The post-Cambrian and pre-Upper Devonian Shoo Fly Complex represents the remnants of an ancient subduction system. The Quartz Hill chert, a thrust-fault-bounded, chlorite-grade greenschist facies unit, is included in the Shoo Fly Complex, and consists of about 25 m of interstratified radiolarite and argillite. Rare earth element (REE) data derived from 15 samples indicate that the Quartz Hill chert contains two chemically distinct groups of rock. Six Group 1 specimens display relatively flat REE/PAAS (post-Archean average Australian shale) distribution patterns, no Ce anomaly, and a variable positive Eu anomaly. In contrast, nine Group 2 specimens exhibit no Ce anomalies, a variable positive Eu anomaly, and display REE/PAAS values that increase from La to Eu, and then decrease from Eu to Lu. The REE, Th, and Sc characteristics of Group 1 samples are like those in Cretaceous, Tertiary, and Quaternary marine sediments containing particles derived from magmatic arcs. In contrast, the REE, Th, and Sc characteristics of Group 2 specimens are suggestive of a mixture of magmatic arc material and alkaline basaltic particulate matter derived from a seamount or ocean island.

Data presented here are consistent with the results from previous petrological and geochemical studies of rocks in the Shoo Fly Complex, and indicate that the Quartz Hill chert was deposited on the margin of an oceanic plate adjacent to a magmatic arc and a seamount(s) or ocean island(s). Thus, the data here and in the literature suggest that the REE, Th, and Sc characteristics of chert/argillite sequences deposited in or adjacent to active subduction systems are controlled primarily by source rocks in adjacent magmatic arcs, and in seamounts or ocean islands located within subducting plates.