ABSTRACT Limestone provides many lessons about Earth’s systems (geosphere, hydrosphere, atmosphere, cryosphere, and biosphere) through the geochemical, hydrologic, ­tectonic, and rock cycles. Limestone is ideal for teaching cross-disciplinary STEM (science, technology, engineering, and math) subjects of biology, chemistry, and physics, along with history and culture through its uses in society as a valuable economic resource. Carbon and calcium chemistry is part of the everyday environment, and limestone deposits around the world are important archives of biotic and abiotic Earth history. Limestones provide data for reconstructing global climate change and provide important “documents” for recreating Earth’s changing biodiversity throughout geologic time, including human history. Limestone precipitation is Earth’s antidote to global warming. Limestone is volumetrically one of our most valuable natural resources with a variety of uses, as well as frequently involved with natural and human-induced environmental hazards. Limestone is a common commodity readily available to all teachers and students, thus it is the ideal material for ­budget-strapped STEM educators to use to address Next Generation Science Standards. Some uses include: using fossils to develop concepts of paleoecology and evolution; using limestones to reconstruct ancient geography (including plate tectonics); and addressing the relevance of limestone to our society as a building stone, for its medical uses, and as a potential hazard associated with karst (caves and sinkholes). Five cross-disciplinary content concepts are addressed to aid teachers in preparing limestone-centric instruction: (1) enhancement of the understanding of chemical reactions and geochemical cycles, (2) biological evolution, (3) physics applications, (4) economic and environmental impacts, and (5) historical and fine arts’ use of limestone.

Abstract Tafoni and honeycombs remain some of the most enigmatic and puzzling geomorphological phenomena. Their globally widespread occurrence across a wide range of lithologies and environmental conditions suggests that their formation is determined by a factor that overarches variations in these conditions and weathering processes. Based on a study of tafoni and honeycombs in the Crimean Piedmont, this paper demonstrates that the primary factor in their formation is the pre-exposure alteration of rocks along fractures and karst conduits as a result of fluid–rock interactions. Such alteration is commonly induced by ascending flow and is related to hypogene karstification. The morphological expression of cavernous features through removal of the alterite can occur under subsurface conditions, but is more frequent on exposure to atmospheric weathering. The local or regional characteristics of a weathering system are irrelevant or of only secondary importance in determining the localization and morphology of cavernous features. New features do not form on rock surfaces where the alteration zone was totally denuded or never present. The proposed model resolves major issues inherent to previous interpretations of cavernous features. It has general applicability and important implications for geodynamic and palaeohydrogeological reconstructions. Typical tafoni and honeycombs may indicate past events of ascending flow and the potential presence of hypogene karst systems.

Abstract Burnsville Cove in Bath and Highland Counties (Virginia, USA) is a karst region in the Valley and Ridge Province of the Appalachian Mountains. The region contains many caves in Silurian to Devonian limestone, and is well suited for examining geologic controls on cave location and cave passage morphology. In Burnsville Cove, many caves are located preferentially near the axes of synclines and anticlines. For example, Butler Cave is an elongate cave where the trunk channel follows the axis of Sinking Creek syncline and most of the side passages follow joints at right angles to the syncline axis. In contrast, the Water Sinks Subway Cave, Owl Cave, and Helictite Cave have abundant maze patterns, and are located near the axis of Chestnut Ridge anticline. The maze patterns may be related to fact that the anticline axis is the site of the greatest amount of flexure, leading to more joints and (or) greater enlargement of joints. Many of the larger caves of Burnsville Cove (e.g., Breathing Cave, Butler Cave-Sinking Creek Cave System, lower parts of the Water Sinks Cave System) are developed in the Silurian Tonoloway Limestone, the stratigraphic unit with the greatest surface exposure in the area. Other caves are developed in the Silurian to Devonian Keyser Limestone of the Helderberg Group (e.g., Owl Cave, upper parts of the Water Sinks Cave System) and in the Devonian Shriver Chert and (or) Licking Creek Limestone of the Helderberg Group (e.g., Helictite Cave). Within the Tonoloway Limestone, the larger caves are developed in the lower member of the Tonoloway Limestone immediately below a bed of silica-cemented sandstone. In contrast, the larger caves in the Keyser Limestone are located preferentially in limestone beds containing stromatoporoid reefs, and some of the larger caves in the Licking Creek Limestone are located in beds of cherty limestone below the Devonian Oris-kany Sandstone. Geologic controls on cave passage morphology include joints, bedding planes, and folds. The influence of joints results in tall and narrow cave passages, whereas the influence of bedding planes results in cave passages with flat ceilings and (or) floors. The influence of folds is less common, but a few cave passages follow fold axes and have distinctive arched ceilings.

On Earth, biology, hydrology, and geology are interlinked such that certain types of life are often associated with specific conditions, including rock type, pressure, temperature, and chemistry. Life on Earth has established itself in diverse and extreme niches, presenting the possibility that Mars, too, may hold records of fossilized and/or extant life in diverse environments. Geologic, paleohydrologic, and climatic conditions through the evolution of Mars are similar in many respects to conditions occurring during the evolution of Earth and, as such, may point to environments on Mars with potential to have supported living systems. Here, we discuss examples of those Martian settings. Such extraterrestrial environments should be targeted by international robotic and/or manned missions to explore potential fossilized or extant life on Mars.