ABSTRACT The late Eocene Florissant Formation in central Colorado is a rich and diverse continental Lagerstätte yielding well-preserved fossil assemblages from lacustrine and fluvial facies. This investigation focused on the lacustrine facies at Clare’s Quarry and used biotic and abiotic evidence to characterize aspects of the lake and processes that resulted in the accumulation and preservation of the host rock and its fossils. Autecology of modern analogs representing the fossil diatom taxa was used to augment sedimentary data in characterizing the lake, propose peripheral habitats within the catchment area, and suggest a terrestrial source for mudstone units. The sedimentary and stratigraphic record at the study site reveals a lake with sufficient depth to allow bottom waters to remain isolated and anoxic for long periods. Sediments that accumulated in the lake produced distinct lacustrine lithofacies that are interpreted as representing at least three modes of origin: stable lake, pyroclastic, and mud turbidite sedimentation. Slow, suspension settling of fine clays and volcanic ash into a moderately deep, stable lake resulted in laminated shales. These laminated shales contain frustules of diatoms from planktic and benthic lake habitats; diatoms transported into the lake from streams and wetlands; fish, mollusks, ostracods, and insects; and plants from marginal and upslope environments. Intermittent volcanic eruptions produced air-fall ash and granular tuff that accumulated as interbeds within the lake shales. Periods of stable lake sedimentation were frequently interrupted by rapid influxes of suspended fine clays, perhaps as mud-dominated turbidites that prograded into the lake at intervals of high runoff triggered by climatic, volcanic, or tectonic events.

ABSTRACT More than 100 air-fall volcanic tephra beds are currently documented from Devonian strata in the eastern United States. These beds act as key sources of various geological data. These include within-basin to basin-to-basin correlation, globally useful geochronologic age dates, and a relatively detailed, if incomplete, record of Acadian–Neoacadian silicic volcanism. The tephras occur irregularly through the vertical Devonian succession, in clusters of several beds, or scattered as a few to single beds. In this contribution, their vertical and lateral distribution and recent radiometric dates are reviewed. Current unresolved issues include correlation of the classic Eifelian-age (lower Middle Devonian) Tioga tephras and dates related to the age of the Onondaga-Marcellus contact in the Appalachian Basin. Here, we used two approaches to examine the paleovolcanic record of Acadian–Neoacadian silicic magmatism and volcanism. Reexamination of volcanic phenocryst distribution maps from the Tioga tephras indicates not one but four or more volcanic sources along the orogen, between southeastern Pennsylvania and northern North Carolina. Finally, radiometric and relative ages of the sedimentary basin tephras are compared and contrasted with current radiometric ages of igneous rocks from New England. Despite data gaps and biases in both records, their comparisons provide insights into Devonian silicic igneous activity in the eastern United States, and into various issues of recognition, deposition, and preservation of tephras in the sedimentary rock record.

Dr. John M. Dennison spent his career studying the Appalachians; teaching and mentoring his students and professional colleagues; publishing papers; leading field trips; and presenting ideas at regional, national, and international conferences. This volume is a collection of papers contributed by former students and colleagues to honor his memory. Topics include stratigraphy and paleontology ranging in age from Ordovician to Mississippian in Kentucky, New York, Tennessee, Virginia, and West Virginia; Devonian airfall tephras throughout the eastern United States; a Devonian lonestone; a Middle Eocene bentonite in North Carolina and its relationship to a volcanic swarm in western Virginia; and a 3D model of a ductile duplex in northwestern Georgia. The stratigraphic and geologic diversity of the papers reflects Dennison's many interests and collaborative relationships.

ABSTRACT Stratigraphic, geochemical, and biomarker data from the Huallaga Basin suggest that organic carbon-rich shales and limestones of the Upper Triassic to Lower Jurassic Aramachay Formation of the Pucará Group, previously identified as potential hydrocarbon source rocks in Peruvian sub-Andean basins, were deposited under low oxygen or anoxic conditions within a semirestricted basin. Rock-Eval and total organic carbon (TOC) data from surface and subsurface locations show that although most Aramachay Formation shale and limestone outcrop samples have relatively high organic carbon content, the unit has little remaining genetic potential; T max data indicate that the thermal maturity of nearly all outcrop samples ranges from wet to dry gas. Visual kerogen analyses show that type II amorphous kerogen is the dominant type in the Aramachay Formation. Cretaceous rocks within the Huallaga Basin are dominated by type II/III and type III kerogen and generally lack sufficient TOC to be effective source rocks for oil. Geochemical and biomarker data indicate that rock extracts and seep oils were derived from mixed shale and carbonate source facies dominated by marine algal and bacterial organic matter and are similar to “Jurassic” oils described from the Marañon and northwestern Ucayali Basins. Hydrocarbon generation and expulsion models suggest that the generation and expulsion of oil from the Aramachay Formation (likely the middle Aramachay Formation) began from west to east in the Huallaga Basin, starting in the now-exhumed western part of the basin during the Early Cretaceous, extending through the middle Oligocene in the central part of the basin and into the Present in the eastern part of the basin. Estimates of vitrinite reflectance (R o ) based on biomarker data indicate that Marañon Basin oils derived from the Aramachay Formation were likely generated during the peak oil phase of generation; oils in the northwestern Ucayali Basin were generated during the late oil phase of generation. Petroleum extracts from outcrop samples in the northern part of the basin and oils from seeps along the southeastern frontal thrust of the basin indicate a late oil level of thermal exposure. Migration of oils into the Marañon and northwestern Ucayali Basins likely occurred prior to the early Pliocene, when formation of the Andean frontal thrust cut off migration routes from the Huallaga Basin.

The Contessa Valley and the Bottaccione Gorge located close to Gubbio (central Italy) include some of the most complete successions of Paleogene sediments known from the Tethyan realm. Owing to the continuous deposition in a pelagic setting, a rather modest tectonic overprint, and the availability of excellent age control through magnetostratigraphy, biostratigraphy, chronostratigraphy, and tephrostratigraphy, and direct radioisotopic dates from interbedded volcaniclastic layers, these sediments have played a prominent role in the establishment of standard Paleogene time scales. We present here a complete and well-preserved Paleogene pelagic composite succession of the Gubbio area that provides the means for a more accurate and precise calibration of the Paleogene time scale. As a necessary step toward the compilation of a more robust database on a wide scale so to improve the magnetostratigraphic, biostratigraphic, and chronostratigraphic framework of the classical Tethyan zonations, enabling regional and supraregional correlations, we have constructed a record of reliable Paleogene planktonic foraminifera, calcareous nannofossil, and dinocyst biohorizons commonly used in tropical to subtropical Cenozoic zonations. In addition, an age model is provided for the Paleogene pelagic composite succession based on magnetostratigraphy, planktonic foraminifera, calcareous nannofossils, and dinocysts that contributes to an integrated chronology for the Paleogene Tethyan sediments from 66 to 23 Ma.

The Late Jurassic (157–150 Ma) Morrison Formation of the Western Interior of the United States contains abundant altered volcanic ash. On the Colorado Plateau, this formation accumulated behind and downwind of a subduction-related volcanic arc along the western margin of North America. The ash in these distal fallout tuffs probably drifted eastward from coignimbrite ash clouds related to collapse calderas. Altered volcanic ash is particularly abundant in the Brushy Basin Member of the upper part of the Morrison Formation. In one 110-m-thick section in eastern Utah, 35 separate beds were deposited in a 2.2 m.y. period. Alteration occurred when glassy volcanic ash fell into fluvial and lacustrine environments, where it was diagenetically altered to various mineral assemblages but most commonly to smectitic clay. Periodically, ash fell into saline, alkaline lakes, and diagenetic alteration of the glassy ash produced a crudely zoned deposit on the Colorado Plateau. Altered volcanic ash beds in the outermost part of the lacustrine deposits are argillic (with smectitic clay), whereas zeolitic (clinoptilolite, analcime) and feldspathic (K-feldspar and albite) alteration dominates the interior zones. Feldspathic ash layers contain secondary silica, and consequently immobile element (e.g., Al, Ti, and high field strength elements) abundances were strongly diluted in these rocks. In contrast, the argillic ash beds experienced strong SiO 2 depletion, and, as a result, they are enriched in the relatively immobile elements. The compositions of the zeolitic ash beds are intermediate between these two extremes and experienced the least alteration. As a result of these changes, immobile element concentrations are less reliable than ratios for determining the original magmatic composition of the ash. Most of the altered ash (regardless of type) was also depleted in water-soluble elements like the alkalies, U, and V. The latter two elements were oxidized during diagenesis of the ash, became soluble, and were partially leached away by groundwater. Locally, U and V in groundwater were reduced upon contact with organic materials and formed important ore deposits. Several aspects of the mineralogy and geochemistry of the altered volcanic ash beds yield information about their original magmatic compositions. The volcanic ash beds typically have small phenoclasts of quartz, sanidine, plagioclase, biotite, zircon, apatite, and Fe-Ti oxides. Titanite is present in ∼40% of the ash beds; pyroxene and amphibole were found in less than 5%. Phenocryst assemblages, mineral compositions, inferred high f O 2 , rare earth element patterns, and immobile element ratios all suggest the parent magmas for the altered tuffs were subduction-related dacites and rhyolites. Small numbers of tuffs have Fe-rich biotite, amphibole, and/or clinopyroxene; both pyroxene and amphibole are alkali rich. These tuffs lack titanite, but some contain anorthoclase and F-rich apatite. Combined with enrichments in Nb and Y, these features show some tuffs had an A-type character and were related to some type of within-arc extension. Paleowind directions, and distribution, radiometric ages, and compositions of the volcanic ash beds and of plutons in the western United States suggest that the most likely eruption sites were in the subduction-related Jurassic magmatic arc, which extended across western Utah and central Nevada and southward into the Mojave of California and southern Arizona (present-day coordinates). Pb isotopic compositions show that at least some of the ash was erupted from magma systems (now exposed as plutons) in the Mojave Desert. We conclude that a brief ignimbrite flare-up from 157 to 150 Ma, but focused on the time period from 152 to 150 Ma, in this region may have been driven by slab steepening and conversion to a strike-slip boundary after a preceding phase of folding and thrusting. The presence of ash beds with A-type characteristics mixed with those that have more typical subduction signatures confirms that the Late Jurassic was geologically a transitional time in North America when subduction was changing to transtensional movement along the western plate boundary.