E. S. Cheney, L. D. Vredenburgh; The role of iron sulfides in the diagenetic formation of iron-poor manganese nodules. Journal of Sedimentary Research ; 38 (4): 1363–1365. doi: https://doi.org/10.1306/74D71B9A-2B21-11D7-8648000102C1865D
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Iron-poor manganese nodules form diagenetically. Under reducing conditions protonodules dissolve; some iron is fixed in sulfide minerals, but manganese migrates up to the oxidized zone and reprecipitates as iron-poor nodules.
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