimentary rocks (muscovite-quartz-plagioclase-biotite-graphite ± fibrolite ± garnet ± tourmaline ± pyrite ± rutile ± pyrrhotite mica schist, hornblende-plagioclase-epidote-biotite-K-feldspar-quartz-titanite-calcite amphibolite, and vesuvianite-plagioclase-quartz-epidote calc-silicate rock) are dominant in the upper part of the lower basement-derived section, and they are intruded by pegmatitic to coarse-grained granite (K-feldspar-plagioclase-quartz-muscovite ± biotite ± garnet) that increases in volume proportion downward. The granite megablock contains both gneissic and weakly or nonfoliated biotite granite varieties (K-feldspar-quartz-plagioclase-biotite ± muscovite ± pyrite), with small schist xenoliths consisting of biotite-plagioclase-quartz ± epidote ± amphibole. The lower basement-derived section and both megablocks exhibit similar middle- to upper-amphibolite-facies metamorphic grades that suggest they might represent parts of a single terrane. However, the mica schists in the lower basement-derived sequence and in the megablock xenoliths show differences in both mineralogy and whole-rock chemistry that suggest a more mafic source for the xenoliths. Similarly, the mineralogy of the amphibolite in the lower basement-derived section and its association with calc-silicate rock suggest a sedimentary protolith, whereas the bulk-rock and mineral chemistry of the megablock amphibolite indicate an igneous protolith. The lower basement-derived granite also shows bulk chemical and mineralogical differences from the megablock gneissic and biotite granites.

The moat of the 85-km-diameter and 35.3-Ma-old Chesapeake Bay impact structure (USA) was drilled at Eyreville Farm in 2005–2006 as part of an International Continental Scientific Drilling Program (ICDP)–U.S. Geological Survey (USGS) drilling project. The Eyreville drilling penetrated postimpact sediments and impactites, as well as crystalline basement-derived material, to a total depth of 1766 m. We present petrographic observations on 43 samples of suevite, impact melt rock, polymict lithic impact breccia, cataclastic gneiss, and clasts in suevite, from the impact breccia section from 1397 to 1551 m depth in the Eyreville B drill core. Suevite samples have a fine-grained clastic matrix and contain a variety of mineral and rock clasts, including sedimentary, metamorphic, and igneous lithologies. Six subunits (U1–U6, from top to bottom) are distinguished in the impact breccia section based on abundance of different clasts, melt particles, and matrix; the boundaries between the subunits are generally gradational. Sedimentary clasts are dominant in most subunits (especially in U1, but also in U3, U4, and U6). There are two melt-rich subunits (U1 and U3), and there are two melt-poor subunits with predominantly crystalline clasts (U2 and U5). The lower part (subunits U5 and U6), which has large blocks of cataclastic gneiss and rare melt particles, probably represents ground-surge material. Subunit U1 possibly represents fallback material, since it contains shard-like melt particles that were solidified before incorporation into the breccia. The melt-poor, crystalline clast–rich subunit U2 could have been formed by slumping of material, probably from the central uplift or from the margin of the transient crater. Melt particles are most abundant near the top of the impact breccia section (above 1409 m) and around 1450 m, where the suevite grades into impact melt rock. Five different types of melt particles have been recognized: (1) clear colorless to brownish glass; (2) melt altered to fine-grained phyllosilicate minerals; (3) recrystallized silica melt; (4) melt with microlites; and (5) dark-brown melt. Proportions of matrix and melt in the suevite are highly variable (~2–67 vol% and 1–67 vol%, respectively; the remainder consists of lithic clasts). Quartz grains in suevite commonly show planar fractures (PFs) and/or planar deformation features (PDFs; 1 or 2 sets, rarely more); some PDFs are decorated. On average, ~16 rel% of quartz grains in suevite samples are shocked (i.e., show PFs and/or PDFs). Sedimentary clasts (e.g., graywacke or sandstone) and polycrystalline quartz clasts have relatively higher proportions of shocked quartz grains, whereas quartz grains in schist and gneiss clasts rarely show shock effects. Rare feldspar grains with PDFs and mica with kink banding were observed. Ballen quartz was noted in melt-rich samples. Evidence of hydrothermal alteration, namely, the presence of smectite and secondary carbonate veins, was found especially in the lower parts of the impact breccia section.

The Chesapeake Bay impact structure, which is 85 km in diameter and 35.5 Ma old, was drilled and cored in a joint International Continental Scientific Drilling Program (ICDP) and U.S. Geological Survey (USGS) drilling project at Eyreville Farm, Virginia, U.S.A. In the Eyreville drill core, 154 m of impact breccia were recovered from the depth interval 1397–1551 m. Major- and trace-element concentrations were determined in 75 polymict impactite samples, 10 samples of cataclastic gneiss blocks, and 24 clasts from impactites. The chemical composition of the polymict impactites does not vary much in the upper part of the section (above ~1450 m), whereas in the lower part, larger differences occur. Polymict impactites show a decrease of SiO 2 content, and slight increases of TiO 2 , Al 2 O 3 , and Fe 2 O 3 abundances, with depth. This is in agreement with an increase of the schist/gneiss component with depth. Concentrations of siderophile elements (Co, Ni) are lower in the polymict impactites than in the basement-derived schists and do not indicate the presence of an extraterrestrial component. The five petrographically determined types of melt particles, i.e., clear glass, altered melt, recrystallized silica melt, melt with microlites, and dark-brown melt, have distinct chemical compositions. Mixing calculations of the proportions of rocks involved in the formation of various polymict impactites and melt particles were carried out using the Harmonic least-squares MiXing (HMX) calculation program. The calculations suggest that the metamorphic basement rocks (i.e., gneiss and schist) constitute the main component of the polymict impactites, together with significant sedimentary and possible minor pegmatite/granite and amphibolite components. The sedimentary component is derived mostly from a sediment characterized by a composition similar to that of the Cretaceous Potomac Formation. Compositions of the melt particles were modeled as mixtures of target rocks or major rock-forming minerals. However, the results of the mixing calculations for the melt particles are not satisfactory, and the composition of the particles could have been modified by hydrothermal alteration. Carbon isotope ratios were determined for 18 samples. The results imply a hydrothermal origin for the carbonate veins from the basement-derived core section; carbon-rich sedimentary clasts from the Exmore breccia and suevite have a δ 13 C range typical for organic matter in sediments.

This paper documents an attempt to detect a meteoritic component in both wash-back (resurge) crater-fill breccia (the so-called Exmore breccia) and in suevites from the Eyreville core hole, which was drilled several kilometers from the center of the 85-km-diameter Chesapeake Bay impact structure, Virginia, USA. Determining the presence of an extraterrestrial component and, in particular, the projectile type for this structure, which is the largest impact structure currently known in the United States, is of importance because it marks one of several large impact events in the late Eocene, during which time the presence of extraterrestrial 3 He and multiple impact ejecta layers provide evidence for a comet or asteroid shower. Previous work has indicated an ordinary chondritic projectile for the largest of the late Eocene craters, the Popigai impact structure in Siberia. The exact relation between the Chesapeake Bay impact event and siderophile element anomalies documented in late Eocene ejecta layers from around the world is not clear. The only clear indication for an extraterrestrial component related to this structure has been the discovery of a meteoritic osmium isotopic signature in impact melt rocks recovered from a hydrogeologic test hole located on Cape Charles near the center of the structure, and confirmation of a similar signature in suevitic rocks would have been desirable in order to place constraints on the type of projectile involved in formation of the Chesapeake Bay crater. Unfortunately, the current data show no discernible differences in the contents of the platinum group elements (PGEs) among the suevite, the Exmore breccia, and several crystalline basement rocks, all from the Eyreville core hole. Abundances of PGEs are uniformly low (e.g., <0.1 ppb Ir), and chondrite-normalized abundance patterns are nonchondritic. These data do not allow unambiguous verification of an extraterrestrial signature. Thus, the nature of the Chesapeake Bay projectile remains ambiguous.

We investigated whole-rock chemical compositions of 318 samples of Exmore breccia (diamicton), impactite (suevite, impact melt rock, polymict lithic impact breccia), and crystalline basement-derived rocks from 444 to 1766 m depth in the International Continental Scientific Drilling Program (ICDP)–U.S. Geological Survey (USGS) Eyreville A and B drill cores (Chesapeake Bay impact structure, Virginia, USA). Here, we compare the average chemical compositions for the Exmore breccia (diamicton), the impactites and their subunits, sandstone, granite, granitic gneiss, and amphibolite of the lithic block section (1095.7–1397.2 m depth), cataclastic gneiss of the impact breccia section, and schist and pegmatite/granite of the basal crystalline section (1551.2–1766.3 m depth). The granite of the megablock (1097.7–1371.1 m depth) is of I-type and is seemingly related to a syncollisional setting. The amphibolite (1377.4–1387.5 m depth) of the lithic block section is of igneous origin and has a tholeiitic character. Based on chemical composition, the Exmore breccia (diamicton) can be subdivided into five units (444.9–450.7, 450.7–468, 468–518, 518–528, and 528–~865 m depth). The units in the depth intervals of 450.7–468 and 518–528 m are enriched in TiO 2 , MgO, Sc, V, Cr, and Zn contents compared to the other Exmore breccia units. In some samples, especially at ~451–455 m depth, the Exmore breccia contains significant amounts of P 2 O 5 . The Exmore breccia is recognized as a mixture of all sedimentary and crystalline target components, and, when compared to the impactites, it contains a significant amount of a SiO 2 -rich target component of sedimentary origin. The chemical composition of the impactites overlaps the compositional range for the Exmore breccia. The impactites generally display a negative correlation of SiO 2 and CaO, and a positive correlation of TiO 2 , Al 2 O 3 , Fe 2 O 3 , and MgO with depth. This is the result of an increasing basement schist component, and a decreasing sedimentary and/or granitic component with depth. Suevite units S2 and S3 display distinct enrichment of Na 2 O by a factor of ~2 compared to all other impactite units, which is interpreted to reflect a higher granitic component in these units.