Experimental evidence has shown the importance of boron on the crystallization behavior of granitic systems; however, the intercrystalline and intracrystalline distribution of boron in mineral phases crystallizing from granitic systems is not well documented. The distribution of boron between coexisting phases in the Tip Top pegmatite, South Dakota, is as follows: beryl ≈ quartz ≈ triphylite ≈ montebrasite ≈potassium feldspar < biotite < albite < muscovite < spodumene ≪ tourmaline. The bulk boron content of the Tip Top pegmatite decreases significantly with the termination of tourmaline crystallization. The significant decrease in boron in the inner zones of the pegmatite is consistent with the depletion of boron in the granite melt by either the crystallization of tourmaline from the granitic melt or the partitioning of boron into an exsolved aqueous solution.

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