We present the results of a compositional characterization study of amphorae from the ancient Greek town of Pharos, today Stari Grad, on the island of Hvar, in central Dalmatia, Croatia. The aim of the study was to identify the provenance of amphorae unearthed in Pharos, to determine the locally produced amphorae, and to identify the provenance of imported amphorae with a scientific-based approach, using optical thin-section petrography and bulk geochemical analysis by wavelength-dispersive X-ray fluorescence on 19 samples of different types of amphorae and reference materials. The results of the analyses allowed us to identify a group of imported amphorae from Corinth or Corfu and a group of imported amphorae from southern Italy, probably from Calabria. We were also able to identify a third group of imported amphorae from an as-yet-unknown provenance/workshop. Finally, according to the geochemical composition and close match with the reference material, namely, kitchenware, only two amphorae from the examined collection could be identified as local products. The results of the compositional characterization of amphorae from Pharos show us that an ancient Greek town had trade contacts beyond the Adriatic-Ionian region, and they provide opportunities for further studies of ancient amphorae production and circulation in this part of the Mediterranean.