Abstract Mining operations disturb the natural hydrological cycle at a local scale by creating new pathways for water flow and conveying large amounts of water, both for use in ore beneficiation and through the dewatering of mining workings. Sulfide minerals exposed to water and oxygen are oxidized through chemical and microbial-enhanced reactions, significantly altering the quality of water (acid mine drainage). Stable isotopes may reveal important information concerning water origin and transfer, as well as chemical processes and solute fluxes within the aqueous environment. Several case studies illustrate the use of stable isotope techniques for clarifying aspects related to water circulation in mining areas within Romania and Finland. Hydrogen and oxygen stable isotopes coupled with total dissolved solids have been used to characterize mine water and for assessing water sources, flow paths and mixing processes at some Romanian mining sites. At Talvivaara mine in Finland, water isotopes and chemical composition were used to determine the extent of waste water contamination in groundwater systems after a leakage at gypsum ponds.

Abstract Illicit trade in gold, mainly sourced from South America and Africa, is used to fund criminal activities such as the drug trade. Laundering money through the purchase of illicit gold, then having it refined and being paid for in clean funds is a major problem, and drives further growth in illicit mining. In order to restrict the influx of illicit gold into the legal domain, it is necessary to be able to identify the traded item as being of a licit or illicit nature. The only way that this can be done with any certainty is by determining, from its chemical composition, the source of the gold and the means by which it has been processed and upgraded. The example dealt with here shows how the use of compositional, processing and geological knowledge is able to discriminate gold from different origins. Data derived from a physical sample is far better able to constrain the source than a paper trail of certification, which can be manipulated.

Abstract The largest UNESCO World Heritage Site in the UK is found in Cornwall and west Devon, and its designation is based specifically on its heritage for metalliferous mining, especially tin, copper and arsenic. With a history of over 2000 years of mining, SW England is exceptional in the nature and extent of its mining landscape. The mining for metallic ores, and more recently for kaolin, is a function of the distinctive geology of the region. The mining hazards that are encountered in areas of metallic mines are a function of: the Paleozoic rocks; the predominant steeply dipping nature of mineral veins and consequent shaft mining; the great depth and complexity of some of the mines; the waste derived from processing metallic ores; the long history of exploitation; and the contamination associated with various by-products of primary ore-processing, refining and smelting, notably arsenic. The hazards associated with kaolin mining are mainly related to the volume of the inert waste products and the need to maintain stable spoil tips, and the depth of the various tailings’ ponds and pits. The extent of mining in Cornwall and Devon has resulted in the counties being leaders in mining heritage preservation and the treatment and remediation of mining-related hazards.