Abstract δ 2 H and δ 18 O values of precipitations follow an empirical linear relationship at the global scale that is called the Global Meteoric Water Line (GMWL) and characterized by a slope of 8. However, Local Meteoric Water Lines (LMWLs) may have different slopes S depending on their geographic situation. Monthly δ 2 H and δ 18 O of precipitation have been compiled from European International Atomic Energy Agency (IAEA) stations. Those data allowed the calculation of the slopes S of the δ 2 H– δ 18 O LMWL determined for each station. S increases with longitude ϕ from c. 5 (Portugal) to c. 9 (Russia) – they are positively correlated with relative humidity (RH), negatively with temperature and positively with the mean intra-annual amplitude of temperatures, which is a proxy of continentality. Slopes of 5–6, recorded in SW Europe, reflect mean RH (70–75%) and sea surface temperatures ( c. 25°C) of the Central Atlantic Ocean where the main flux of moisture is formed before being transported by the westerlies. In addition, falling water droplets within an air column with a high RH (>80%) and low temperature are expected to escape sub-cloud evaporation. Therefore, slopes with values close to 9 are considered to reflect isotopic equilibrium conditions during the condensation of water vapour in clouds.

Abstract In this chapter, we analyse the influence of the Carpathian Mountains on the variability of stable isotopes in precipitation by employing a combination of observed and model data. Overall, the mean value of the stable isotopes in precipitation over the Carpathian Mountains, based on observational data, was −9.8‰ for δ 18 O and −68.6‰ for δ 2 H. The local meteoric line, using all samples from the study sites, was δ 2 H = 7.65 × δ 18 O + 5.82. The simulated δ 18 O, based on the ECHAM5-wiso isotopes enable model, showed good agreement with the observed isotopic data. By comparing all the monthly values of the observed isotopic data from all analysed stations and the corresponding model data, a correlation coefficient of 0.76 ( n = 455, p < 0.001) was obtained. The spatial distribution of the simulated δ 18 O values in precipitation had the lowest values over the Romanian Carpathian Mountains and the highest values over the extra-Carpathian area, with the maximum in southeastern Romania. This pattern was strongly influenced by the Carpathian Mountains orography. Using the simulated δ 18 O data, we show that the spatial distribution of the δ 18 O values increases with temperature and decreases with altitude and latitude (−0.5‰ for δ 18 O per degree of latitude). The continental gradient is characterized by a polynomial trend of the second degree in the form of a large-open ‘U’ shape, and the general pattern of the δ 18 O values follows the spatial distribution of the Carpathian Mountains.

Abstract The measurement of stable water isotopes (i.e. δ 18 O and δ 2 H) in precipitation is a powerful tool for detecting changes in climate patterns, assessing groundwater movements and studying the hydrological budget. In this study, daily precipitation was collected and δ 18 O and δ 2 H were analysed in Corner Brook, western Newfoundland, and Labrador, for 2015. The study provides the first background data of any kind related to liquid water isotopes in western Newfoundland. More than 130 samples were analysed using a state-of-the-art cavity ring-down spectrometer, the Picarro Liquid Water Isotope Analyzer L2130-i, with a minimal instrumental error. The data suggest seasonal variations in which the δ 18 O varies from −33.4 to −0.03‰ (±0.023‰) and δ 2 H ranges from −253.4 to 15.1‰ (±0.148‰). Our data are compared with modern meteorological data and publicly available δ 18 O and δ 2 H data from greater Atlantic Canada, which suggests that the atmospheric circulation patterns, spatial features and other climate factors are distinct in Corner Brook. Isotopes in meteorological precipitation data referenced and collected in this study reflect the cool, wet climate and air-mass fluctuations unique to the geographical region and thus, this baseline is fundamental to understanding the modern isotope hydrological/climatic studies for this region.

Abstract To investigate the influence of local climate and transboundary circulation of moisture on the stable isotope of precipitation in Ramnicu Valcea, Romania, monthly values of δ 2 H, δ 18 O, deuterium excess (d excess ), temperature, relative humidity and precipitation were determined between January 2012 and December 2018. Monthly analysis showed differences in d excess varying between 24.2‰ (October 2015) and −23.7‰ (July 2013) with a multi-annual average of 6.1 ± 5.9‰, suggesting an Atlantic origin of moisture with episodic Mediterranean transport. Also a significant correlation between the North Atlantic Oscillation on the local temperature during winter season was noticed. The local meteoric water line (LMWL) for the entire period showed slope and intercept values similar to those for neighbouring localities with the same altitude. When the analysis was extended to summer (April–October) and winter (November–March) seasons, the LMWL slope and intercept were different, reflecting the summer–winter difference in temperatures and air circulation. The monthly values of all parameters formed equal-spaced time series whose detailed analysis confirmed at p < 0.01 that δ 2 H, δ 18 O, temperature and relative humidity show a well-evidenced one-year periodicity. In contrast, precipitation and d excess seasonality were almost unrecognizable, most probably owing to the reduced number of observations.

Abstract Stable isotope ratios of cave bat guano reflect environmental influences at the soil and plant level within the foraging range of the bats. Carbon, nitrogen and hydrogen isotopes have utility in reconstructing precipitation and temperature as well as in tracing the influence of large-scale atmospheric circulation and climate variability. Guano-derived stable isotope time series have been demonstrated to effectively provide high-resolution records of palaeoenvironmental variation from the late Pleistocene to present. Owing to their influence on these isotopes, factors such as bat ecology, species foraging range and site location must be considered when interpreting such records. Research analysing the isotopic composition of guano has provided a highly resolved history of vegetation and climate dynamics previously less understood. In this chapter we discuss the factors influencing the δ 13 C, δ 15 N and δ 2 H values in guano and provide an up-to-date review of cave guano as palaeo-climate archive.

ABSTRACT Shorelines formed by terminal lakes record past changes in regional moisture budgets. In the western Great Basin of North America, winter precipitation accounts for nearly half of the annual total and is well correlated with northeast Pacific storm track activity and moisture transport. We evaluated these relationships and found that historical precipitation between 1910 and 2012 was better correlated to moisture transport (0.78, p < 0.01) than to storm track activity (0.54, p < 0.01) because moisture transport better captures dynamics associated with the Sierra Nevada rain shadow. We derived modern analogs of enhanced and reduced storm track activity and moisture transport from reanalysis products and used associated winter precipitation anomalies with these analogs as inputs to a coupled water balance and lake evaporation model of the Walker Lake basin. Simulated lake-level responses were compared with a radiocarbon-dated lakeshore chronology spanning the past 3700 yr. Wet analogs developed from winters in the 90th and 75th percentiles for storminess and moisture transport produced lake levels that exceeded estimated late Holocene highstands by 50 m. Dry analogs (10th and 25th percentiles) produced lake levels corresponding to Medieval megadrought lowstands. The twentieth century is shown to be as wet as any century in the past 3700 yr. Our results demonstrate the sensitivity of terminal lakes to winter season circulations and highlight the value of using moisture transport as a predictor of cool season precipitation and to evaluate how past or future changes in regional circulations will influence the water balance of dryland regions.