Abstract

The behavior of quartzose and olivinic sands subjected to water percolation is important in studying the weathering of a sediment. Sorption of H+ ions from the water and desorption of metal ions from the sediment take place in a fashion similar to that caused by an ion exchange resin. This fact permits the construction of a mathematical model that gives the expected amount of H+ sorption for a bed as a function of time and space.

Sorption-desorption processes in sediments are responsible for weathering of silicate beds, water quality changes, and possibly play a role in porosity changes. These sorption-desorption reactions are pH dependent and also vary according to the O:Si ratio. It seems that all sorption phenomena at the sediment-water interface can be conceived as adjustments to produce a minimum of free energy difference between the crystal, the surface, and the external environment.

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