The Origin, Evolution, and Environmental Impact of Oceanic Large Igneous Provinces
Lithium isotope evidence for magmatic assimilation of hydrothermally influenced crust beneath oceanic large igneous provinces
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Published:May 01, 2015
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CiteCitation
Takashi Sano, Yoshiro Nishio, 2015. "Lithium isotope evidence for magmatic assimilation of hydrothermally influenced crust beneath oceanic large igneous provinces", The Origin, Evolution, and Environmental Impact of Oceanic Large Igneous Provinces, Clive R. Neal, William W. Sager, Takashi Sano, Elisabetta Erba
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Fresh basalts from the Ontong Java Plateau (OJP) and the Shatsky Rise show lithium enrichments comparable to those of mid-oceanic ridge basalts (MORBs) and ocean island basalts (OIBs), with Li contents being significantly higher at a given MgO content. The Li isotopic compositions of the Shatsky Rise basalts (δ7Li = +6‰ to +7‰) are at the higher end of the range exhibited by OIBs, whereas OJP basalts (δ7Li = +3‰ to +5‰) have Li isotopic compositions similar to MORBs. Among all the basalts from the two oceanic large igneous provinces (LIPs), one sample from the Shatsky Rise is isotopically enriched (e.g., low 143Nd/144Nd and 176Hf/177Hf) and has higher K/Ti and lower La/Nb than the other samples. Relationships between δ7Li and K/Ti, La/Nb, and Rb/Nb of this sample indicate that it may have been affected by mantle that was metasomatized by slab-derived fluids. Apart from this isotopically enriched sample, δ7Li values of basalts from the two oceanic LIPs are positively correlated with K/Ti and Rb/Nb. Obvious linear relationships exist between δ7Li and Yb/Li, Y/Li, and Dy/Li for samples from the Shatsky Rise. These geochemical relationships can be explained by magmatic assimilation of hydrothermally influenced crust. The high δ7Li values of the Shatsky Rise basalts imply that the degree of assimilation is high because shallow magma chambers allow greater assimilation of hydrothermally influenced crust. In contrast, the low δ7Li values of the OJP samples may indicate they have undergone little assimilation as compared with the Shatsky Rise basalts.
- alkali metals
- assimilation
- basalts
- chemical composition
- crust
- Expedition 324
- hafnium
- Hf-177/Hf-176
- igneous rocks
- Integrated Ocean Drilling Program
- IODP Site U1346
- IODP Site U1347
- IODP Site U1349
- IODP Site U1350
- isotope ratios
- isotopes
- large igneous provinces
- Li-7/Li-6
- lithium
- magma chambers
- magmas
- metals
- mid-ocean ridge basalts
- Nd-144/Nd-143
- neodymium
- North Pacific
- Northwest Pacific
- ocean-island basalts
- Ontong Java Plateau
- Pacific Ocean
- rare earths
- Shatsky Rise
- slabs
- stable isotopes
- volcanic rocks
- West Pacific