Abstract The Cadia district of New South Wales contains four alkalic porphyry Au-Cu deposits (Cadia East, Ridgeway, Cadia Hill, and Cadia Quarry) and two Cu-Au-Fe skarn prospects (Big Cadia and Little Cadia), with a total of ~50 Moz Au and ~9.5 Mt Cu (reserves, resources, and past production). The ore deposits are hosted by volcaniclastic rocks of the Weemalla Formation and Forest Reefs Volcanics, which were deposited in a submarine basin on the flanks of the Macquarie Arc during the Middle to Late Ordovician. Alkalic magmatism occurred during the Benambran orogeny in the Late Ordovician to early Silurian, resulting in the emplacement of monzonite intrusive complexes and the formation of porphyry Au-Cu mineralization. Ridgeway formed synchronous with the first compressive peak of deformation and is characterized by an intrusion-centered quartz-magnetite-bornite-chalcopyrite-Au vein stockwork associated with calc-potassic alteration localized around the apex of the pencil-like Ridgeway intrusive complex. The volcanic-hosted giant Cadia East deposit and the intrusion-hosted Cadia Hill and Cadia Quarry deposits formed during a period of relaxation after the first compressive peak of the Benambran orogeny and are characterized by sheeted quartz-sulfide-carbonate vein arrays associated with subtle potassic, calc-potassic, and propylitic alteration halos.

ABSTRACT Blocks of variably serpentinized oceanic mantle peridotite (harzburgite, olivine orthopyroxenite, and dunite) are entrained within a latest Cretaceous (“Laramide”) low-angle subduction channel, the Orocopia Schist, exposed at Cemetery Ridge, southwest Arizona. Oceanic peridotite, serpentinized by seawater, is strikingly out of place in this region of Paleoproterozoic to Jurassic continental crust. Correspondingly, the Cemetery Ridge peridotite contains four serpentinization-related sulfide or intermetallic minerals quite unusual for an inland, continental tectonic setting: pentlandite, cobalt pentlandite, heazlewoodite, and awaruite. The peridotite also contains two Ni-arsenide minerals, orcélite and maucherite; and, less commonly, the sulfides pyrrhotite, bismuthinite, bornite, and parkerite(?). These minerals form tiny to small (~3–100 μm) grains sparsely scattered amongst the profusion of serpentine and magnetite produced by serpentinization of olivine; many grains are enclosed in magnetite. The three principal sulfide minerals at Cemetery Ridge are pentlandite [(Ni,Fe) 8.93 S 8 ] in all samples studied, and cobalt pentlandite [(Co,Ni,Fe) 9.01 S 8 ] and heazlewoodite (Ni 2.98 S 2 ) in many or most. Pentlandite and cobalt pentlandite form a discontinuous series to 74 molar percent of the Co end member. High-Co pentlandite has systematically elevated Ni/Fe. Pyrrhotite (Fe 7.88 S 8 ) occurs only in one high-S sample. Although orcélite (Ni 4.71 As 2 ) and maucherite (Ni 11.06 As 8 ) are volumetrically rare, one or both are found in most samples. Awaruite (Ni 5 Fe) is extremely rare, a few minute blebs in two samples. Sulfide assemblages at Cemetery Ridge indicate the highly reduced pore fluid typical of serpentinization. Sulfur was introduced into Cemetery Ridge peridotite during the early stages of serpentinization, as one aspect of a general enrichment in fluid-mobile elements in a suprasubduction (mantle-wedge) environment. Further serpentinization was accompanied by progressive desulfurization, with concomitant transformation from minerals of higher to lower sulfidation, and partial transfer of first Fe then Ni from sulfide to oxide phases. Five Ni or Ni-Co sulfide or arsenide minerals at Cemetery Ridge are new and unexpected for Arizona, where serpentinite is quite rare and Ni or Co deposits unknown. Sulfide minerals and assemblages at Cemetery Ridge are comparable to those of serpentinites in such places as the California and Oregon Coast Ranges and Mid-Atlantic Ridge, emphasizing the uniqueness of the tectonic setting of the subducted oceanic peridotite at Cemetery Ridge, and enhancing the status of the Orocopia and related schists as the world’s type (first-recognized, best-known) low-angle paleosubduction complex.