Concentrates of detrital muscovite were prepared from the Bischofalm Quartzite (late Ordovician) exposed in the Southalpine Carnic Alps, Austria. Two size fractions (150–175 pm and 85-100 μm) from two samples display similarly discordant 40Ar/39Ar age spectra in which apparent ages systematically increase from c. 300 Ma to c. 600 Ma in low-temperature portions of each analysis. Intermediate- and high-temperature increments are characterized by apparent ages of c. 620–645 Ma. Characteristics of the age spectra suggest minor late Palaeozoic, Variscan or combined Variscan/Alpine rejuvenations of argon isotopic systems within detrital grains which originally crystallized within a late Precambrian source terrain. The detrital muscovite ages provide evidence for a Cadomian-age source region for some basement sequences within the Austroalpine/Southalpine sectors of the Eastern Alps. The occurrence of Cadomian-age detritus in the Eastern Alps suggests links with Armorica and other, similarly aged tectonic elements within Alpine chains initiating along northern margins of Gondwana.