Abstract
Elevated topography is evident across the continental margins of the Atlantic. The Cumberland Peninsula, Baffin Island, formed as the result of rifting along the Labrador–Baffin margins in the late Mesozoic and is dominated by low-relief high-elevation topography. Apatite fission-track (AFT) analysis of the landscape previously concluded that the area has experienced a differential protracted cooling regime since the Devonian; however, defined periods of cooling and the direct causes of exhumation were unresolved. This work combines the original AFT data with 98 apatite new (U–Th)/He (AHe) ages from 16 samples and applies the newly developed ‘broken crystals’ technique to provide a greater number of thermal constraints for thermal history modelling to better constrain the topographic evolution. The spatial distribution of AFT and AHe ages implies that exhumation has been significant toward the SE (Labrador) coastline, and results of thermal modelling outline three notable periods of cooling: in the pre-rift stage (460–200 Ma), from synrift stage to present (120–0 Ma) and within the post-rift stage (30–0 Ma). Pre-rift cooling is interpreted as the result of exhumation of Laurentia and synrift cooling as the result of rift-flank uplift to the SE and differential erosion of landscape, whereas the final post-rift period is probably an artefact of the modelling process. These results suggest that the source of the Cumberland Peninsula's modern-day elevated topography is uplift during rifting in the Cretaceous and the isostatic compensation following continuous Mesozoic and Cenozoic differential erosion. This work highlights how interaction of rift tectonics and isostasy can be the principal source for modern elevated continental margins, and also provides insight into the pre-rift exhumational history of central Laurentia.
Supplementary material: Thermal histories are available at: https://doi.org/10.6084/m9.figshare.c.4528409
The continental margins of the Atlantic exhibit elevated coastal topography reaching c. 3 km in height, yet the source and age of topography remains a contentious issue (Japsen & Chalmers 2000; Nielsen et al. 2009; Green et al. 2018). The margins of Brazil, southern Africa, Norway and Greenland are all characterized by high-elevation low-relief topography, and aspects of the offshore stratigraphy have been interpreted in terms of a fluctuating onshore denudational history (Riis 1996; Evans 1997; Japsen 1998; Chalmers 2000; Burke & Gunnell 2008; Cobbold et al. 2010). Various mechanisms have previously been suggested to explain both the onshore and offshore geology: mantle diapirism (Rohrman & van der Beek 1996), rift-flank uplift (Redfield et al. 2005), tectonic rejuvenation (Ksienzyk et al. 2014), far-field stress changes (Japsen et al. 2014) and isostasy (Medvedev et al. 2008). However, a clear consensus is yet to be established.
Low-temperature thermochronology and thermal history modelling have become vital tools in establishing the onshore denudational and uplift histories of modern passive margins (e.g. Gallagher et al. 1994; Cockburn et al. 2000; Kounov et al. 2009; Wildman et al. 2015), in part owing to a lack of direct geological evidence and difficulties integrating onshore and offshore histories. Thermal histories generated from across several continental margins outline the timing and style of cooling or heating to establish periods of exhumation or burial respectively, helping to infer how a landscape has evolved (Gallagher et al. 1998). Across Greenland and Brazil topography is interpreted to have formed from multiple tectonic uplift events following the end of rifting, inferred from episodic rapid cooling in thermal histories (Japsen et al. 2006, 2012, 2014), whereas protracted cooling, observed in thermal models from Norway and southern Africa, suggests that topography along these margins results from a prolonged denudation across elevated rift flanks (Brown et al. 2000; Hendriks & Andriessen 2002) or ancient topography (Nielsen et al. 2009). These contrasting interpretations illustrate the contentious debate surrounding the evolution of Atlantic continental margins and highlight the key role thermal history modelling plays in establishing the topographic evolution of continental margins.
The Baffin Mountains, along the NE coastline of Baffin Island (Fig. 1), are an example of low-relief landscape at high elevation (c. 2 km) and, as in many other instances from margins across the Atlantic, the source of this topography remains enigmatic. Early geomorphological research from Baffin Island suggested that much of the modern landscape is the result of a peneplain that was uplifted in the late Cenozoic (Cooke 1931; Mercer 1956). However, apatite fission-track data and thermal history models from the Cumberland Peninsula, SE Baffin Island, show no evidence for uplift in the Cenozoic and are interpreted as the result of protracted erosion since the Devonian (McGregor et al. 2013). The present work attempts to better constrain the thermal history from across the Cumberland Peninsula with the addition of 98 single grain apatite (U–Th)/He ages from 16 samples of the original fission-track dataset and, further, utilizing the ‘broken crystals’ approach in one sample to provide greater temporal and thermal resolution (Brown et al. 2013). The resulting spatial data trends and enhanced thermal histories suggest that uplift of the margin occurred during rifting in the late Mesozoic and has since been preserved by isostatic forces, and additional insight into the pre-rift history is also provided.
Geological setting
The geology of the Cumberland Peninsula is dominated by Archean orthogneisses and amphibolites of the Hoare Bay Group and granulites of the Cumberland batholith that amalgamated as part of the ‘Rae Craton Expansion’ (c. 2.0 Ga) (St-Onge et al. 2009). The collision of five Archean terranes led to the metamorphism of the original continental shelf sediments of the Hoare Bay Group (1.88 Ga) (St-Onge et al. 2009) and generated the granitic melt of the Cumberland Batholith, now located across the centre of Baffin Island. Subsequent collision with the Superior Craton to the west, as part of the Trans-Hudson Orogeny (c. 1.8 Ga), combined many early crustal domains to form the supercontinent of Laurentia (Lewry & Collerson 1990; St-Onge et al. 2009). Evidence of intra-cratonic subsidence and uplift of Laurentia during the Paleozoic and Mesozoic is apparent in several localities (Flowers et al. 2012; Ault et al. 2013; Zhang et al. 2012), although it is poorly resolved owing to a lack of preserved geology.
Extension between eastern Canada and western Greenland is believed to have begun in the Late Triassic and continued to the Paleocene (Larsen et al. 2009). The geochemistry of igneous intrusions across both margins and observed fault block rotation in the offshore outline three intense periods of rifting in the late Mesozoic and early Cenozoic: Late Jurassic to Early Cretaceous (150–130 Ma), Mid-Cretaceous (120–100 Ma) and Late Cretaceous to Paleocene (80–64 Ma) (Balkwill 1987; Larsen et al. 2009). Ocean spreading in the region began in the Labrador Sea during the Late Cretaceous and migrated northwards into Baffin Bay in the Paleocene, aided by the c. 700 km long strike-slip Ungava Fault Zone (Funck et al. 2007; Suckro et al. 2013) (Fig. 1). Spreading within Baffin Bay was kinematically reoriented in the Late Paleocene to Early Eocene (from north–south to NNW–SSE) (c. 57–53 Ma), coeval with the Eurekan Orogeny to the north, and ceased altogether in the Late Eocene (c. 34 Ma) (Oakey & Chalmers 2012) (Fig. 1).
Rifting led to significant sedimentary basin development across Baffin Bay and the Davis Strait, with several kilometres of deltaic and marine sediments offshore (Chalmers 2012). Onshore stratigraphic exposure across the Cumberland Peninsula is limited to Cretaceous sands found in half-grabens on Durban, Padloping and Quqalluit islands interpreted as the deposits of a major Cretaceous braided river system (Burden & Langille 1990) (Fig. 1). Subaqueous and subaerial volcanoclastic deposits and lavas overlie these Cretaceous sands, onlapping onto the surrounding basement, and are interpreted as the most westerly extent of the West Greenland Igneous Province (Clarke & Upton 1971) (Fig. 1). Offshore stratigraphy is not well defined, although Cretaceous sands are found just below the seafloor of the NE coastline of the Cumberland Peninsula (MacLean et al. 2014) and c. 1 km of Neogene sediments is present off the shelf (Thiébault et al. 1989; Chalmers 2012). The elevated peneplain across Baffin Island has been proposed to result from uplift in the late Cenozoic, although contemporary studies have suggested that these features may be formed through differential erosion across the landscape during glaciation (Egholm et al. 2017; Strunk et al. 2017).
The discernible lack of Mesozoic and Cenozoic rocks makes it difficult to constrain the onshore evolution of the region. Fortunately, the application of apatite low-temperature thermochronology can contribute to our understanding of the region's history.
Methods
Low-temperature thermochronology
In this study thermal histories are generated by the joint inversion of apatite fission-track (AFT) and apatite (U–Th)/He (AHe) data (Gallagher et al. 1998). AFT utilizes damage trails produced within the crystal lattice of apatite following the fission decay of 238U to establish the age and rate of cooling through the apatite fission-track partial annealing zone (PAZ; 120–60°C). Central ages utilized in this study were determined through the external detector method (Gleadow 1981), and the style of cooling is established by the distribution of horizontal confined fission-track lengths, as residence in the PAZ shortens tracks from their initial size (c. 16.2 µm) producing a length distribution dependent on a sample's thermal history. AHe utilizes the accumulation of 4He in the apatite grains derived from the alpha decay of 238U, 235U and 232Th at temperatures <70°C (Wolf et al. 1998). The concentrations of both 4He and radioactive isotopes are used to determine the time at which the grain was within the helium partial retention zone (HePRZ; 70–40°C) (Wolf et al. 1998; Stockli et al. 2000), providing temporal and thermal constraints on a geological timescale.
From the 20 samples analysed in the initial AFT study (McGregor et al. 2013), 16 were used for whole grain (U–Th)/He analysis and 20 fragmented grains were analysed from one of the youngest AFT samples (Ec8) (Brown et al. 2013). Selecting appropriate apatite grains from metamorphic rocks is difficult because of the high likelihood of 4He-rich inclusions and pitted mineral surfaces, caused by grain boundary interactions at depth (Dempster et al. 2006). Criteria used to ensure that suitable grains were picked included a euhedral or sub-euhedral morphology, a lack of observable mineral inclusions and good optical clarity to ensure the internal structure of the grain could be observed. Analysis was completed at the London Geochronology Centre, where each grain was heated to c. 650°C for 120 s using a 25 W 808 nm diode laser and 4He was measured with a Balzers quadrupole mass spectrometer. Uranium and thorium measurements were completed through acid digestion and isotope dilution with an Agilent 7700x inductively coupled plasma mass spectrometry system.
AHe single-grain age dispersion is common in non-orogenic settings owing to multiple factors: grain size (Reiners & Farley 2001), 4He implantation (Farley et al. 1996), U- and Th-rich inclusions (Vermeesch et al. 2007), implantation (Gautheron et al. 2012) and radiation damage (Shuster et al. 2006; Flowers et al. 2009; Gautheron et al. 2009). In an attempt to improve thermal history model precision, the use of fragmented grains on sample Ec8 was employed. Apatite grains commonly break parallel to the c-axis during mineral separation, producing a grain fragment with a specific portion of the helium diffusion profile and calculated ages are either younger or older than the potential ‘whole grain’ age (Brown et al. 2013). The analysis of >20 fragments of varying lengths from a single rock sample generates a distribution of ages with ‘predictable’ dispersion that provides a greater number of thermal and temporal constraints for thermal history modelling (Beucher et al. 2013).
Thermal modelling
Integrated inverse modelling of AFT and AHe data was completed using the transdimensional Bayesian Markov Chain Monte Carlo (MCMC) within QTQt (Gallagher 2012). This approach samples >200 000 thermal histories, continually assessing the predictions of AFT central age, track distribution and AHe ages against each iteration to ascertain if the prediction has improved and finally producing an ‘expected model’ that is bound by 95% credibility intervals. This ‘expected model’ outlines a single thermal history derived from a wide range of possible outcomes and does not forcibly overinterpret the data in the modelling process, producing a thermal history dependent on the joint inversion of both datasets and the quality of the data. Moreover, this approach also permits the application of c-axis correction on AFT track length data (Donelick et al. 1999), greatly improving modelling accuracy, and the resampling of AHe age error, which allows for a greater degree of freedom while modelling and objectively discounting single AHe ages that are incompatible with the counterpart AFT data.
As mentioned above, radiation damage within apatite grains can influence AHe ages, producing ≤100% dispersion in affected samples. Continuing recoil of the U and Th decay chain can damage the surrounding crystal lattice, creating vacancies that can accommodate 4He diffused above c. 70°C that is then included in analysis, increasing the overall age (Shuster et al. 2006). In an attempt to improve the compatibility of dispersed AHe ages, a radiation damage diffusion model and alternative diffusion parameters are incorporated that treat radiation damage defects similarly to fission tracks during a calculated thermal history (Gautheron et al. 2009). Although this may not account for all dispersion within samples, it has been shown to improve AFT and AHe age predictions in comparison with standard apatite diffusion kinetics (e.g. Cogné et al. 2012; Guillaume et al. 2013; Leprêtre et al. 2015; Wildman et al. 2015; Kasanzu 2017).
Results
Low-temperature thermochronology
Fission-track central ages (extracted from McGregor et al. 2013) range between 177.4 ± 6.8 Ma and 440.9 ± 22.2 Ma and display a trend of younger ages toward the SE margin (Figs 2 and 3b) outlining isochrons dipping to the SE–NW (Fig. 3c). Mean track lengths (MTL) range between 12.09–13.27 µm (uncorrected) and 13.17–14.22 µm (c-axis corrected), with the highest values found across inland and elevated areas, whereas lower MTLs focus around highly glaciated coastal regions. Plots of AFT central ages and MTL against elevation exhibit no obvious trend (Fig. 3a), whereas a positive correlation is apparent between Cl wt% and AFT central age (Fig. 4d) and absent between the kinetic parameter Dpar and AFT central age (Fig. 4a). Of the 22 samples, five provide χ2 values of less than 5%, although dispersion of all samples is <15%, suggesting that low values are probably determined by fewer than 20 grains counted or low track densities.
Whole grain AHe ages range between 0.0 Ma and 3.4 Ga for uncorrected ages and 0.0 Ma and 4.6 Ga for corrected ages (Table 1). Specific removal of ages considered very young (<1 Ma) and those considered very old (>1 Ga) from the dataset produces alternative age ranges; 5.51 and 610.2 Ma (uncorrected) and 8.09 and 690.8 Ma (corrected). Mean sample ages from this altered dataset range between 104.0 and 279.4 Ma (uncorrected) and 123.7 and 329.9 Ma (corrected) and also display a trend of younger ages toward the SE, similar to that of AFT central ages (Figs 2 and 3b). Effective uranium concentration (eU = [U] + 0.235[Th]) against AHe age shows weak to moderate positive correlations in 11 of the 16 whole grain samples, whereas equivalent spherical radius and AHe age show weak to moderate positive correlations in 14 of the 16 samples (Fig. 3d). These trends imply that both radiation damage and grain geometry are dominant controls on whole grain ages and suggest that many of the samples have spent considerable time within the HePRZ (Reiners & Farley 2001; Flowers et al. 2009). Grains with anomalously high ages (>1 Ga) imply that significant quantities of additional 4He have entered the diffusion domain, probably through micro-inclusions or implantation. Very young ages (<1 Ma) can be attributed to the potential accidental selection of zircon instead of apatite or a failure to reach an optimum temperature during 4He extraction. Fragment (‘broken grain’) ages range between 62.6 and 610.1 Ma (uncorrected), and 68.4 and 690.1 Ma (corrected). eU against fragment age also exhibits a weak positive correlation, whereas fragment length against fragment age displays no obvious trend, again suggesting that radiation damage is a principal control on AHe ages.
Sample (mean)* | He (Vol (10−9 cm3)) | U (ppm) | Th (ppm) | Sm (ppm) | eU† (ppm) | Length (µm) | Width (µm) | r'‡ (µm) | Ft§ | Measured age (Ma) | Corrected age¶ (Ma) | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Ec1 (231.2) | a | 0.00 | 14.71 | 25.80 | 41.68 | 20.77 | 152 | 102 | 57.3 | 0.74 | 0.10 ± 0.01** | 0.13 ± 0.01** |
b | 0.13 | 121.15 | 115.73 | 37.08 | 148.35 | 174 | 75 | 46.3 | 0.68 | 5.51 ± 0.28 | 8.09 ± 0.40 | |
c | 11.17 | 48.93 | 16.02 | 76.44 | 52.69 | 203 | 110 | 64.9 | 0.77 | 460.80 ± 23.04 | 597.86 ± 29.89 | |
d | 2.12 | 0.30 | 1.00 | 0.30 | 0.54 | 253 | 134 | 79.5 | 0.81 | 3790.37 ± 189.52** | 4666.69 ± 233.33** | |
e | 3.74 | 59.66 | 10.30 | 134 | 62.08 | 218 | 87 | 54.4 | 0.73 | 227.29 ± 11.36 | 312.49 ± 15.62 | |
EC2 (201.8) | a | 8.75 | 87.58 | 23.09 | 976 | 94.00 | 156 | 88 | 51.6 | 0.71 | 267.41 ± 7.94 | 311.94 ± 9.23 |
b | 3.08 | 59.70 | 4.92 | 1061 | 62.13 | 153 | 66 | 40.9 | 0.64 | 181.06 ± 6.58 | 220.17 ± 7.97 | |
c | 2.55 | 46.07 | 10.97 | 1219 | 50.13 | 174 | 93 | 54.9 | 0.73 | 153.64 ± 5.07 | 178.67 ± 5.88 | |
d | 2.92 | 44.71 | 12.40 | 800 | 48.59 | 144 | 85 | 49.0 | 0.70 | 204.29 ± 7.40 | 242.22 ± 8.76 | |
e | 3.36 | 79.83 | 4.69 | 1020 | 82.17 | 149 | 79 | 46.8 | 0.68 | 202.59 ± 6.67 | 242.87 ± 7.97 | |
Ec5a (144.9) | a | 0.50 | 104 | 466 | 92.00 | 214 | 182 | 95 | 56.5 | 0.74 | 231.88 ± 3.18 | 323.75 ± 4.50 |
b | 0.90 | 26.11 | 4.26 | 35.34 | 27.15 | 243 | 101 | 62.7 | 0.76 | 94.74 ± 0.91 | 124.09 ± 1.19 | |
e | 1.62 | 17.95 | 7.30 | 26.14 | 19.71 | 173 | 110 | 62.6 | 0.76 | 102.61 ± 0.95 | 136.42 ± 1.26 | |
f | 1.46 | 11 320 | 1271 | 100 | 11 619 | 376 | 117 | 75.9 | 0.80 | 0.17 ± 0.00** | 0.21 ± 0.00** | |
h | 4.49 | 41.18 | 8.70 | 46.00 | 43.27 | 360 | 132 | 83.1 | 0.82 | 150.23 ± 1.25 | 183.02 ± 1.51 | |
Ec7 (104.0) | a | 1.09 | 26.72 | 3.86 | 64.05 | 27.71 | 184 | 100 | 59.0 | 0.75 | 112.16 ± 4.05 | 129.08 ± 4.65 |
b | 0.24 | 17.82 | 2.98 | 54.61 | 18.59 | 132 | 78 | 45.3 | 0.67 | 86.79 ± 5.18 | 104.48 ± 6.23 | |
c | 1.46 | 30.77 | 4.55 | 69.82 | 31.92 | 138 | 89 | 50.6 | 0.71 | 142.50 ± 5.03 | 169.79 ± 5.98 | |
d | 0.33 | 21.01 | 2.87 | 46.32 | 21.74 | 127 | 83 | 46.8 | 0.68 | 97.57 ± 5.61 | 116.79 ± 6.71 | |
e | 0.28 | 18.06 | 4.10 | 46.11 | 19.08 | 149 | 77 | 45.9 | 0.68 | 81.14 ± 4.60 | 98.57 ± 5.58 | |
Ec8 (201.3) | b | – | 0.29 | 0.29 | 0.55 | 0.35 | 241 | 118 | 71.1 | 0.79 | – ± –** | – ± –** |
d | 4.66 | 22.38 | 4.65 | 53.00 | 23.54 | 228 | 135 | 78.1 | 0.81 | 235.37 ± 1.88 | 292.22 ± 2.32 | |
f | 3.22 | 28.79 | 10.47 | 101 | 31.37 | 195 | 157 | 84.0 | 0.82 | 206.00 ± 17.00 | 257.00 ± 22.00 | |
g | 0.47 | 9.50 | 3.54 | 44.77 | 10.39 | 193 | 136 | 75.4 | 0.80 | 146.53 ± 1.98 | 185.63 ± 2.50 | |
i | 1.56 | 13.59 | 6.90 | 53.00 | 15.27 | 138 | 120 | 62.7 | 0.76 | 217.14 ± 2.13 | 297.47 ± 2.91 | |
Ec81T (145.9) | a | 0.64 | 13.12 | 4.46 | 40.20 | 14.22 | 197 | 151 | 240.4 | 0.94 | 74.82 ± 0.59 | 80.43 ± 0.64 |
b | 0.33 | 13.06 | 5.41 | 46.72 | 14.39 | 124 | 137 | 194.9 | 0.92 | 92.27 ± 1.11 | 103.65 ± 1.25 | |
c | 0.51 | 9.14 | 4.57 | 46.62 | 10.27 | 173 | 130 | 207.8 | 0.93 | 127.44 ± 1.15 | 138.55 ± 1.25 | |
d | 11.01 | 92.40 | 82.65 | 108.61 | 111.96 | 180 | 165 | 249.7 | 0.94 | 164.58 ± 1.23 | 177.67 ± 1.33 | |
e | 0.70 | 7.48 | 4.62 | 39.92 | 8.62 | 189 | 135 | 219.3 | 0.93 | 156.59 ± 1.25 | 169.31 ± 1.35 | |
f | 0.55 | 10.89 | 2.77 | 33.77 | 11.58 | 174 | 124 | 201.0 | 0.93 | 124.59 ± 1.21 | 135.56 ± 1.31 | |
h | 0.50 | 12.63 | 4.33 | 78.07 | 13.74 | 175 | 138 | 218.2 | 0.93 | 79.67 ± 0.77 | 86.38 ± 0.84 | |
i | 0.79 | 11.98 | 4.22 | 53.45 | 13.03 | 239 | 145 | 245.3 | 0.94 | 105.27 ± 0.93 | 112.56 ± 1.00 | |
j | 0.27 | 9.18 | 5.53 | 50.13 | 10.55 | 169 | 119 | 193.6 | 0.92 | 62.61 ± 0.75 | 68.44 ± 0.82 | |
k | 0.31 | 18.26 | 5.25 | 33.38 | 19.53 | 132 | 97 | 156.1 | 0.90 | 113.52 ± 1.43 | 126.84 ± 1.60 | |
l | 0.66 | 23.60 | 5.37 | 79.80 | 24.96 | 178 | 118 | 195.0 | 0.92 | 112.37 ± 1.07 | 122.42 ± 1.17 | |
m | 0.21 | 11.68 | 5.45 | 49.51 | 13.02 | 129 | 109 | 168.7 | 0.91 | 66.65 ± 1.03 | 74.31 ± 1.15 | |
n | 0.24 | 14.02 | 4.28 | 59.09 | 15.10 | 113 | 115 | 168.0 | 0.91 | 91.91 ± 1.34 | 103.94 ± 1.51 | |
o | 0.35 | 9.10 | 6.19 | 53.46 | 10.62 | 103 | 139 | 182.7 | 0.92 | 131.76 ± 1.51 | 160.78 ± 1.84 | |
p | 2.92 | 38.62 | 5.39 | 70.18 | 39.97 | 176 | 122 | 199.2 | 0.92 | 197.95 ± 1.56 | 215.20 ± 1.69 | |
q | 1.38 | 14.50 | 3.59 | 55.98 | 15.41 | 175 | 201 | 281.8 | 0.95 | 166.88 ± 1.28 | 181.36 ± 1.39 | |
r | 1.02 | 84.35 | 13.68 | 71.00 | 87.65 | 134 | 99 | 159.8 | 0.91 | 90.51 ± 0.79 | 100.85 ± 0.88 | |
s | 0.25 | 6.05 | 3.13 | 12.26 | 6.80 | 123 | 99 | 155.6 | 0.90 | 77.43 ± 1.05 | 86.99 ± 1.18 | |
t | 1.85 | 24.48 | 3.47 | 69.66 | 25.38 | 127 | 76 | 128.5 | 0.88 | 610.17 ± 6.18 | 690.08 ± 6.94 | |
u | 1.74 | 17.52 | 3.85 | 84.80 | 18.52 | 165 | 120 | 194.3 | 0.92 | 271.03 ± 2.01 | 295.59 ± 2.19 | |
Ec12 (129.1) | a | 3.51 | 56.00 | 30.66 | 812 | 64.00 | 214 | 105 | 63.2 | 0.76 | 101.63 ± 0.87 | 133.65 ± 1.14 |
b | 1.71 | 10.45 | 19.77 | 586 | 15.80 | 182 | 106 | 61.6 | 0.76 | 155.37 ± 1.38 | 209.08 ± 1.85 | |
d | 5.83 | 5.19 | 1.93 | 3.09 | 5.65 | 231 | 80 | 51.1 | 0.71 | 0.83 ± 1.76** | 1.16 ± 2.46** | |
e | 5.14 | 17.97 | 59.00 | 440 | 32.27 | 203 | 113 | 66.3 | 0.78 | 130.31 ± 1.03 | 172.28 ± 1.37 | |
Ec13 (220.3) | a | 3.25 | 17.10 | 3.25 | 511 | 18.48 | 218 | 113 | 67.3 | 0.78 | 210.66 ± 1.87 | 270.67 ± 2.39 |
b | 5.24 | 19.30 | 2.08 | 912 | 20.89 | 224 | 126 | 73.8 | 0.80 | 278.20 ± 2.51 | 348.96 ± 3.13 | |
c | 2.65 | 29.85 | 1.56 | 989 | 31.41 | 186 | 103 | 60.5 | 0.75 | 187.63 ± 1.74 | 248.91 ± 2.29 | |
d | 1.56 | 54.00 | 9.80 | 1433 | 58.00 | 137 | 76 | 44.6 | 0.67 | 202.17 ± 2.04 | 301.51 ± 3.01 | |
e | 2.96 | 29.14 | 4.51 | 809 | 31.18 | 181 | 86 | 52.1 | 0.72 | 222.69 ± 1.96 | 309.52 ± 2.71 | |
EC14 (279.5) | a | 0.88 | 23.34 | 5.92 | 685 | 25.56 | 177 | 64 | 40.7 | 0.64 | 208.00 ± 10.00 | 255.00 ± 12.00 |
b | 2.64 | 21.37 | 1.31 | 543 | 22.33 | 163 | 86 | 51.3 | 0.71 | 418.00 ± 19.00 | 495.00 ± 23.00 | |
c | 2.56 | 22.38 | 4.10 | 667 | 24.15 | 191 | 108 | 63.1 | 0.76 | 238.88 ± 8.87 | 272.00 ± 10.00 | |
d | 3.75 | 25.01 | 2.12 | 563 | 26.19 | 194 | 114 | 66.0 | 0.77 | 273.59 ± 9.98 | 309.00 ± 11.00 | |
e | 1.80 | 27.77 | 2.46 | 587 | 29.05 | 161 | 76 | 46.0 | 0.68 | 258.82 ± 9.68 | 309.00 ± 12.00 | |
Ec16 (250.3) | b | 48.59 | 47.48 | 1.60 | 553 | 49.00 | 353 | 166 | 100.8 | 0.85 | 510.55 ± 3.99 | 596.45 ± 4.72 |
d | 0.00 | 0.06 | 1.57 | 3.32 | 0.43 | 115 | 62 | 36.6 | 0.60 | 35.41 ± 50.08 | 65.57 ± 92.74 | |
g | 2.21 | 18.52 | 0.61 | 264 | 18.98 | 189 | 76 | 47.5 | 0.69 | 290.60 ± 2.83 | 415.81 ± 4.00 | |
h | 2.09 | 67.00 | 2.20 | 615 | 68.00 | 199 | 83 | 51.5 | 0.71 | 257.94 ± 2.65 | 358.14 ± 3.65 | |
b | 1.93 | 48.70 | 3.65 | 429 | 50.08 | 158 | 102 | 57.8 | 0.74 | 157.08 ± 1.23 | 213.31 ± 1.66 | |
EC17 (234.5) | a | 1.40 | 13.81 | 7.31 | 653 | 16.31 | 169 | 103 | 59.3 | 0.75 | 194.85 ± 8.37 | 222.79 ± 9.57 |
b | 1.21 | 20.69 | 0.85 | 749 | 21.80 | 186 | 99 | 58.4 | 0.75 | 182.65 ± 6.97 | 211.08 ± 8.03 | |
c | 0.97 | 18.76 | 1.78 | 912 | 20.28 | 167 | 67 | 41.7 | 0.65 | 277.00 ± 18.00 | 336.00 ± 21.00 | |
d | 6.96 | 25.48 | 1.67 | 746 | 26.77 | 136 | 64 | 38.7 | 0.62 | 256.19 ± 8.22 | 2.86 ± 0.09 | |
e | 0.61 | 12.65 | 1.40 | 618 | 13.73 | 179 | 70 | 43.7 | 0.66 | 262.00 ± 21.00 | 316.00 ± 25.00 | |
Ec18 (222.4) | c | 0.00 | 0.98 | 4.15 | 8.77 | 1.95 | 119 | 100 | 52.8 | 0.72 | 0.62 ± 3.41** | 0.00 ± 0.00** |
e | 0.00 | 31.04 | 30.06 | 2.17 | 38.11 | 180 | 140 | 75.6 | 0.80 | 0.52 ± 0.20** | 0.65 ± 0.25** | |
f | 1.41 | 49.00 | 29.23 | 813 | 57.00 | 151 | 74 | 44.6 | 0.67 | 195.42 ± 1.99 | 292.23 ± 2.96 | |
g | – | 1.80 | 1.57 | 6.81 | 2.16 | 197 | 83 | 51.4 | 0.71 | 0.39 ± 0.14** | – ± –** | |
i | 14.65 | 21.30 | 14.73 | 415 | 25.27 | 272 | 200 | 109.7 | 0.86 | 249.32 ± 2.09 | 292.82 ± 2.44 | |
Ec19 (211.7) | a | 5.00 | 24.39 | 12.21 | 590 | 27.97 | 198 | 126 | 139.3 | 0.89 | 196.73 ± 1.27 | 221.91 ± 1.43 |
b | 9.06 | 43.85 | 6.07 | 774 | 46.21 | 216 | 126 | 136.8 | 0.89 | 232.45 ± 1.64 | 261.69 ± 1.84 | |
c | 9.83 | 23.25 | 11.65 | 720 | 26.85 | 289 | 169 | 98.3 | 0.85 | 214.61 ± 6.00 | 259.21 ± 7.23 | |
d | 1.60 | 19.41 | 7.85 | 667 | 22.07 | 216 | 80 | 50.8 | 0.71 | 204.47 ± 9.06 | 231.00 ± 10.00 | |
e | 8.21 | 46.56 | 9.80 | 968 | 50.03 | 230 | 128 | 75.1 | 0.80 | 210.32 ± 5.92 | 237.28 ± 6.67 | |
Ec20 (212.7) | 16 | 6.48 | 48.00 | 30.92 | 181.0 | 55.00 | 211 | 121 | 70.7 | 0.79 | 277.18 ± 2.42 | 353.49 ± 3.07 |
27 | 1.04 | 39.23 | 10.92 | 26.9 | 41.79 | 137 | 89 | 50.4 | 0.71 | 52.71 ± 0.54 | 75.88 ± 0.78 | |
32 | 17.98 | 67.00 | 458 | 43.5 | 175 | 201 | 107 | 63.3 | 0.77 | 326.62 ± 2.91 | 440.30 ± 3.88 | |
43 | 3.55 | 29.72 | 3.21 | 32.1 | 30.47 | 237 | 112 | 67.8 | 0.78 | 249.90 ± 2.43 | 319.23 ± 3.08 | |
45 | 2.52 | 41.17 | 4.31 | 16.3 | 42.18 | 182 | 109 | 62.9 | 0.76 | 156.92 ± 1.52 | 206.65 ± 2.00 | |
Ec21 (189.7) | a | 10.24 | 25.60 | 0.16 | 405 | 26.13 | 327 | 137 | 85.0 | 0.82 | 141.41 ± 1.08 | 171.35 ± 1.31 |
b | 23.87 | 22.82 | 1.97 | 460 | 23.84 | 510 | 179 | 114.1 | 0.87 | 226.91 ± 1.72 | 260.83 ± 1.97 | |
c | 0.00 | 19.37 | 8.64 | 8.9 | 21.41 | 266 | 129 | 78.0 | 0.81 | 0.30 ± 5.70** | 0.40 ± 7.10** | |
f | 6.90 | 25.64 | 2.16 | 426 | 26.66 | 380 | 222 | 128.7 | 0.88 | 179.31 ± 1.37 | 203.67 ± 1.56 | |
g | 3.56 | 46.38 | 6.77 | 478 | 48.55 | 380 | 222 | 128.7 | 0.88 | 211.11 ± 1.70 | 239.77 ± 1.93 | |
Ec22 (195.4) | a | 8.12 | 24.11 | 1.31 | 122 | 24.57 | 305 | 166 | 97.8 | 0.85 | 214.38 ± 1.47 | 253.49 ± 1.73 |
e | 2.36 | 22.18 | 1.00 | 135 | 22.57 | 238 | 113 | 68.3 | 0.78 | 130.04 ± 1.18 | 166.22 ± 1.50 | |
f | 4.69 | 28.40 | 2.21 | 143 | 29.09 | 263 | 168 | 95.5 | 0.84 | 163.32 ± 1.28 | 194.95 ± 1.52 | |
g | 2.78 | 37.51 | 14.44 | 156 | 41.09 | 180 | 79 | 48.7 | 0.70 | 297.36 ± 2.27 | 423.86 ± 3.21 | |
h | 4.05 | 40.55 | 15.73 | 85.6 | 44.35 | 183 | 146 | 78.3 | 0.81 | 172.05 ± 1.19 | 217.91 ± 1.50 | |
Ec23 (194.4) | a | 3.00 | 42.94 | 2.50 | 277 | 43.86 | 155 | 106 | 59.1 | 0.75 | 216.93 ± 1.76 | 292.90 ± 2.36 |
b | 11.63 | 44.20 | 1.24 | 352 | 44.91 | 273 | 178 | 100.5 | 0.85 | 261.91 ± 1.86 | 309.35 ± 2.19 | |
c | 2.51 | 53.99 | 2.57 | 480 | 55.17 | 182 | 111 | 63.9 | 0.77 | 156.46 ± 1.25 | 205.14 ± 1.63 | |
d | 0.00 | 0.94 | 1.09 | 0.41 | 1.19 | 145 | 99 | 55.3 | 0.73 | – ± –** | – ± –** | |
e | 2.37 | 38.34 | 3.72 | 240 | 39.50 | 188 | 101 | 59.6 | 0.75 | 142.44 ± 1.11 | 189.98 ± 1.48 |
Sample (mean)* | He (Vol (10−9 cm3)) | U (ppm) | Th (ppm) | Sm (ppm) | eU† (ppm) | Length (µm) | Width (µm) | r'‡ (µm) | Ft§ | Measured age (Ma) | Corrected age¶ (Ma) | |
---|---|---|---|---|---|---|---|---|---|---|---|---|
Ec1 (231.2) | a | 0.00 | 14.71 | 25.80 | 41.68 | 20.77 | 152 | 102 | 57.3 | 0.74 | 0.10 ± 0.01** | 0.13 ± 0.01** |
b | 0.13 | 121.15 | 115.73 | 37.08 | 148.35 | 174 | 75 | 46.3 | 0.68 | 5.51 ± 0.28 | 8.09 ± 0.40 | |
c | 11.17 | 48.93 | 16.02 | 76.44 | 52.69 | 203 | 110 | 64.9 | 0.77 | 460.80 ± 23.04 | 597.86 ± 29.89 | |
d | 2.12 | 0.30 | 1.00 | 0.30 | 0.54 | 253 | 134 | 79.5 | 0.81 | 3790.37 ± 189.52** | 4666.69 ± 233.33** | |
e | 3.74 | 59.66 | 10.30 | 134 | 62.08 | 218 | 87 | 54.4 | 0.73 | 227.29 ± 11.36 | 312.49 ± 15.62 | |
EC2 (201.8) | a | 8.75 | 87.58 | 23.09 | 976 | 94.00 | 156 | 88 | 51.6 | 0.71 | 267.41 ± 7.94 | 311.94 ± 9.23 |
b | 3.08 | 59.70 | 4.92 | 1061 | 62.13 | 153 | 66 | 40.9 | 0.64 | 181.06 ± 6.58 | 220.17 ± 7.97 | |
c | 2.55 | 46.07 | 10.97 | 1219 | 50.13 | 174 | 93 | 54.9 | 0.73 | 153.64 ± 5.07 | 178.67 ± 5.88 | |
d | 2.92 | 44.71 | 12.40 | 800 | 48.59 | 144 | 85 | 49.0 | 0.70 | 204.29 ± 7.40 | 242.22 ± 8.76 | |
e | 3.36 | 79.83 | 4.69 | 1020 | 82.17 | 149 | 79 | 46.8 | 0.68 | 202.59 ± 6.67 | 242.87 ± 7.97 | |
Ec5a (144.9) | a | 0.50 | 104 | 466 | 92.00 | 214 | 182 | 95 | 56.5 | 0.74 | 231.88 ± 3.18 | 323.75 ± 4.50 |
b | 0.90 | 26.11 | 4.26 | 35.34 | 27.15 | 243 | 101 | 62.7 | 0.76 | 94.74 ± 0.91 | 124.09 ± 1.19 | |
e | 1.62 | 17.95 | 7.30 | 26.14 | 19.71 | 173 | 110 | 62.6 | 0.76 | 102.61 ± 0.95 | 136.42 ± 1.26 | |
f | 1.46 | 11 320 | 1271 | 100 | 11 619 | 376 | 117 | 75.9 | 0.80 | 0.17 ± 0.00** | 0.21 ± 0.00** | |
h | 4.49 | 41.18 | 8.70 | 46.00 | 43.27 | 360 | 132 | 83.1 | 0.82 | 150.23 ± 1.25 | 183.02 ± 1.51 | |
Ec7 (104.0) | a | 1.09 | 26.72 | 3.86 | 64.05 | 27.71 | 184 | 100 | 59.0 | 0.75 | 112.16 ± 4.05 | 129.08 ± 4.65 |
b | 0.24 | 17.82 | 2.98 | 54.61 | 18.59 | 132 | 78 | 45.3 | 0.67 | 86.79 ± 5.18 | 104.48 ± 6.23 | |
c | 1.46 | 30.77 | 4.55 | 69.82 | 31.92 | 138 | 89 | 50.6 | 0.71 | 142.50 ± 5.03 | 169.79 ± 5.98 | |
d | 0.33 | 21.01 | 2.87 | 46.32 | 21.74 | 127 | 83 | 46.8 | 0.68 | 97.57 ± 5.61 | 116.79 ± 6.71 | |
e | 0.28 | 18.06 | 4.10 | 46.11 | 19.08 | 149 | 77 | 45.9 | 0.68 | 81.14 ± 4.60 | 98.57 ± 5.58 | |
Ec8 (201.3) | b | – | 0.29 | 0.29 | 0.55 | 0.35 | 241 | 118 | 71.1 | 0.79 | – ± –** | – ± –** |
d | 4.66 | 22.38 | 4.65 | 53.00 | 23.54 | 228 | 135 | 78.1 | 0.81 | 235.37 ± 1.88 | 292.22 ± 2.32 | |
f | 3.22 | 28.79 | 10.47 | 101 | 31.37 | 195 | 157 | 84.0 | 0.82 | 206.00 ± 17.00 | 257.00 ± 22.00 | |
g | 0.47 | 9.50 | 3.54 | 44.77 | 10.39 | 193 | 136 | 75.4 | 0.80 | 146.53 ± 1.98 | 185.63 ± 2.50 | |
i | 1.56 | 13.59 | 6.90 | 53.00 | 15.27 | 138 | 120 | 62.7 | 0.76 | 217.14 ± 2.13 | 297.47 ± 2.91 | |
Ec81T (145.9) | a | 0.64 | 13.12 | 4.46 | 40.20 | 14.22 | 197 | 151 | 240.4 | 0.94 | 74.82 ± 0.59 | 80.43 ± 0.64 |
b | 0.33 | 13.06 | 5.41 | 46.72 | 14.39 | 124 | 137 | 194.9 | 0.92 | 92.27 ± 1.11 | 103.65 ± 1.25 | |
c | 0.51 | 9.14 | 4.57 | 46.62 | 10.27 | 173 | 130 | 207.8 | 0.93 | 127.44 ± 1.15 | 138.55 ± 1.25 | |
d | 11.01 | 92.40 | 82.65 | 108.61 | 111.96 | 180 | 165 | 249.7 | 0.94 | 164.58 ± 1.23 | 177.67 ± 1.33 | |
e | 0.70 | 7.48 | 4.62 | 39.92 | 8.62 | 189 | 135 | 219.3 | 0.93 | 156.59 ± 1.25 | 169.31 ± 1.35 | |
f | 0.55 | 10.89 | 2.77 | 33.77 | 11.58 | 174 | 124 | 201.0 | 0.93 | 124.59 ± 1.21 | 135.56 ± 1.31 | |
h | 0.50 | 12.63 | 4.33 | 78.07 | 13.74 | 175 | 138 | 218.2 | 0.93 | 79.67 ± 0.77 | 86.38 ± 0.84 | |
i | 0.79 | 11.98 | 4.22 | 53.45 | 13.03 | 239 | 145 | 245.3 | 0.94 | 105.27 ± 0.93 | 112.56 ± 1.00 | |
j | 0.27 | 9.18 | 5.53 | 50.13 | 10.55 | 169 | 119 | 193.6 | 0.92 | 62.61 ± 0.75 | 68.44 ± 0.82 | |
k | 0.31 | 18.26 | 5.25 | 33.38 | 19.53 | 132 | 97 | 156.1 | 0.90 | 113.52 ± 1.43 | 126.84 ± 1.60 | |
l | 0.66 | 23.60 | 5.37 | 79.80 | 24.96 | 178 | 118 | 195.0 | 0.92 | 112.37 ± 1.07 | 122.42 ± 1.17 | |
m | 0.21 | 11.68 | 5.45 | 49.51 | 13.02 | 129 | 109 | 168.7 | 0.91 | 66.65 ± 1.03 | 74.31 ± 1.15 | |
n | 0.24 | 14.02 | 4.28 | 59.09 | 15.10 | 113 | 115 | 168.0 | 0.91 | 91.91 ± 1.34 | 103.94 ± 1.51 | |
o | 0.35 | 9.10 | 6.19 | 53.46 | 10.62 | 103 | 139 | 182.7 | 0.92 | 131.76 ± 1.51 | 160.78 ± 1.84 | |
p | 2.92 | 38.62 | 5.39 | 70.18 | 39.97 | 176 | 122 | 199.2 | 0.92 | 197.95 ± 1.56 | 215.20 ± 1.69 | |
q | 1.38 | 14.50 | 3.59 | 55.98 | 15.41 | 175 | 201 | 281.8 | 0.95 | 166.88 ± 1.28 | 181.36 ± 1.39 | |
r | 1.02 | 84.35 | 13.68 | 71.00 | 87.65 | 134 | 99 | 159.8 | 0.91 | 90.51 ± 0.79 | 100.85 ± 0.88 | |
s | 0.25 | 6.05 | 3.13 | 12.26 | 6.80 | 123 | 99 | 155.6 | 0.90 | 77.43 ± 1.05 | 86.99 ± 1.18 | |
t | 1.85 | 24.48 | 3.47 | 69.66 | 25.38 | 127 | 76 | 128.5 | 0.88 | 610.17 ± 6.18 | 690.08 ± 6.94 | |
u | 1.74 | 17.52 | 3.85 | 84.80 | 18.52 | 165 | 120 | 194.3 | 0.92 | 271.03 ± 2.01 | 295.59 ± 2.19 | |
Ec12 (129.1) | a | 3.51 | 56.00 | 30.66 | 812 | 64.00 | 214 | 105 | 63.2 | 0.76 | 101.63 ± 0.87 | 133.65 ± 1.14 |
b | 1.71 | 10.45 | 19.77 | 586 | 15.80 | 182 | 106 | 61.6 | 0.76 | 155.37 ± 1.38 | 209.08 ± 1.85 | |
d | 5.83 | 5.19 | 1.93 | 3.09 | 5.65 | 231 | 80 | 51.1 | 0.71 | 0.83 ± 1.76** | 1.16 ± 2.46** | |
e | 5.14 | 17.97 | 59.00 | 440 | 32.27 | 203 | 113 | 66.3 | 0.78 | 130.31 ± 1.03 | 172.28 ± 1.37 | |
Ec13 (220.3) | a | 3.25 | 17.10 | 3.25 | 511 | 18.48 | 218 | 113 | 67.3 | 0.78 | 210.66 ± 1.87 | 270.67 ± 2.39 |
b | 5.24 | 19.30 | 2.08 | 912 | 20.89 | 224 | 126 | 73.8 | 0.80 | 278.20 ± 2.51 | 348.96 ± 3.13 | |
c | 2.65 | 29.85 | 1.56 | 989 | 31.41 | 186 | 103 | 60.5 | 0.75 | 187.63 ± 1.74 | 248.91 ± 2.29 | |
d | 1.56 | 54.00 | 9.80 | 1433 | 58.00 | 137 | 76 | 44.6 | 0.67 | 202.17 ± 2.04 | 301.51 ± 3.01 | |
e | 2.96 | 29.14 | 4.51 | 809 | 31.18 | 181 | 86 | 52.1 | 0.72 | 222.69 ± 1.96 | 309.52 ± 2.71 | |
EC14 (279.5) | a | 0.88 | 23.34 | 5.92 | 685 | 25.56 | 177 | 64 | 40.7 | 0.64 | 208.00 ± 10.00 | 255.00 ± 12.00 |
b | 2.64 | 21.37 | 1.31 | 543 | 22.33 | 163 | 86 | 51.3 | 0.71 | 418.00 ± 19.00 | 495.00 ± 23.00 | |
c | 2.56 | 22.38 | 4.10 | 667 | 24.15 | 191 | 108 | 63.1 | 0.76 | 238.88 ± 8.87 | 272.00 ± 10.00 | |
d | 3.75 | 25.01 | 2.12 | 563 | 26.19 | 194 | 114 | 66.0 | 0.77 | 273.59 ± 9.98 | 309.00 ± 11.00 | |
e | 1.80 | 27.77 | 2.46 | 587 | 29.05 | 161 | 76 | 46.0 | 0.68 | 258.82 ± 9.68 | 309.00 ± 12.00 | |
Ec16 (250.3) | b | 48.59 | 47.48 | 1.60 | 553 | 49.00 | 353 | 166 | 100.8 | 0.85 | 510.55 ± 3.99 | 596.45 ± 4.72 |
d | 0.00 | 0.06 | 1.57 | 3.32 | 0.43 | 115 | 62 | 36.6 | 0.60 | 35.41 ± 50.08 | 65.57 ± 92.74 | |
g | 2.21 | 18.52 | 0.61 | 264 | 18.98 | 189 | 76 | 47.5 | 0.69 | 290.60 ± 2.83 | 415.81 ± 4.00 | |
h | 2.09 | 67.00 | 2.20 | 615 | 68.00 | 199 | 83 | 51.5 | 0.71 | 257.94 ± 2.65 | 358.14 ± 3.65 | |
b | 1.93 | 48.70 | 3.65 | 429 | 50.08 | 158 | 102 | 57.8 | 0.74 | 157.08 ± 1.23 | 213.31 ± 1.66 | |
EC17 (234.5) | a | 1.40 | 13.81 | 7.31 | 653 | 16.31 | 169 | 103 | 59.3 | 0.75 | 194.85 ± 8.37 | 222.79 ± 9.57 |
b | 1.21 | 20.69 | 0.85 | 749 | 21.80 | 186 | 99 | 58.4 | 0.75 | 182.65 ± 6.97 | 211.08 ± 8.03 | |
c | 0.97 | 18.76 | 1.78 | 912 | 20.28 | 167 | 67 | 41.7 | 0.65 | 277.00 ± 18.00 | 336.00 ± 21.00 | |
d | 6.96 | 25.48 | 1.67 | 746 | 26.77 | 136 | 64 | 38.7 | 0.62 | 256.19 ± 8.22 | 2.86 ± 0.09 | |
e | 0.61 | 12.65 | 1.40 | 618 | 13.73 | 179 | 70 | 43.7 | 0.66 | 262.00 ± 21.00 | 316.00 ± 25.00 | |
Ec18 (222.4) | c | 0.00 | 0.98 | 4.15 | 8.77 | 1.95 | 119 | 100 | 52.8 | 0.72 | 0.62 ± 3.41** | 0.00 ± 0.00** |
e | 0.00 | 31.04 | 30.06 | 2.17 | 38.11 | 180 | 140 | 75.6 | 0.80 | 0.52 ± 0.20** | 0.65 ± 0.25** | |
f | 1.41 | 49.00 | 29.23 | 813 | 57.00 | 151 | 74 | 44.6 | 0.67 | 195.42 ± 1.99 | 292.23 ± 2.96 | |
g | – | 1.80 | 1.57 | 6.81 | 2.16 | 197 | 83 | 51.4 | 0.71 | 0.39 ± 0.14** | – ± –** | |
i | 14.65 | 21.30 | 14.73 | 415 | 25.27 | 272 | 200 | 109.7 | 0.86 | 249.32 ± 2.09 | 292.82 ± 2.44 | |
Ec19 (211.7) | a | 5.00 | 24.39 | 12.21 | 590 | 27.97 | 198 | 126 | 139.3 | 0.89 | 196.73 ± 1.27 | 221.91 ± 1.43 |
b | 9.06 | 43.85 | 6.07 | 774 | 46.21 | 216 | 126 | 136.8 | 0.89 | 232.45 ± 1.64 | 261.69 ± 1.84 | |
c | 9.83 | 23.25 | 11.65 | 720 | 26.85 | 289 | 169 | 98.3 | 0.85 | 214.61 ± 6.00 | 259.21 ± 7.23 | |
d | 1.60 | 19.41 | 7.85 | 667 | 22.07 | 216 | 80 | 50.8 | 0.71 | 204.47 ± 9.06 | 231.00 ± 10.00 | |
e | 8.21 | 46.56 | 9.80 | 968 | 50.03 | 230 | 128 | 75.1 | 0.80 | 210.32 ± 5.92 | 237.28 ± 6.67 | |
Ec20 (212.7) | 16 | 6.48 | 48.00 | 30.92 | 181.0 | 55.00 | 211 | 121 | 70.7 | 0.79 | 277.18 ± 2.42 | 353.49 ± 3.07 |
27 | 1.04 | 39.23 | 10.92 | 26.9 | 41.79 | 137 | 89 | 50.4 | 0.71 | 52.71 ± 0.54 | 75.88 ± 0.78 | |
32 | 17.98 | 67.00 | 458 | 43.5 | 175 | 201 | 107 | 63.3 | 0.77 | 326.62 ± 2.91 | 440.30 ± 3.88 | |
43 | 3.55 | 29.72 | 3.21 | 32.1 | 30.47 | 237 | 112 | 67.8 | 0.78 | 249.90 ± 2.43 | 319.23 ± 3.08 | |
45 | 2.52 | 41.17 | 4.31 | 16.3 | 42.18 | 182 | 109 | 62.9 | 0.76 | 156.92 ± 1.52 | 206.65 ± 2.00 | |
Ec21 (189.7) | a | 10.24 | 25.60 | 0.16 | 405 | 26.13 | 327 | 137 | 85.0 | 0.82 | 141.41 ± 1.08 | 171.35 ± 1.31 |
b | 23.87 | 22.82 | 1.97 | 460 | 23.84 | 510 | 179 | 114.1 | 0.87 | 226.91 ± 1.72 | 260.83 ± 1.97 | |
c | 0.00 | 19.37 | 8.64 | 8.9 | 21.41 | 266 | 129 | 78.0 | 0.81 | 0.30 ± 5.70** | 0.40 ± 7.10** | |
f | 6.90 | 25.64 | 2.16 | 426 | 26.66 | 380 | 222 | 128.7 | 0.88 | 179.31 ± 1.37 | 203.67 ± 1.56 | |
g | 3.56 | 46.38 | 6.77 | 478 | 48.55 | 380 | 222 | 128.7 | 0.88 | 211.11 ± 1.70 | 239.77 ± 1.93 | |
Ec22 (195.4) | a | 8.12 | 24.11 | 1.31 | 122 | 24.57 | 305 | 166 | 97.8 | 0.85 | 214.38 ± 1.47 | 253.49 ± 1.73 |
e | 2.36 | 22.18 | 1.00 | 135 | 22.57 | 238 | 113 | 68.3 | 0.78 | 130.04 ± 1.18 | 166.22 ± 1.50 | |
f | 4.69 | 28.40 | 2.21 | 143 | 29.09 | 263 | 168 | 95.5 | 0.84 | 163.32 ± 1.28 | 194.95 ± 1.52 | |
g | 2.78 | 37.51 | 14.44 | 156 | 41.09 | 180 | 79 | 48.7 | 0.70 | 297.36 ± 2.27 | 423.86 ± 3.21 | |
h | 4.05 | 40.55 | 15.73 | 85.6 | 44.35 | 183 | 146 | 78.3 | 0.81 | 172.05 ± 1.19 | 217.91 ± 1.50 | |
Ec23 (194.4) | a | 3.00 | 42.94 | 2.50 | 277 | 43.86 | 155 | 106 | 59.1 | 0.75 | 216.93 ± 1.76 | 292.90 ± 2.36 |
b | 11.63 | 44.20 | 1.24 | 352 | 44.91 | 273 | 178 | 100.5 | 0.85 | 261.91 ± 1.86 | 309.35 ± 2.19 | |
c | 2.51 | 53.99 | 2.57 | 480 | 55.17 | 182 | 111 | 63.9 | 0.77 | 156.46 ± 1.25 | 205.14 ± 1.63 | |
d | 0.00 | 0.94 | 1.09 | 0.41 | 1.19 | 145 | 99 | 55.3 | 0.73 | – ± –** | – ± –** | |
e | 2.37 | 38.34 | 3.72 | 240 | 39.50 | 188 | 101 | 59.6 | 0.75 | 142.44 ± 1.11 | 189.98 ± 1.48 |
Mean is the arithmetic mean age for each sample calculated from ages given in the two rightmost columns, except that those with ** represent grain ages that have been excluded for being either <1 Ma or >1 Ga.
eU = [U] + 0.235[Th].
r' is the spherical equivalent radius.
Ft is the calculated correction factor from Farley et al. (1996).
¶Corrected age is calculated from Measured Age/Ft.
Examination of both the AFT and AHe data reveals an overlapping of age ranges across several samples, reflecting the extent of dispersion in the data, although AFT central age against mean AHe age does exhibit a moderate positive correlation, suggesting some compatibility between the two systems. Notably, dispersion of AHe ages does display a weak positive correlation against AFT central age, implying that older AFT central ages may yield wider dispersion in the (U–Th)/He system, conceivably owing to thermal histories with extended periods of time within the HePRZ.
Thermal modelling
Thermal histories generated from across the study area exhibit both linear protracted cooling and a variety of cooling episodes stretching from the late Paleozoic to Late Cenozoic. The study area is divided into three segments (NW, central and SE) and thermal histories can be found in Figure 4 and the supplementary material.
In the NW segment, thermal histories from across Qikiqtarjuaq and the coastline exhibit accelerated cooling from the Cretaceous to present in Ec1, Ec2 and Ec17, with a rate of cooling that varies between 0.4 and 0.8°C Ma−1. A Late Cenozoic cooling episode is also observed in the more elevated Ec13, Ec16 and Ec18 samples, with rates ranging between 0.7 and 1.5°C Ma−1. Late Paleozoic–early Mesozoic cooling is exhibited in Ec13 and Ec16 from elevated positions and Ec17 from a low elevation, with cooling rates spanning 0. 4–1.1°C Ma−1, whereas Ec14 and Ec3, the only sample with just AFT data, both exhibit linear protracted cooling with a rate of 0.2°C Ma−1.
In the central segment of the study area, accelerated cooling from the Cretaceous to present is observed only in Ec22, with a cooling rate of 0.5°C Ma−1. A Late Cenozoic cooling episode is also observed in thermal histories from low-elevation coastal samples Ec12 and Ec19, both exhibiting a rate of 1°C Ma−1. Accelerated late Paleozoic–early Mesozoic cooling is observed in low-elevation samples Ec19, Ec21 and Ec22 with varying rate of cooling between 0.3 and 1.1°C Ma−1, whereas linear protracted cooling is observed in the elevated and inland samples Ec20 and Ec23, both exhibiting a rate of 0.2°C Ma−1.
In the SE segment, accelerated cooling from the Cretaceous to present is displayed in the low-elevation samples Ec7 and Ec8, with a rate between 0.6 and 0.8°C Ma−1. A Late Cenozoic cooling episode is also observed in only the low-elevation sample Ec5, exhibiting a rate of 1.4°C Ma−1. Additionally, late Mesozoic cooling is also observed in the low-elevation Ec7 and Ec8 samples with rates varying between 1.2 and 1.3°C Ma−1, whereas the elevated Ec10 sample, derived from AFT data alone, exhibits linear protracted cooling with a rate of 0.25°C Ma−1.
Predicted AFT central ages and c-axis corrected track distributions from thermal histories are all modelled within error, with the exception of Ec14, where the central age is calculated from only four grains, suggesting that the age itself is anomalous. Predictions of whole grain AHe ages vary, with AHe ages younger than the counterpart AFT central ages appropriately replicated whereas ages similar to or older than AFT central ages are predicted poorly. Fragment grain ages within sample Ec8 display a similar trend, with younger ages predicted well alongside AFT and whole grain AHe ages although five fragments older than the AFT central age are poorly replicated (Fig. 5).
Discussion
Evolution of the Cumberland Peninsula
The AFT and AHe results and thermal histories from this work suggest that the modern topography of the Cumberland Peninsula has been predominantly shaped by surface uplift during rifting in the Cretaceous and subsequent differential denudation. Additionally, insight into the pre-rift history of the region is provided by a collection of thermal histories that imply exhumation of central Laurentia during the late Paleozoic–early Mesozoic. These results support the conclusions of the original AFT study (McGregor et al. 2013), although improved resolution of the synrift and post-rift history has been gained through the addition of AHe data.
Uplift and preservation of the Cumberland Peninsula's topography
The principal source of surface uplift across the Cumberland Peninsula is probably flank uplift during active rifting in the Cretaceous (Fig. 6a). Rift-flank uplift of strong, cold lithosphere is a long-known and well-understood phenomenon (Buck 1986; Braun & Beaumont 1989; Weissel & Karner 1989) and can account for kilometres of rock uplift during the active rifting phase. Spatial trends in the AFT and AHe data exhibit younger ages toward the SE coastline and outline inclined isochrons oriented NW–SE, implying that considerable rock uplift of the SE coastline has occurred (Fig. 3). This is corroborated by the onset of cooling in the Cretaceous, evident in many of the thermal histories from coastal and low-elevation samples (Fig. 5), probably the thermal response to exhumation during and following uplift. Exhumation of the region at the time is evident, with an erosional contact between synrift fluvial sediments and the underlying basement observable across Durban, Padloping and Quqalluit islands (Fig. 1) (Burden & Langille 1990). Moreover, this proposed rift-flank uplift of the SE margin accounts for the higher modern topography observed toward the SE of the study area, indicative of a major erosional escarpment (Fig. 6a) (Mayer 1986; Tucker & Slingerland 1994), that would have redirected drainage systems in the study area NE into Baffin Bay during rifting.
After the end of rifting in the Early Paleocene, differential erosion of the rift flank probably continued throughout the post-rift stage. Many of the thermal histories from across the margin outline continuous cooling throughout the Cenozoic, with cooling rates themselves varying between high and low elevations, implying that differential denudation was evident across the landscape (Fig. 5). This last point is implied by the modern fjordal distribution, which mimics the characteristics of dendritic drainage patterns (Fig. 6b), suggesting that later glaciers may have overprinted rift-related fluvial systems through topographically constrained glacial flow. Two dendritic glacial drainage systems are observable within the modern landscape (Fig. 6b), extracted through the application of flow accumulation analysis, an analytical approach that determines overland fluid flow pathways based on digital elevation models (Jenson & Domingue 1988). These systems flow SW–NE into Baffin Bay at Padloping Island and Qikiqtarjuaq, overlapping the location of the aforementioned Cretaceous river sediments (Fig. 6b) and suggesting that they may outline the redirected fluvial systems that formed during surface uplift in the Cretaceous. Glacial overprinting of these river valleys is likely to have occurred during the Neogene and Quaternary, inheriting the dendritic drainage pattern through the process of selective linear erosion that over-deepened the pre-glacial network, analogous to similar examples from Greenland (Bamber et al. 2013; Cooper et al. 2016).
This interpretation of the post-rift evolution of the Cumberland Peninsula does fail to account for the final period of cooling observed in a number of thermal histories. This cooling (c. 30–0 Ma) occurs outside the temperature sensitivity ranges of both the AFT and AHe systems, implying that it may be an artefact of the modelling process owing to a drop in surface temperatures in the Late Cenozoic (c. 10–20°C). Climatic cooling at high latitudes is thought to have occurred at the Eocene–Oligocene boundary (c. 33 Ma) (Eldrett et al. 2009; Bernard et al. 2016), and the onset of glaciation across NE Canada is believed to have occurred in the Miocene (Ehlers & Gibbard 2007). A significant drop in surface temperature following a sample's exit from the PAZ and HePRZ would result in a significant cooling event being present in thermal models owing to the enforced present-day thermal constraint of 0°C.
In addition to defining the region's uplift history, results from thermal modelling also provide insight into the exhumation of the Cumberland Peninsula prior to rifting, supporting the conclusions of McGregor et al. (2013). A record of the geology during this time is absent in the study area, although cooling during the late Paleozoic–early Mesozoic in a collection of thermal models (Fig. 5) reiterates the conclusions of numerous studies that infer widespread exhumation of Laurentia during the same period (Pysklywec & Mitrovica 2000; Flowers et al. 2012; Ault et al. 2013; McGregor et al. 2013). Stratigraphic evidence of exhumation from this time is limited in the immediate surroundings, although much larger basins across the craton's periphery, such as the Sverdrup Basin, do show evidence of terrestrial systems originating from across Laurentia (Patchett et al. 2004; Midwinter et al. 2016). This could suggest that large-scale fluvial systems flowed across Laurentia toward the Sverdrup Basin during the late Paleozoic and early Mesozoic (Fig. 6c), providing a viable mechanism for cooling across the Cumberland Peninsula prior to later rifting.
Preservation of the Cumberland Peninsula's topography
The results presented above suggest that the origin of high topography across SE Baffin Island occurred during rifting in the Cretaceous followed by continuous fluvial and glacial erosion in the Cenozoic. This interpretation provides an explanation for much of the thermochronology, geomorphology and stratigraphy, although it does not explain how the modern topography itself remains elevated at present (≤2 km).
A mechanism that can explain elevated topography in regions of continuous exhumation is isostatic feedback from the lithosphere following differential denudation (Stephenson & Lambeck 1985; Gilchrist & Summerfield 1990; Tucker & Slingerland 1994; Rouby et al. 2013). Surface uplift across Greenland and Norway in response to erosional unloading of the lithosphere during glaciation has been shown to reach c. 1000 m (Medvedev et al. 2008, 2013; Medvedev & Hartz 2015), implying that a similar effect may have occurred across the Cumberland Peninsula. The extent of glacial erosion across the margin is evident in the modern geomorphology, suggesting that significant volumes of rock have been removed, in turn driving a considerable isostatic response. To test the degree to which erosion has driven surface uplift in the region, a simple 2D flexural model of the isostatic response was considered, in which the modern fjords are refilled with eroded material (Fig. 7) (see also supplementary material), analogous to the work of Medvedev et al. (2013). Results show an increase in maximum elevation of 91 m and a drop in average elevation of 209 m, outlining how differential denudation of the lithosphere will produce rock column uplift and effectively preserve the highest topography (Fig. 7). This model provides a simple demonstration of the first-order role isostasy plays within the exhumation of passive margins and how it preserves the elevated rift-flank topography of the Cumberland Peninsula.
Implications for Atlantic continental margins
The origin and age of topography across continental passive margins has been a widely debated topic within the geological community for over a century (e.g. Geikie 1901; Reusch 1901; Steers 1948; Holtedahl 1958; Mörner 1979; Japsen & Chalmers 2000; Anell et al. 2009; Nielsen et al. 2009; Green et al. 2013, 2018; Japsen et al. 2018). Both post-rift tectonism and isostatic compensation driven by differential erosion are cited as possible sources of elevated topography across Greenland, Norway, Brazil and South Africa (Brown et al. 2000; Hendriks & Andriessen 2002; Japsen et al. 2006, 2012, 2014; Nielsen et al. 2009). The contentious interpretation of inferred peneplains as direct indicators of surface uplift and the lack of an obvious cause of uplift following the end of rifting make it difficult to support the former theory of passive margin topographic generation. Instead, the conclusions of this work support the latter of the two theories as the rift-related topography of the Cumberland Peninsula is interpreted to have has been preserved by differential exhumation of the rift flank and isostatic compensation. Moreover, the trend in AFT central ages suggesting the flexure of the lithosphere is comparable with those observed across southern Norway (Redfield et al. 2005), West Greenland (Redfield 2010) and Brazil (Gallagher et al. 1995), highlighting the probable first-order control rifting has on passive margin topography. The similarity in these results would suggest that topography along many Atlantic passive margins may be explained through the interaction of rift tectonics, differential exhumation and isostatic compensation rather than post-rift tectonism.
Previous thermochronological studies from passive margins in the Baffin Bay region display similar trends in cooling, providing regional consistency to this study's interpretation. Across the continental margins of Baffin Bay and the Labrador Sea AFT and AHe ages appear similar to those reported here (Hendriks et al. 1993; Japsen et al. 2006; Jess et al. 2019; McDannell et al. 2019), and the interpretation of rift-related uplift and differential erosion shaping the landscape is comparable (Hendriks et al. 1993; Jess et al. 2019). AFT data from both Newfoundland and West Greenland are interpreted to suggest that the modern topography is the result of rift-related uplift (Hendriks et al. 1993; Jess et al. 2019), whereas low rates of exhumation during the Cenozoic are inferred from thermal modelling of both AFT and AHe data (Jess et al. 2018). Collectively this suggests that much of the topography observed across the wider region is probably the result of preserved rift-related uplift, such that both margins have evolved according to a single unifying conceptual model that does not require the intervention of post-rift uplift.
Dispersion in AHe ages
The application of the ‘broken crystal’ technique within Ec8 improves modelling results through the inclusion of additional thermal information, although robust joint inverse thermal history modelling of other samples is made difficult by high levels of whole grain age dispersion (Fig. 5; Ec12 and Ec16). The radiation damage model and diffusion parameters applied to thermal histories (Gautheron et al. 2009) improves AHe age predictions relative to standard apatite diffusion parameters (Farley 2000), although it does not produce suitable predictions for a collection of the AHe ages. This implies other underlying factors, which are not accounted for in the modelling method (e.g. mineral inclusions, zonation, implantation), and the developing understanding of the AHe system may hinder effective prediction of highly dispersed AHe ages in the passive margin settings. Moreover, data used to validate and justify radiation damage models commonly differ from those found along passive margin settings: (1) sedimentary samples are commonly used; (2) AFT ages rarely exceed 200 Ma; (3) there is a lack of well-documented stratigraphy commonly in place to improve modelling constraints (Flowers et al. 2009; Gautheron et al. 2009, 2012). Accordingly, the geological setting of the Cumberland Peninsula and lengthy periods spent within the HePRZ (>100 myr) hinder the application of current radiation damage models, implying that further work on the topic in passive margin settings is essential.
Summary and conclusions
Low-temperature thermochronology and thermal history modelling help to outline how the landscape of the Cumberland Peninsula, Baffin Island, has evolved through the Mesozoic and Cenozoic. Results from this work imply that the modern topography of the margin is derived from rift-flank uplift in the Mesozoic and isostatic flexure in response to erosion thereafter.
Rift-flank uplift of the margin is implied by the spatial distribution of AFT and AHe ages, the onset of accelerated cooling in the Cretaceous and the modern geomorphology. It is suggested that during rifting, uplift of the SE coastline of Baffin Island formed a considerable elevated landscape and escarpment that forced erosive fluvial systems NE into Baffin Bay. These fluvial drainage patterns may still be observable in the modern geomorphology as selective linear erosion during glaciation probably over-deepened many of the pre-glacial valleys to form the modern fjords. Two outcomes of this differential erosion include the preservation of elevated topography and the removal of vast quantities of rock from the upper crust, prompting a positive isostatic response across the peninsula. In addition to constraining the timing uplift, insight into the pre-rift history of the region is provided, with widespread cooling in the late Paleozoic and early Mesozoic linked to exhumation of Laurentia, in accordance with similar interpretations from across the Cumberland Peninsula and northern Canada. These results and interpretations provide a suitable account of the Cumberland Peninsula region's uplift history and determine that its modern elevated topography is a remnant rift flank, augmented by differential erosion and isostasy.
Acknowledgements
E. McGregor is sincerely thanked for the collection of samples, and A. Carter and J. Schwanethal are also thanked for their assistance in sample preparation and analysis. Thanks are also given to Y. Gunnell, J. Spotila and L. Currie for their constructive comments and reviews.
Funding
The work reported here was conducted during a PhD study undertaken as part of the Natural Environment Research Council (NERC) Centre for Doctoral Training (CDT) in Oil & Gas (grant number NEM00578X/1) and was sponsored by the University of Aberdeen.