The formation and evolution of Palaeoarchaean De Kraalen and Witrivier Greenstone Belts (DKGB and WGB) of the Kaapvaal Craton are poorly known. Here we report zircon and rutile in situ U-Pb ages and zircon Hf isotopic data from a variety of supracrustal rocks. The zircon cores from a metamafic amphibole-bearing gneiss from the DKGB give a protolith age of 3 441 ± 5 Ma, whereas the zircon mantle domains give a metamorphic age of 3 211 ± 16 Ma. The 176Hf/177Hft values for all zircon domains give a tight cluster around 0.280596 ± 0.00006 (2 SD).

U-Pb analyses of zircon for an amphibolite intercalated with thin calc-silicate layers from the WGB give a single crystallisation age of 3 230 ± 3 Ma, but the Hf isotope ratios of these zircon grains define two different populations. The first population yields 176Hf/177Hf~3.23 Ga = 0.28064 ± 0.00004, corresponding to εHf~3.23 Ga = 2.4 ± 1.9 (2SD) and Hf model ages between ca. 3.51 to 3.30 Ga. These are Hf isotope characteristics for zircons from a relatively juvenile source extracted from a depleted mantle source ca. 0.28 to 0.07 Ga prior zircon crystallisation. The second population yields 176Hf/177Hf~3.23 Ga = 0.28093 ± 0.00004 with εHf~3.23 Ga = 8.1 ± 1.3 (2SD). These Hf data combined with the 206Pb/207Pb ages lead to isotope ratios that lie above those of Depleted Mantle. The unusually high Hf isotope signature for the cores of the zircons from the WGB amphibolite most likely represent a contribution from an early highly depleted mantle source.

A rutile in situ U-Pb age of 3.085 Ga from a recrystallised quartzite indicate that the rocks from the DKGB experienced slow cooling following the 3.21 Ga metamorphic event or (partial) resetting due to elevated geothermal gradient caused by the ca. 3.1 Ga intrusions of the Vrede Granitiod Suite. The latter interpretation is preferred because ~145 Ma of slow cooling from the amphibolite facies conditions of peak metamorphism to the blocking temperature for mass diffusion of Pb in rutile is unlikely. While the Zr-in-rutile temperature of ca. 710°C at 7 kbar for DKGB most likely records the peak temperature of the ~3.23 to 3.21 Ga event.

The trace element concentrations of the metamorphic rutile grains within the quartzite of the DKGB indicate that the source rock was enriched in Cr. Either due to silification during hydrothermal alteration of the (ultra)mafic country rock or during deposition in an atmosphere that allowed for chromite grains to be part of the sediment.

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