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The structure of topaz contains chains (parallel to y) of edge-sharing Al-(O,F,OH) octahedra and SiO4 tetrahedra (Fig. 35): four of the six anions around each Al are oxygens shared with the SiO4 tetrahedra, the others being fluorine or hydroxyl ions. In topaz Si-O tetrahedra do not share oxygens with other tetrahedra; it is thus classified as an orthosilicate.

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