Cycling of redox-sensitive elements such as Fe is affected by not only ambient Eh-pH conditions, but also by a significant biomass that may derive energy through changes in redox state (e.g., Nealson 1983; Lovely et al. 1987; Myers and Nealson 1988; Ghiorse 1989). The evidence now seems overwhelming that biological processing of redox-sensitive metals is likely to be the rule in surface- and near-surface environments, rather than the exception. The Fe redox cycle of the Earth fundamentally begins with tectonic processes, where “juvenile” crust (high-temperature metamorphic and igneous rocks) that contains Fe which is largely in the...
Isotopic Constraints on Biogeochemical Cycling of Fe
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Clark M. Johnson, Brian L. Beard, Eric E. Roden, Dianne K. Newman, Kenneth H. Nealson; Isotopic Constraints on Biogeochemical Cycling of Fe. Reviews in Mineralogy and Geochemistry 2004;; 55 (1): 359–408. doi: https://doi.org/10.2138/gsrmg.55.1.359
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