The crystal-chemistry of 13 elbaite-schorl tourmaline crystals from the Cruzeiro pegmatite (Minas Gerais, Brazil) was studied with a multi-analytical approach (SREF, EMPA, SIMS, MS). Effective cation radii at the Y and Z sites and site populations were refined by a minimization procedure. The results indicate that the crystals belong to the alkali group. Elbaite crystals are O2−-free at the W and V sites and show OH content at the O2 site (up to 0.2 apfu). Conversely, schorl crystals always show O2− at the W site. The main substitutional mechanism is the dehydroxylation type:

\[^{Y}Fe^{2+}\ +\ ^{Y}Fe^{3+}\ +\ ^{W}O\ {\rightarrow}\ ^{Y}Li\ +\ ^{Y}Al\ +\ ^{W}(OH+F).\]

The T site is characterized by TSi → TAl substitution. <X-O> is linearly correlated with vacancy content in crystals with (OH + F) ≤ 4, whereas it is almost constant in crystals with OH at the O2 position. Along the series, <Y-O> is inversely correlated with YAl. The Z site is almost fully occupied by R3+ (with ZAl largely dominant) and the ZFetotZAl substitution explains the inverse correlation of <Z-O> with ZAl.

In the elbaite compositional range, lattice parameters are functions of <Y-O>, whereas in the schorl range they are essentially functions of <Z-O>. Along the whole elbaite-schorl series, both chemical substitutions and size increase of Y are far larger than those of Z. In spite of this, lattice parameters increase with <Y-O> as much as with <Z-O>. This is due to the role of the [ZO6] polyhedra, which extend along a and c to form the skeleton of the tourmaline structure. Therefore, any change in the size of Z leads to a change in the whole structure.

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