Abstract The interaction of magma and wall-rocks is inevitable when magma is moving through Earth's crust. These interactions happen on different timescales and especially the short-term interactions (seconds to days) during the final ascent of the magma can induce changes in eruption dynamics. However, information on this matter is scarce and scattered in different scientific fields. We conducted this review in order to present a full picture of the state of the art for short-timescale magma–wall-rock interactions. According to the three existing studies on short-term magma–carbonate interactions, magma viscosity is the most important controlling factor for carbonate assimilation. Lower viscosity magmas enhance CO 2 -bubble migration away from the reaction site, resulting in a higher carbonate assimilation rate. The released CO 2 plays an important role regarding eruption dynamics since a higher CO 2 release rate would result in accelerated magma ascent and may increase eruption intensity. Despite the importance for hazard assessment, important factors (pressure, magma composition, vapour phase solubilities, carbonate clast properties) for carbonate assimilation in general and CO 2 release rate in particular are not or only poorly constrained. This review presents the present-day knowledge of short-term magma–carbonate interaction that is relevant to establish the basis for future work concerning magma–wall-rock interactions.

Abstract A dataset on the chemical composition of mineral water discharges from São Miguel, 76 samples, depicts a large variability of chemical types and dissolved solids content. The distribution of the discharges shows an association with the three active Quaternary central volcanoes that dominate the geology of São Miguel, namely Furnas, Fogo and Sete Cidades, 74% of which are springs, 13% fumaroles, 12% wells and 1% hand-dug wells. Total dissolved solids (TDS) values are in the range of 159–20 957 mg l −1 , discharge temperature varies from 15 to 99.5°C and waters are mainly strongly acid to slightly alkaline (pH ranging between 2.2 and 7.71). Springs discharge mainly from perched-water bodies, corresponding to Na-HCO 3 and Na-HCO 3 -Cl-type waters, with a composition influenced by absorption of CO 2 and mixing between meteoric water and boiling waters with a hydrothermal component. Instead the majority of the wells are distributed along the coast and depict chloride enrichment owing to mixture with seawater. The lower pH values are associated with boiling pools at Fogo Volcano with a SO 4 -dominated chemistry, resulting from steam-heating of shallow perched-water bodies.

Abstract Soufrière Hills Volcano produced prodigious quantities of sulphur dioxide (SO 2) gas throughout 1995–2013. An unprecedented, detailed record of SO 2 flux shows that high SO 2 fluxes were sustained through eruptive pauses and for two years after the end of lava extrusion and are decoupled from lava extrusion rates. Lava extrusion rates have exhibited strong 1- to 2-year cyclicity. Wavelet analysis demonstrates periodicities of c. 5 months and c. 2 years within the SO 2 time series, as well as the shorter cycles identified previously. The latter period is similar to the wavelength of cycles in lava extrusion, albeit non-systematically offset. The periodicities are consistent with pressure changes accompanying deformation in a coupled magma reservoir system whereby double periodic behaviour may arise from limited connectivity between two reservoirs. During periods of lava extrusion SO 2 is released together with the lava (yielding the c. 2 year period), albeit with some offset. In contrast, when magma cannot flow because of its yield strength, SO 2 is released independently from lava (yielding the c. 5 month period). Our results have implications for eruption forecasting. It seems likely that, when deep supply of magma ceases, gas fluxes will cease to be periodic.

Abstract This work integrates the available geological information and geochronology data for the Cretaceous–Recent magmatism in the South Atlantic, represented by onshore and offshore magmatic events, including the oceanic islands along the transform faults and near the mid-ocean ridge. The analysis of the igneous rocks and their tectonic settings allows new insights into the evolution of the African and Brazilian continental margins during the South Atlantic opening. Following the abundant volcanism in the Early Cretaceous, the magmatic quiescence during the Aptian–Albian times is a common characteristic of almost all Brazilian and West African marginal basins. However, rocks ascribed to the Cabo Granite (104 Ma) are observed in NE Brazil. In West Africa, sparse Aptian–Albian ages are observed in a few coastal igneous centres. In the SE Brazilian margin, an east–west alkaline magmatic trend is observed from Poços de Caldas to Cabo Frio, comprising igneous intrusions dated from 87 to 64 Ma. Mafic dyke swarms trending NW also occur in the region extending from the Cabo Frio Province towards the Central Brazilian Craton. On the West African side, Early Cretaceous–Recent volcanism is observed in the Walvis Ridge (139 Ma), the St Helena Ridge (81 Ma) and the Cameroon Volcanic Line (Early Tertiary–Recent). Volcanic islands such as Ascencion (1.0–0.65 Ma), Tristão da Cunha (2.5–0.13 Ma) and the St Helena islands (12 Ma) most probably correspond to mantle plumes or hot spots presently located near the mid-Atlantic spreading centre. Within the South America platform and deep oceanic regions, the following volcanic islands are observed: the Rio Grande Rise (88–86 Ma), Abrolhos (54–44 Ma), the Vitória–Trindade Chain (no age), Trindade (2.8–1.2 Ma) and Fernando de Noronha (12–1.5 Ma). There are several volcanic features along the NW–SE-trending Cruzeiro do Sul Lineament from Cabo Frio to the Rio Grande Rise, but they have not been dated. The only known occurrence of serpentinized mantle rocks in the South Atlantic margin is associated with the Saint Peter and Saint Paul Rocks located along the São Paulo Fracture Zone. The Cameroon Volcanic Line in NW Africa is related to the magmatism that started in the Late Cretaceous and shows local manifestations up to the Present. The compilation of all available magmatic ages suggests an asymmetrical evolution between the African and South America platforms with more pre-break-up and post-break-up magmatism observed in the Brazilian margin. This is most likely to have resulted from the different geological processes operating during the South Atlantic Ocean opening, shifts in the spreading centre, and, possibly, the rising and waning of mantle plumes. Supplementary material: A complete table with radiometric dates that have been obtained by universities, government agencies and research groups is available at: www.geolsoc.org.uk/SUP18596