ABSTRACT Three Silurian basin fills, the Llandovery–Wenlock Croagh Patrick and Killary Harbour–Joyce Country successions and the Ludlow–Pridoli Louisburgh–Clare Island succession, overstep the tectonic contacts between elements of the Grampian (Taconic) accretionary history of the Caledonian-Appalachian orogeny in western Ireland. New U-Pb detrital zircon data from lower strata of these Silurian rocks provide insight into basin evolution and paleogeography. The shallow-marine Croagh Patrick succession unconformably overlies the Clew Bay Complex and the northern part of the Ordovician South Mayo Trough. Two samples have zircon populations dominated by Proterozoic grains typical of the Laurentian margin, with few younger grains. Up to 13% of the grains form a cluster at ca. 950–800 Ma, which is younger than known Grenville magmatism on the local Laurentian margin and older than known magmatism from Iapetan rifting; these may be recycled grains from Dalradian strata, derived from distal Tonian intrusions. The Killary Harbour–Joyce Country succession overlies the structural contact between the Lough Nafooey arc and the Connemara Dalradian block and records a transgressive-regressive cycle. Four samples of the Lough Mask Formation show contrasting age spectra. Two samples from east of the Maam Valley fault zone, one each from above Dalradian and Nafooey arc basement, are dominated by Proterozoic grains with ages typical of a Laurentian or Dalradian source, likely in north Mayo. One sample also includes 8% Silurian grains. Two samples from west of the fault overlie Dalradian basement and are dominated by Ordovician grains. Circa 450 Ma ages are younger than any preserved Ordovician rocks in the region and are inferred to represent poorly preserved arc fragments that are exposed in northeastern North America. Cambrian to late Neoproterozoic grains in association with young Ordovician ages suggest derivation from a peri-Gondwanan source in the late stages of Iapetus closure. The Louisburgh–Clare Island succession comprises terrestrial red beds. It unconformably overlies the Clew Bay Complex on Clare Island and is faulted against the Croagh Patrick succession on the mainland. The Strake Banded Formation yielded an age spectrum dominated by Proterozoic Laurentian as well as Ordovician–Silurian ages. Although the basin formed during strike-slip deformation along the Laurentian margin in Ireland and Scotland, sediment provenance is consistent with local Dalradian sources and contemporaneous volcanism. Our results support ideas that Ganderian continental fragments became part of Laurentia prior to the full closure of the Iapetus Ocean.

ABSTRACT In 1935, Krynine postulated that first-cycle arkose in the humid tropical setting of southern Mexico can be rapidly eroded with minimal chemical weathering and redeposited as second-cycle arkose. Modern quantitative data confirm this hypothesis and highlight exceptions where first-cycle arkosic sediments have been diagenetically altered by intense weathering to yield second-cycle quartz arenites. In this study, extensive sampling of upland source rocks and their derived sediments provided a robust data set with which to quantitatively evaluate the composition and provenance of Holocene sediments. Three upland source terrains were identified: Paleozoic crystalline basement of the Chiapas Massif; Mesozoic to Cenozoic siliciclastic and carbonate rocks of the Chiapas fold belt; and Cenozoic sedimentary rocks in the foothills of the fold belt. Holocene sediments from these source terrains are grouped into seven facies (A–G) based on their provenance and geographic location. Facies A consists of feldspathic sediments from the Mezcalapa-Grijalva River that are sourced from the Chiapas Massif. Facies B consists of lithic-rich sediments from the same area that are derived from the Chiapas fold belt. Facies A and B consist predominantly of first-cycle sand capable of yielding arkosic deposits. Facies C represents a mixture of Facies A and B sands deposited along the course of the Mezcalapa-Grijalva River. Facies D (from Rio Sierra) and Facies E (from Rio Pedregal) represent second-cycle feldspathic sands of the coastal-plain delta and were derived from Cenozoic sedimentary rocks of the foothills. Mild chemical weathering due to rapid mechanical erosion enabled the creation of these arkosic deposits. They are less feldspathic than their parents and have limited occurrence due to mixing with less feldspathic first-cycle sands downstream from their sources. Facies F (from Rio Zanapa) and Facies G (from Lagunas Rosario and Enmedio) represent second-cycle quartzose sands of the low-lying savanna that were also derived from Cenozoic sedimentary rocks in the foothills of the fold belt. Intense, long-term (>10,000 yr) chemical weathering of these sands has precluded the formation of arkoses, instead yielding quartz arenites. They are more weathered than the delta sands (Facies D, E) with a greater loss of feldspar and carbonate detritus. They are enriched in silica and depleted in alumina, CaO, Na 2 O, and K 2 O relative to Facies A arkoses due to loss of feldspars and mafic minerals. Second-cycle sediments eroded from Tertiary sedimentary rocks in the foothills (Facies D–G) contain detrital serpentine and chromite with high abundances of Cr and Ni, suggesting an ultramafic component in their provenance. Cr and Ni are effective tracers for second-cycle components in sands of mixed provenance.

Abstract: The Vedder (Oligocene) and Kreyenhagen (Eocene) sandstones at the Greeley oil field consist of arkosic to subarkosic arenites and wackes deposited in shallow marine environments. Burial depths of the Vedder sandstones exceed 3150 m and the reservoir temperature is 124°C. The Kreyenhagen sandstones are buried to greater than 3920 m and the reservoir temperature is estimated to be c. 135°C. These sandstones are currently at or very near their deepest burial depths. The textural relationships of the diagenetic minerals suggest syndepositional formation of glauconite, phosphate and pyrite, followed by early precipitation of pore-lining clay coatings and carbonate cements along with framework-grain fracturing and possibly dissolution. With increasing burial, dissolution of the framework grains continued, accompanied by the albitization of feldspars, the formation of K-feldspar and quartz overgrowths, the precipitation of kaolinite and other clays and possibly the precipitation of late carbonate cements. Finally, hydrocarbon migration and the formation of pyrite occurred during late diagenesis. Porosity preservation and reservoir quality are primarily the result of plagioclase dissolution occurring as the strata approached their current burial depths. Mass balance calculations indicate the significant export of aluminium out of the sands. Thus secondary porosity produced by plagioclase dissolution has replaced the primary porosity destroyed by compaction, and now accounts for the majority of the porosity in these rocks.