How is hydrogen distributed among minerals and how is it bonded in their crystal structures? These are important questions, because the amount of hydrogen and the bonding configuration of hydrogen in crystalline materials governs many of that material’s properties: its thermal and compressional behavior, P–T phase stability, rheology, and electrical conductivity. A reliable reconstruction of the Earth’s interior, or the prediction of mineral transformations in complex industrial processes, must account for these parameters. Neutron diffraction can locate hydrogen sites in mineral structures, reveal any static or dynamic hydrogen disorder, help define the libration regime of hydrogen, and elucidate hydrogen-bonding configurations. Thus, that most elusive element for X-ray probes is perfectly detectable using neutrons.
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Research Article|
June 01, 2021
Where is the Hydrogen?
G. Diego Gatta;
Dipartimento Scienze della Terra, Università degli Studi di Milano, Via Botticelli 23, I-20133 Milano, Italy
E-mail: diego.gatta@unimi.it
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Klaudia Hradil;
X-ray center, Technischen Universität Wien, Getreidemarkt 9, A-1060 Vienna, Austria
E-mail: martin.meven@frm2.tum.de
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Martin Meven
Institut für Kristallographie, RWTH Aachen University and Jülich Centre for Neutron Science, FZ Juelich GmbH, at Heinz Maier-Leibnitz Zentrum, Lichtenbergstrasse 1, D-85747 Garching, Germany
E-mail: martin.meven@frm2.tum.de
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Dipartimento Scienze della Terra, Università degli Studi di Milano, Via Botticelli 23, I-20133 Milano, Italy
Publisher: Mineralogical Society of America
First Online:
01 Sep 2021
Online ISSN: 1811-5217
Print ISSN: 1811-5209
Copyright © 2021 by the Mineralogical Society of America
Mineralogical Society of America
Elements (2021) 17 (3): 163–168.
Article history
First Online:
01 Sep 2021
Citation
G. Diego Gatta, Klaudia Hradil, Martin Meven; Where is the Hydrogen?. Elements 2021;; 17 (3): 163–168. doi: https://doi.org/10.2138/gselements.17.3.163
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Index Terms/Descriptors
- bonding
- chemical properties
- circulation
- compression
- crystal structure
- crystallography
- fluid flow
- hydrates
- hydrogen
- hydroxyl ion
- minerals
- neutron diffraction analysis
- order-disorder
- P-T conditions
- physical properties
- Rietveld refinement
- ring silicates
- sheet silicates
- silicates
- thermal properties
- transformations
- X-ray data
- neutron scattering methods
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