Syenogranites and monzogranites of Edward VII Peninsula, Marie Byrd Land, represent magmatism associated with continental rifting and the separation of New Zealand from W Antarctica in the mid-Cretaceous. These coarse-grained, leucocratic, subsolvus biotite granites occur as five small plutons cutting Lower Palaeozoic metasediments. Petrographic features include the predominance of microcline perthite over albite, bipyramidal smoky quartz, red-brown biotite and accessory ilmenite, zircon, apatite, monazite and fluorite. Enclaves are absent and miarolitic cavites are rare.

The granites are a weakly peraluminous, potassic, and highly fractionated suite with high concentrations of Rb, Nb, Y, HREE and F in the most evolved compositions. REE patterns vary from LREE-enriched (Ce_N/Yb_N = 8.4), to flat REE patterns (Ce_N/Yb_N = 1.1) with large negative Eu anomalies (Eu/Eu* =0.02). Initial ⁸⁷Sr/⁸⁶Sr ratios are 0.7116–0.7206 and initial ε_Nd values are −5.5 to −7.7. Generalised fractionation trends for the suite are explicable in terms of the modal mineralogy. Monazite crystallisation exerted a predominant control on LREE concentrations.

The geochemistry of the Edward VII Peninsula granites suggests an infracrustal I-type source, and regionally available Devonian-Carboniferous I-type granodiorites and tonalites satisfy the isotopic constraints. The granites classify as A-type (preferred term A-subtype) and Within-Plate Granites on standard diagrams, but the least fractionated rocks clearly indicate the I-type, Volcanic Arc Granite geochemical signatures of their inferred crustal sources.