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Kyanite has a structure in which the oxygen atoms are arranged in a slightly distorted close-packed cubic array. As in andalusite and sillimanite, there are chains of Al-O octahedra (Al coloured green in Fig. 29) and these are linked together by the remaining Si, Al and O atoms, Si being coordinated by four oxygen atoms, and Al by six oxygen atoms. The Si-O tetrahedra do not share corners with other Si-O tetrahedra, although they may appear to do so because of overlap in projection. The volumes of the unit cell of the three Al2SiO5 polymorphs and their molar volumes are as listed in Table 6, confirming that kyanite has the lowest specific volume and will thus be the polymorph favoured by highest pressure conditions.

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