Abstract

The suitability of boron nitride for use as a crucible material in silicate and oxygen-bearing metal sulfide systems has been investigated. Boron nitride is unsatisfactory for use with many silicate systems because its presence in combination with a source of oxygen establishes the oxygen fugacity at values below that of the assemblage quartz + fayalite + iron, reducing transition metal ions such as Ni2+ and Fe2+ to the metallic state. B2O3, resulting from the oxidation of BN, acts as a flux to promote formation of melt.

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