Geological and geochemical characteristics of banded iron formations (BIFs) suggest that they formed by mixing locally (or regionally) discharged submarine hydrothermal fluids with local seawater, rather than by upwelling deep ocean water. Submarine hydrothermal fluids typically evolved from local seawater by acquiring heat, metals, and sulfur during deep circulation through a variety of rocks (e.g., volcanics, evaporites) in greenstone terranes that developed under a variety of tectonic settings. In general, when the fluids were heated above ∼350 °C, they may have produced Cu- and Zn-rich volcanogenic massive sulfide deposits (VMSDs), whereas those heated less than ∼200 °C were generally poor in H 2 S and heavy metals, except Fe, and may have subsequently produced BIFs. Depending on the salinity contrast between discharging hydrothermal fluids (evolved seawater) and local seawater, hydrothermal fluids may (1) mix rapidly with local seawater to form smoker-type BIFs or (2) create a metal- and silica-rich brine pool, mix slowly with the overlying water body, and form brine pool-type BIFs. BIFs associated with VMSDs and volcanic rocks generally belong to smoker-type BIFs; many formed at seawater depths >2.5 km. Large BIFs, including the 2.6–2.4 Ga BIFs in the Hamersley Basin, Australia, the 2.5 Ga Kuruman IF in South Africa, and the 1.87 Ga BIFs in the Lake Superior region, United States-Canada, belong to brine pool-type BIFs. The Hamersley Basin and possibly other large BIF-hosting basins were probably land-locked seas (like the Black Sea) where river waters diluted the surface water zone and the underlying water bodies were anoxic. During the accumulation of a BIF sequence, the dominant Fe mineralogy frequently changed from ferric (hydr)oxides (oxide BIFs) to siderite (carbonate BIFs) and to pyrite (sulfide BIFs). Such changes were probably caused by changes in the relative amounts of dissolved O 2 (DO), ΣCO 3 2− , and ΣS 2− in local seawater. From the Fe 2+ -O 2 mass balance calculations for the formation of iron oxides in smoker-type BIFs, and the relationship between the atmospheric pO 2 and oceanic O 2 depth profile, we conclude that the atmosphere and oceans have been fully oxygenated since ca. 3.8 Ga, except in local anoxic basins. Thermodynamic analyses of the formational conditions of siderite and analyses of the carbon isotopic composition of siderite associated with major BIFs suggest that the pre–1.8 Ga atmosphere was CO 2 -rich (pCO 2 >100 PAL) and CH 4 -poor (pCH 4 ≈ 10 ppm); therefore, CO 2 , rather than CH 4 , was the major greenhouse gas throughout geologic history. After a decline of hydrothermal fluid flux, BIF-hosting basins generally became euxinic (H 2 S-rich) because of the increased activity of sulfate-reducing bacteria (SRB) and SO 4 2− -rich seawater, and thereby accumulated organic carbon-rich and pyrite-rich black shales (sulfide-type BIFs). The SO 4 2− contents and SRB activity in the oceans have been essentially the same since ca. 3.8 Ga. The Archean oceans were most likely poor in both Fe 2+ and silica, much like modern oceans. Our study also suggests that diverse communities of organisms, including cyanobacteria, SRB, methanogens, methanotrophs, and eukaryotes, evolved very early in Earth's history, probably by the time the oldest BIFs (ca. 3.8 Ga) formed. BIFs have been found in rocks of all geologic age. Therefore, they cannot be indicators of an anoxic atmosphere and/or anoxic oceans as suggested by many previous researchers. Instead, BIFs indicate that the atmosphere and ocean chemistry have been regulated at present compositions (except pCO 2 ) through geologic history by interactions with the biosphere. The general trend of declining size and abundance of BIFs with geologic time reflects the cooling history of Earth's interior.

The Bryansk-Kursk-Voronezh intracontinental collisional orogen was formed by the juvenile Middle Paleoproterozoic assemblages in combination with Early Paleoproterozoic complexes and areas of reworked Archean crust. The crucial events fall in the time interval 2.1–2.0 Ga. The orogen includes a sequence of second-order, near-meridional orogens, which, in turn, consist of tectonic belts. From the west eastward, these are the Krivoi Rog–Bryansk orogen, the orogen of the Kursk magnetic anomaly (KMA), and the East Voronezh orogen. The latter may be regarded as an axial (central) structural element, which marks a transient rupture of the continental crust. The north to south extent of the orogen along the strike of the second-order orogens reaches 900 km long and ca. 900 km in width. The Krivoi Rog–Bryansk orogen consists of two groups of tectonic belts. Its western region is composed of tectonic nappes pertaining to the Kulazhino gneiss and the Bryansk granulite-gneiss belts. The eastern region, including the Krupetsk-Znamensk belt and the Meshchevsk system of tectonic sheets, with significant role of intensely deformed banded iron formations (BIF) of the Kursk and Oskol groups, is also the western imbricated margin of the Archean Kursk craton. The volcanic-sedimentary BIF belts play the main role in the structure of the KMA orogen. The second important component is composed of subvolcanic and plutonic mafic-ultramafic, felsic, and alkaline rock complexes. Granite-gneiss domes are related to the final stage of the orogen evolution. The East Voronezh orogen consists of the Lipetsk-Losevka volcanic-plutonic belt and the Vorontsovka imbricated thrust belt, separated by the Losevka-Mamon suture. The evolution of the Bryansk-Kursk-Voronezh orogen as a whole includes: onset of rifting within the Archean Kursk craton (2.59–2.53 Ga); terrigenous and chemical sedimentation including BIF and volcanic activity (2.5–2.10 Ga), periodically accompanied by emplacement of intrusions (2.6–2.5 Ga and 2.1–2.05 Ga); metamorphism under granulite-facies conditions in the Kulazhino and Bryansk belts at 2.13 Ga and in the Vorontsovka belt at 2.10 Ga; intrusive magmatism in the Vorontsovka belt generally synchronous with high-temperature metamorphism; suprasubduction magmatism and formation of the Lipetsk-Losevka volcanic-plutonic belt 2.10–2.05 Ga ago; the collision-related reverse and thrust faulting and folding in the BIF belts accompanied by westward and south-westward overturning; rheomorphism and formation of granite-gneiss and granite-migmatite domes deforming the fold-nappe assemblages in the BIF belts of KMA; and the tectonothermal activity of postcollisional and anorogenic stages (2.07–1.9 Ga) expressed by emplacement of alkaline ultramafic and gabbro-syenite intrusions in the Lipetsk-Losevka belt and its hinterland. The most active phase of tectonic evolution spanned the time interval 2.1–2.0 Ga, which was no less than 100 Ma long and coincided with the active stage of extension, sedimentation, and high-temperature metamorphism in the northern part of the East European craton.

Black shales and Mn carbonates interbedded with glacial deposits from the Neoproterozoic of southern China exhibit extremely heavy values of pyrite S isotopes that may reflect the peculiar environment of Earth at this time. δ 34 S averages +30‰ at Tanganshan and +44‰ at Xiangtan, compared with typical values of 0‰ to +5‰ found in younger deposits. Furthermore there is no distinction between the shales and the Mn carbonate ores in the Neoproterozoic, unlike the younger deposits, which show much lighter δ 34 S in the shales than in the Mn ores (the spread is 25‰). Most other chemical parameters are very similar to both the younger Mn deposits and those from the Paleoproterozoic. The exception is the rare earth elements (REE). All Neoproterozoic Fe ores and most Neoproterozoic Mn ores lack the positive Eu anomaly that characterizes Archean and Paleoproterozoic Fe-Mn accumulations. On the other hand, Neoproterozoic Mn deposits have positive Ce anomalies on North American Shale Composite (NASC) normalized plots, in contrast to other MnCO 3 ores. The ΣREE is also higher than in other Mn deposits, but lower than in modern deep-sea crusts. Sulfide S values in all Neoproterozoic shales tend to be exceptionally variable and to often show much heavier values than can be found in marine strata from the Phanerozoic. Therefore the anomalous δ 34 S values we observed reflect peculiar conditions in the world oceans at this time rather than purely local effects. Times of enrichment of seawater sulfate in 34 S do not correspond to periods of glaciation, so the likely cause of the S isotope patterns is not worldwide glaciation, but a generally low level of dissolved sulfate S in the Neoproterozoic oceans that allowed modest increases in the amounts of S removed as pyrite to drive down the oceanic S reservoir enough to produce strong Rayleigh reservoir effects. The abundance worldwide of Sturtian-age Mn and Fe deposits indicates an increase in Fe flux to the oceans that would have been sufficient to depress SO 4 2- levels severely and to result in residual dissolved S extremely enriched in 34 S. REE evidence indicates that most of this enhanced Fe and Mn flux came from diagenetic remobilization of detrital oxides rather than from ridge-crest hydrothermal systems, in contrast to the Paleoproterozoic banded iron formations. Rapid introduction of lateritic soil residues to restricted basins by low-latitude glaciation could have provided the needed excess Fe and Mn to drive this system.

Four cherts sampled in the East Pilbara craton (Western Australia) at Marble Bar (Towers Formation), North Pole Dome (Dresser and Apex Basalt Formation), and Kittys Gap (Panorama Formation) were studied for micro- and nanomineralogy and geochemistry to determine their protoliths and to provide new insights on the physico-chemical and biological conditions of their depositional environments. The Marble Bar chert was formed at the interface with a basaltic rock. Hydrothermal fluids leached major and trace elements from the basalt and silicified the protolith of this chert. The elements Fe, Mn, Si, Ca, Mg, REE, Au, Pd, Cr, and Ni precipitated as a microbanded iron formation (BIF) under reducing and alkaline conditions. The chert is composed of magnetite, carbonates, and quartz and forms a stromatolite-like structure. Later oxidizing fluids replaced magnetite and carbonates with Fe-Mn oxyhydroxides. They show vermicular microtextures and filamentous nanotextures. Each filament is composed of euhedral nanoscopic hematite. These oxides contain several thousands of ppm of N and C, and measured C/N ratios are similar to those observed in organic matter preserved in marine sediments, thus suggesting an organic activity. Two black cherts from hydrothermal dykes of the North Pole Dome are interpreted as having had a black shale precursor, based on the REE (rare earth elements) and trace metal characteristics. These rocks were probably entrained into the dykes and hydrothermally overprinted. Although these two cherts had the same history, the physico-chemical conditions differed during their formation. The chert from the chert-barite unit of the Dresser Formation was formed under reducing and alkaline conditions. This is clearly indicated by clusters of nanosulfide spherules replacing precursor minerals; weblike Fe-sulfides intergrown with sphalerite; As-pyrite and vaesite; and the presence of carbonates. The black chert from the Apex Basalt Formation was formed under oxidizing conditions, as indicated by clusters of nanospherules of Fe-oxides and a negative Ce anomaly. A black and white laminated chert from Kittys Gap was formed in a shallow marine to subaerial environment, by silicification of a rhyodacitic volcaniclastic rock. This process was accompanied by the development of microbial mats on the sediment surfaces and the formation of microbial colonies around precursor K-feldspars, Ti-bearing biotites, amphiboles, and ghost spherulites. The environment was slightly oxidizing, as indicated by the negative Ce anomaly and the presence of Ti-oxides. The presence of K-bearing phyllosilicates rather than K-feldspars indicates that the environment was also slightly acidic. Elevated Cu and Zn contents in the black laminae point to a limited influence from hydrothermal fluids. The silica probably originated mainly from alteration of the minerals of the volcaniclastic rock due to diagenetic alteration by seawater.