Yucca Mountain, a site in southwest Nevada, has been proposed for a deep underground radioactive waste repository. An extensive database of geochemical and isotopic characteristics has been established for pore waters and gases from the unsaturated zone, perched water, and saturated zone waters in the Yucca Mountain area. The development of this database has been driven by diverse needs of the Yucca Mountain Project, especially those aspects of the project involving process modeling and performance assessment. Water and gas chemistries influence the sorption behavior of radionuclides and the solubility of the radionuclide compounds that form. The chemistry of waters that...