We report here an investigation of amphibole synthesis within the ternary system Ca 2 Mg 5 Si 8 O 22 (OH) 2 -NaCa 2 Mg 4 Al 3 Si 6 O 22 (OH) 2 -Mg 7 Si (sub 8 ) O 22 (OH) 2 (= TR-PG-MC) to define better the limits of solid solution for amphiboles formed along and near the join tremolite-pargasite. Hydrothermal syntheses were conducted in the range of 750-1000 degrees C and 1-6 kbar. Syntheses at 10 mol% compositional intervals along the TR-PG join produced incomplete yields of amphibole, and the resultant amphiboles were found to be associated with varying amounts of accessory clinopyroxene, plagioclase, and gehlenite. Syntheses of end-member pargasite with progressively greater amounts of the MC component produced a very good amphibole yield for a pargasite composition containing 2.5 mol% MC. The persistence of clinopyroxene or gehlenite and the improved yield of pargasitic amphibole with minor addition of the MC component indicate a shift toward MC enrichment for amphiboles made from bulk compositions directly on the TR-PG join. Syntheses within the TR-PG-MC ternary system suggest that the Ca-rich limit of solid solution is a slightly curved field in the TR-PG-MC field. Amphiboles made along this join showed a very systematic change in the (151) and (331) peak spacing with mol% PG, providing a simple technique for deducing the composition of amphiboles made near the tremolite-pargasite join. Electron microprobe analysis confirms that the amphiboles for the most part conform to the "pargasite" substitution. The one exception being amphiboles formed near 80-90 mol% PG compositions, which proved both difficult to synthesize ( approximately 75 wt% amphibole yield) and displayed a small, but significant, excess of Na in their structure. High yields of amphibole could be formed from this same bulk composition with the use of a dilute NaOH solution instead of pure water, suggesting that there was insufficient Na in the starting mixture to allow complete amphibole formation. Structural refinements using X-ray diffraction (XRD) Rietveld refinement confirmed the high Na content for this sample and also revealed a non-linear trend in the unit-cell volume with composition, with a maximum at the 80 mol% PG bulk composition. The difficulty in synthesizing amphiboles near this bulk composition and its unusually high volume suggest that immiscibility in natural hornblendes may initiate with increasing pressure for pargasite-rich bulk compositions.