Contact metamorphism along widespread dolerite sills and dykes, emplaced at 182 to 183 Ma through the sedimentary host rocks of the Karoo Basin, triggered devolatilization of carbon-rich shales of the Lower Ecca Group. Hornfel samples collected from drill cores that intersect dolerite sills were analyzed for mineral phase equilibria, chemistry and porosity to characterize thermal aureoles at various distances from sill intrusions. Andalusite-chiastolite and cordierite porphyroblasts with biotite and muscovite occur within 10 to 20 m of many intrusive contacts. These metamorphic minerals crystallized when host shales attained maximum temperatures ranging between 450 and 600°C. Scanning electron microscopy imaging confirms that the hornfels are compact and that their metamorphic minerals limit porosity along grain boundaries. In few cases intra-mineral porosity occurs within individual crystals such as calcite, andalusite and cordierite. Disequilibrium metamorphic textures such as irregular grain boundaries, and inclusions in andalusite and cordierite reveal that the elevated temperatures were too short-lived to accomplish complete (re)crystallization. Thermal modeling results are consistent with the observed metamorphic mineral assemblages. Gas leakage calculations along a 7 m and a 47 m thick dolerite sill that intrude toward the top of the Whitehill Formation suggest that methane volumes ranging between 8 to 15 Tcf were generated during the sill emplacement. Methane was likely released into the atmosphere through hydrothermal vent complexes that are well preserved in the western Karoo Basin. If such loss was widespread across the entire basin, the implications for paleo-climate change and preserved shale gas reserves in the Karoo Basin of South Africa would be significant.

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