ABSTRACT In total, 33 and 65 chrome-spinel (Cr-spinel) grains in the >63 and 32–63 μm size fractions, respectively, were recovered from 12 beds in two stratigraphically separated groups along the 240-m-thick Monte Acuto section of the Maiolica limestone in central Italy, spanning from the Berriasian to the early Hauterivian. The chemistry of these detrital spinels suggests they may represent windblown ophiolitic detritus, showing the evolution of an ophiolite evolving from a mid-ocean-ridge basalt setting (Bosso section) to a suprasubduction-zone setting, including a backarc and an arc setting (Monte Acuto section). The source of the Maiolica detrital minerals may have been the obducting ophiolites of the Albanides and/or the Hellenides, which show a similar evolution. In this case, it is particularly important to note how the Cr-spinel detritus in the Maiolica limestone records this evolution over a relatively short period of time, lasting ~10 m.y.

ABSTRACT The Popigai (100 km in diameter) and the Chesapeake Bay (40–85 km diameter) impact structures formed within ~10–20 k.y. in the late Eocene during a 2 m.y. period with enhanced flux of 3 He-rich interplanetary dust to Earth. Ejecta from the Siberian Popigai impact structure have been found in late Eocene marine sediments at numerous deep-sea drilling sites around the globe and also in a few marine sections outcropped on land, like the Massignano section near Ancona in Italy. In the Massignano section, the Popigai layer is associated with an iridium anomaly, shocked quartz, and abundant clinopyroxene-bearing (cpx) spherules, altered to smectite and flattened to “pancake spherules.” The ejecta are also associated with a significant enrichment of H-chondritic chromite grains (>63 μm), likely representing unmelted fragments of the impactor. The Massignano section also contains abundant terrestrial chrome-spinel grains, making reconstructions of the micrometeorite flux very difficult. We therefore searched for an alternative section that would be more useful for these types of studies. Here, we report the discovery of such a section, and also the first discovery of the Popigai ejecta in another locality in Italy, the Monte Vaccaro section, 90 km west of Ancona. The Monte Vaccaro section biostratigraphy was established based on calcareous nannoplankton, which allowed the identification of a sequence of distinct bioevents showing a good correlation with the Massignano section. In both the Monte Vaccaro and Massignano sections, the Popigai ejecta layer occurs in calcareous nannofossil zone CNE 19. The ejecta layer in the Monte Vaccaro section contains shocked quartz, abundant pancake spherules, and an iridium anomaly of 700 ppt, which is three times higher than the peak Ir measured in the ejecta layer at Massignano. In a 105-kg-size sample from just above the ejecta layer at Monte Vaccaro, we also found an enrichment of H-chondritic chromite grains. Because of its condensed nature and low content of terrestrial spinel grains, the Monte Vaccaro section holds great potential for reconstructions of the micrometeorite flux to Earth during the late Eocene using spinels.

ABSTRACT We reconstructed a record of the micrometeorite flux in the Late Cretaceous using the distribution of extraterrestrial spinel grains across an ~2 m.y. interval of elevated 3 He in the Turonian Stage (ca. 92–90 Ma). From ~30 m of the limestone succession in the Bottaccione section, Italy, a total of 979 kg of rock from levels below and within the 3 He excursion yielded 603 spinel grains (32–355 μm size). Of those, 115 represent equilibrated ordinary chondritic chromite (EC). Within the 3 He excursion, there is no change in the number of EC grains per kilogram of sediment, but H-chondritic grains dominate over L and LL grains (70%, 27%, and 3%), contrary to the interval before the excursion, where the relation between the three groups (50%, 44%, and 6%) is similar to today and to the Early Cretaceous. Intriguingly, within the 3 He anomaly, there is also a factor-of-five increase of vanadium-rich chrome spinels likely originating from achondritic and unequilibrated ordinary chondritic meteorites. The 3 He anomaly has an unusually spiky and temporal progression not readily explained by present models for delivery of extraterrestrial dust to Earth. Previous suggestions of a relation to a comet or asteroid shower possibly associated with dust-producing lunar impacts are not supported by our data. Instead, the spinel data preliminary indicate a more general disturbance of the asteroid belt, where different parent bodies or source regions of micrometeorites were affected at the same time. More spinel grains need to be recovered and more oxygen isotopic analyses of grains are required to resolve the origin of the 3 He anomaly.

ABSTRACT The present-day ocean-climate system configuration took shape during the Miocene Epoch. Toward the end of the epoch, in the late Tortonian at ca. 8.5 Ma, there was an exceptional event: collisional disruption of an >150-km-diameter asteroid, which created the Veritas family of asteroids in the asteroid belt. This event increased the flux of interplanetary dust particles rich in 3 He to Earth and probably caused a period of increased dust in the atmosphere, with consequent alteration of global and local environmental conditions. A late Miocene 3 He anomaly likely related to the Veritas event has been registered in deep-sea sediments from Ocean Drilling Program (ODP) Site 926 (Atlantic Ocean), ODP Site 757 (Indian Ocean), and in the late Tortonian–early Messinian Monte dei Corvi section near Ancona, Italy. Here, we report the results of a study in the Monte dei Corvi section aimed to recover extraterrestrial chrome-spinel grains across the 3 He anomaly interval, as has been done for the similar late Eocene 3 He anomaly in the nearby Massignano section. In this study, three ~100 kg samples were collected from the Monte dei Corvi section: two within the 3 He peak interval and one outside the anomaly interval as a background reference sample. In total, 1151 chrome-spinel grains (>63 µm) were recovered, but based on chemical composition, none of the grains has a clear extraterrestrial origin. This supports the inference that the 3 He anomaly is indeed related to the Veritas event and not to an approximately coeval breakup of a smaller H-chondritic body in the asteroid belt, an event registered in meteoritic cosmic-ray exposure ages. Spectral studies of the Veritas asteroids indicate that they are made up of carbonaceous chondritic material. Such meteorites generally have very low chrome-spinel concentrations in the grain-size range considered here, contrary to the very chromite-rich ordinary chondrites. The terrestrial grains recovered were classified, and their composition showed that all the grains have an ophiolitic origin with no substantial compositional and distributional change through the section. The source area of the terrestrial grains was probably the Dinarides orogen.