Many studies have constrained that late-Variscan buckling produced the arcuate geometry of the Ibero-Armorican belt. Nonetheless, debate remains on the associated geodynamic framework. Poorly studied Late Carboniferous intramontane basins offer an excellent framework to decipher the timing and kinematics of the late- to post-Variscan tectonics. Understanding the latter also helps constrain the structural emplacement mode of contemporaneous W-Sn-Nb-Ta-Li mineralisation. In Iberia, the Porto-Sátão syncline is exemplary of such a Late Carboniferous intramontane basin. We present a structural analysis of the syncline, its basement and the associated W-Sn deposits. The regional structure is dictated by the Alcudian angular unconformity, caused by Cadomian tectonics (575-555Ma) and separating tilted Ediacaran and subhorizontal Lower Palaeozoic formations. Superposed Variscan deformation led to F1-F3 folds with steep and gentle plunges, respectively. The late-orogenic D3 fabric is locally affected by post-orogenic F4 kink folds and a S4 crenulation cleavage. W-Sn bearing vein systems occur along granite-hosted cone sheets, or exploit cross-fold joints associated with the F3 and F4 fold generations, revealing a close kinematic relationship between granite-related mineralisation and the late- to post-Variscan deformation style. This structural history is interpreted as a plate-scale geodynamic change from Late Carboniferous N-S (D3) to Early Permian WNW-ESE (D4) convergence.