Most magmatic chromite deposits, particularly those in stratiform layered ultramafic-mafic intrusions, are interpreted to have formed by processes that decrease the solubility of chromite. However, such models have difficulty in explaining the great thicknesses (up to 10 m) of chromite mineralization at Inyala and Railway Block (Zimbabwe), Ipueira-Medrado (Brazil), Uitkomst (South Africa), and Sukinda (India), and the very great (up to 100 m) thicknesses of chromitite at Kemi (Finland) and in the Black Thor Intrusive Complex (Canada). We propose a new process that involves partial melting of Fe ± Ti oxide–rich rocks (oxide-facies iron formation or ferrogabbro) and conversion of fine-grained oxide to chromite by reaction with Cr-rich komatiitic magma in a dynamic magma conduit. This process is analogous to the widely accepted model for the upgrading of barren iron-sulfide xenomelts to form magmatic nickel–copper–platinum group element deposits. We demonstrate that this process is geologically, physically, and chemically feasible, that it probably occurred in the Black Thor Intrusive Complex, and that it may have applications elsewhere.
Chromite deposits have traditionally been subdivided into stratiform (type I) and podiform (type II) types (e.g., Stowe, 1994). However, it has become clear that type I stratiform deposits can be subdivided (Prendergast, 2008) into those hosted by large, differentiated layered intrusions (periodically replenished magma chambers) (type IA), and small, less-differentiated magmatic conduits (flow-through feeder conduits and /or sills) (type IB) (Table DR1 in the GSA Data Repository1). Type IB deposits are normally laterally less extensive but thicker than type IA deposits, are typically hosted by more ultramafic rocks, are ordinarily derived from more magnesian—commonly komatiitic—magmas, and usually have higher Mg and lower Al contents (Table DR1).
A fundamental problem in the genesis of all stratiform chromite deposits is how layers of massive to semi-massive chromite that are commonly up to 1 m thick (e.g., Bushveld [South Africa], Stillwater [Montana, USA]), less commonly up to 10 m thick (e.g., Inyala and Railway Block [Zimbabwe], Ipueira-Medrado [Brazil], Uitkomst [South Africa], Sukinda [India]), but in some cases up to 100 m thick (e.g., Kemi [Finland], Black Thor Intrusive Complex [Canada]) (Table DR1) are generated from magmas that typically contain <0.35% Cr and crystallize very small amounts of chromite (normally <1% of the cumulus assemblage). Many models have been suggested, including (1) liquid immiscibility (e.g., McDonald, 1965), (2) oxidation (e.g., Ulmer, 1969; Ferreira Filho and Araujo, 2009), (3) felsification (e.g., Irvine, 1975; Spandler et al., 2005), (4) magma mixing (e.g., Irvine, 1977; Campbell and Murck, 1993), (5) pressure increase (e.g., Cameron, 1980; Lipin, 1993) or decrease (Latypov et al., 2018), (6) assimilation of iron formation (e.g., Rollinson, 1997), (7) hydration (e.g., Azar, 2010; Prendergast, 2008), (8) dynamic crystallization (Yudovskaya et al., 2015), and (9) cumulate-melt interaction (e.g., O’Driscoll et al., 2010), with or without upward transport (e.g., Eales, 2000; Mondal and Mathez, 2007) and/or downward slumping (e.g., Maier et al., 2013).
These processes are not mutually exclusive and may have operated to varying degrees in different deposits, yet all have problems. Upward-transport models simply relocate the problem, add a major degree of fluid dynamic complexity in terms of requiring re-entrainment of previously segregated chromite, and do not explain why chromite does not occur in economic concentrations in volcanic rocks. Magma mixing, contamination, oxidation, hydration, and pressure changes all are feasible to varying degrees, but require the amount of magma to greatly exceed the thickness of the host intrusion (e.g., Campbell and Murck, 1993; Eales, 2000; Carson et al., 2013). Layered intrusions likely inflated during crystallization and never contained melt zones of the thicknesses required at the lower (more realistic) efficiencies of extraction. Phase-equilibria studies (e.g., Irvine, 1977; Murck and Campbell, 1986) indicate that the most popular model—mixing of parental (new influx) and fractionated (resident) magmas across the convex olivine-chromite cotectic to drive it into the volume of chromite-only crystallization—can generate only ∼0.1 wt% chromite as the magma is driven back to the cotectic. The interval over which chromite alone can crystallize after a pressure decrease (Latypov et al., 2018) has not been established, however it is limited within this context by the low solubility of Cr in silicate magmas.
Crystallization and deposition of chromite in a flow-through system, analogous to the lava channels and magma conduits that host magmatic Ni–Cu–platinum group element (PGE) deposits (e.g., Lesher et al., 1984; Lesher, 1989; Arndt et al., 2008), which are inferred to have processed two to three orders of magnitude more magma than the amount of sulfide presently preserved in the channels, would solve the mass-balance problem. However, the process(es) required to drive the magma into the field of chromite-only crystallization would need to occur continuously over very long periods of time to generate the vast amounts of chromite in type IB deposits.
Wholesale assimilation of iron formation (Rollinson, 1997) explains the close association of many type IB deposits with iron formation (Table DR2), however there are several problems with such a process:
(1) The presence of cotectic olivine(-chromite) cumulate rocks in the lower parts of the host intrusions (e.g., Kemi: Alapieti et al., 1989; Black Thor: Carson et al., 2013) indicates that the magmas were already saturated in chromite, so they should not have been able to assimilate another oxide phase.
(2) Adding an assimilant containing >20% FeO to a komatiitic magma that would normally contain ∼10%–12% FeO would increase the Fe/Mg ratios of olivine, orthopyroxene, and clinopyroxene, which does not appear to be observed (e.g., Azar, 2010).
(3) Assimilation-crystallization models indicate that the modal proportion of chromite generated by such a process would be <0.3% (Azar, 2010).
PARTIAL MELTING AND UPGRADING
A solution to this problem would be for the parental magma to partially melt an oxide-rich lithology such as oxide-facies iron formation or ferrogabbro. A high-Mg komatiitic magma with ∼30% MgO would be undersaturated in chromite (Murck and Campbell, 1986) and would be able to completely assimilate significant amounts of either lithology; however, a low-Mg komatiitic magma with ∼20% MgO would be saturated in chromite and would be able to dissolve the silicate phases but not the oxide phases. Addition of silica would account for the abundance of orthopyroxene in magmas that normally crystallize clinopyroxene (Arndt et al., 2008).
Converting xenocrystic magnetite and/or ilmenite to chromite requires magnetite to incorporate Cr-Al-Mg-V-Ni from the magma and release Fe and/or Ti into the magma. Magnetite and chromite are both isometric, so the conversion from magnetite would be topotactic, whereas ilmenite is trigonal, so the conversion from ilmenite would require a structural inversion, however that is unlikely to be a barrier at such high temperatures.
The Black Thor and Double Eagle Intrusive Complexes in the Ring of Fire Intrusive Suite of northern Ontario (Canada) appear to have had the best opportunity to generate chromite mineralization by the proposed mechanism. There are oxide-silicate–facies iron formations and Fe-Ti oxide-bearing gabbros in underlying rocks, the intrusions contain iron-formation and gabbro xenoliths, the parental magma was a chromite-saturated low-Mg komatiite (Mungall et al., 2010), and the chromite-bearing intrusions are dominated by cumulates and interpreted to represent flow-through magma conduits (Carson et al., 2013). The chromites in the Black Thor Intrusive Complex exhibit a wide range of textures including (1) massive, (2) inclusion-bearing (predominantly serpentine-actinolite-chlorite interpreted to represent altered komatiitic melt inclusions), and (3) pitted with fine Fe ± Cu sulfides (Fig. 3A). The first and third are similar to the textures of magnetite-silicate±sulfide iron-formations below the Black Thor Intrusive Complex (Fig. 3B), consistent with them being the source of the oxide in this deposit.
There are examples where magmas have thermomechanically eroded oxide-facies iron formation (e.g., Duluth [Minnesota, USA]: Ripley, 1986; Digger’s Rock [Western Australia]: Perring et al., 1996; Hunters Road [Zimbabwe]: Prendergast, 2003); however, none of these systems contain anomalous chromite. In the case of Duluth, the magma may have been too poor in Cr, whereas the magma at Digger’s Rock and Hunters Road may have been undersaturated in chromite. Unfortunately, none of these studies reported the Cr contents of the oxide xenoliths. The country rocks of the Sukinda and the Inyala intrusions include iron formation, but no iron-formation xenoliths were reported by Chakraborty and Chakraborty (1984), Mondal et al. (2006), or Rollinson (1997). The Kemi intrusion contains Na-rich gneissic xenoliths; however, no iron-formation xenoliths were reported by Alapieti et al. (1989).
There are <2-cm-thick chromite layers in strongly differentiated komatiite flows where chromite has reached saturation after significant degrees of fractional crystallization (e.g., Kambalda: Lesher, 1989) and rare occurrences of Cr-rich lavas (e.g., Halkoaho et al., 2000), but the amount of chromite is very small and it is clear that it formed via fractional crystallization. The absence of thick chromite seams in komatiitic, picritic, or basalt lavas suggest that despite its fine grain size and theoretical high transportability (see Lesher, 2017), chromite is normally trapped at the same stratigraphic levels where it forms and is not normally transported significant distances vertically, likely because it forms larger untransportable “pseudoslugs”.
The proposed process (Fig. 4) requires further testing; however, it explains a major paradox in the genesis of conduit-hosted, if not all, stratiform chromite deposits. It may also have applications in the genesis of some intrusions containing anomalous amounts of Fe-Ti-V oxides associated with high-Ti, low-Cr basaltic magmas.
The Natural Sciences and Engineering Council of Canada (DG 203171-2012) and Cliffs Natural Resources (CRD 446109-2012) provided financial support; the Ontario Geological Survey and the Geological Survey of Canada Targeted Geosciences Initiative program provided in-kind analytical support; and Cliffs Natural Resources and Noront Resources provided in-kind logistical support. We are grateful to Bronwyn Azar, Pedro Jugo, Riku Metsaranta, Ryan Weston, Jesse Robertson, Edward Ripley, and Roger Scoon for helpful discussions, and to Steve Barnes and an anonymous reviewer for insightful comments on the manuscript. This is Mineral Exploration Research Centre Metal Earth Contribution MERC-ME-2018-100.