ABSTRACT The late early to middle Miocene period (18–12.7 Ma) was marked by profound environmental change, as Earth entered into the warmest climate phase of the Neogene (Miocene climate optimum) and then transitioned to a much colder mode with development of permanent ice sheets on Antarctica. Integration of high-resolution benthic foraminiferal isotope records in well-preserved sedimentary successions from the Pacific, Southern, and Indian Oceans provides a long-term perspective with which to assess relationships among climate change, ocean circulation, and carbon cycle dynamics during these successive climate reversals. Fundamentally different modes of ocean circulation and carbon cycling prevailed on an almost ice-free Earth during the Miocene climate optimum (ca. 16.9–14.7 Ma). Comparison of δ 13 C profiles revealed a marked decrease in ocean stratification and in the strength of the meridional overturning circulation during the Miocene climate optimum. We speculate that labile polar ice sheets, weaker Southern Hemisphere westerlies, higher sea level, and more acidic, oxygen-depleted oceans promoted shelf-basin partitioning of carbonate deposition and a weaker meridional overturning circulation, reducing the sequestration efficiency of the biological pump. X-ray fluorescence scanning data additionally revealed that 100 k.y. eccentricity-paced transient hyperthermal events coincided with intense episodes of deep-water acidification and deoxygenation. The in-phase coherence of δ 18 O and δ 13 C at the eccentricity band further suggests that orbitally paced processes such as remineralization of organic carbon from the deep-ocean dissolved organic carbon pool and/or weathering-induced carbon and nutrient fluxes from tropical monsoonal regions to the ocean contributed to the high amplitude variability of the marine carbon cycle. Stepwise global cooling and ice-sheet expansion during the middle Miocene climate transition (ca. 14.7–13.8 Ma) were associated with dampening of astronomically driven climate cycles and progressive steepening of the δ 13 C gradient between intermediate and deep waters, indicating intensification and vertical expansion of ocean meridional overturning circulation following the end of the Miocene climate optimum. Together, these results underline the crucial role of the marine carbon cycle and low-latitude processes in driving climate dynamics on an almost ice-free Earth.

Abstract The Antarctic Peninsula is distinguished by late Neogene volcanic activity related to a series of northerly younging ridge crest–trench collisions and the progressive opening of ‘slab windows’ in the subjacent mantle. The outcrops were amongst the last to be discovered in the region, with many occurrences not visited until the 1970s and 1980s. The volcanism consists of several monogenetic volcanic fields and small isolated centres. It is sodic alkaline to tholeiitic in composition, and ranges in age between 7.7 Ma and present. No eruptions have been observed (with the possible, but dubious, exception of Seal Nunataks in 1893) but very young isotopic ages for some outcrops suggest that future eruptions are a possibility. The eruptions were overwhelmingly glaciovolcanic and the outcrops have been a major source of information on glaciovolcano construction. They have also been highly influential in advancing our understanding of the configuration of the Plio-Pleistocene Antarctic Peninsula Ice Sheet. However, our knowledge is hindered by a paucity of modern, precise isotopic ages. In particular, there is no obvious relationship between the age of ridge crest–trench collisions and the timing of slab-window volcanism, a puzzle that may only be resolved by new dating.

Abstract Nineteen large (2348–4285 m above sea level) central polygenetic alkaline shield-like composite volcanoes and numerous smaller volcanoes in Marie Byrd Land (MBL) and western Ellsworth Land rise above the West Antarctic Ice Sheet (WAIS) and comprise the MBL Volcanic Group (MBLVG). Earliest MBLVG volcanism dates to the latest Eocene (36.6 Ma). Polygenetic volcanism began by the middle Miocene (13.4 Ma) and has continued into the Holocene without major interruptions, producing the central volcanoes with 24 large (2–10 km-diameter) summit calderas and abundant evidence for explosive eruptions in caldera-rim deposits. Rock lithofacies are dominated by basanite and trachyte/phonolite lava and breccia, deposited in both subaerial and ice-contact environments. The chronology of MBLVG volcanism is well constrained by 330 age analyses, including 52 new 40 Ar/ 39 Ar ages. A volcanic lithofacies record of glaciation provides evidence of local ice-cap glaciation at 29–27 Ma and of widespread WAIS glaciation by 9 Ma. Late Quaternary glaciovolcanic records document WAIS expansions that correlate to eustatic sea-level lowstands (MIS 16, 4 and 2): the WAIS was +500 m at 609 ka at coastal Mount Murphy, and +400 m at 64.7 ka, +400 m at 21.2 ka and +575 m at 17.5 ka at inland Mount Takahe.

Abstract In Marie Byrd Land and Ellsworth Land 19 large polygenetic volcanoes and numerous smaller centres are exposed above the West Antarctic Ice Sheet along the northern flank of the West Antarctic Rift System. The Cenozoic (36.7 Ma to active) volcanism of the Marie Byrd Land Volcanic Group (MBLVG) encompasses the full spectrum of alkaline series compositions ranging from basalt to intermediate (e.g. mugearite, benmoreite) to phonolite, peralkaline trachyte, rhyolite and rare pantellerite. Differentiation from basalt is described by progressive fractional crystallization; however, to produce silica-oversaturated compositions two mechanisms are proposed: (1) polybaric fractionation with early-stage removal of amphibole at high pressures; and (2) assimilation–fractional crystallization to explain elevated 87 Sr/ 86 Sr i ratios. Most basalts are silica-undersaturated and enriched in incompatible trace elements (e.g. La/Yb N >10), indicating small degrees of partial melting of a garnet-bearing mantle. Mildly silica-undersaturated and rare silica-saturated basalts, including tholeiites, are less enriched (La/Yb N <10), a result of higher degrees of melting. Trace elements and isotopes (Sr, Nd, Pb) reveal a regional gradient explained by mixing between two mantle components, subduction-modified lithosphere and HIMU-like plume ( 206 Pb/ 204 Pb >20) materials. Geophysical studies indicate a deep thermal anomaly beneath central Marie Byrd Land, suggesting a plume influence on volcanism and tectonism.

Abstract Driven by successful achievements in recovering high-resolution ice records of climate and atmospheric composition through the Late Quaternary, new ice–tephra sequences from various sites of the East Antarctic Ice Sheet (EAIS) have been studied in the last two decades spanning an age range of a few centuries to 800 kyr. The tephrostratigraphic framework for the inner EAIS, based on ash occurrence in three multi-kilometre-deep ice cores, shows that the South Sandwich Islands represent a major source for tephra, highlighting the major role in the ash dispersal played by clockwise circum-Antarctic atmospheric circulation penetrating the Antarctic continent. Tephra records from the eastern periphery of the EAIS, however, are obviously influenced by explosive activity sourced in nearby Antarctic rift provinces. These tephra inventories have provided a fundamental complement to the near-vent volcanic record, in terms of both frequency/chronology of explosive volcanism and of magma chemical evolution through time. Despite recent progress, current data are still sparse. There is a need for further tephra studies to collect data from unexplored EAIS sectors, along with extending the tephra inventory back in time. Ongoing international palaeoclimatic initiatives of ice-core drilling could represent a significant motivation for the tephra community and for Quaternary Antarctic volcanologists.

Abstract Two volcanoes in Marie Byrd Land, Mount Berlin and Mount Takahe, can be considered active, and a third, Mount Waesche, may be as well; although the chronology of activity is less well constrained. The records of explosive activity of these three volcanoes is well represented through deposits on the volcano flanks and tephra layers found in blue ice areas, as well as by the presence of cryptotephra layers found in West and East Antarctic ice cores. Records of effusive volcanism are found on the volcano flanks but some deposits may be obscured by pervasive glacerization of the edifices. Based on a compilation of tephra depths–ages in ice cores, the activity patterns of Mount Takahe and Mount Berlin are dramatically different. Mount Takahe has erupted infrequently over the past 100 kyr. Mount Berlin, by contrast, has erupted episodically during this time interval, with the number of eruptions being dramatically higher in the time interval between c. 32 and 18 ka. Integration of the Mount Berlin tephra record from ice cores and blue ice areas over a 500 kyr time span reveals a pattern of geochemical evolution related to small batches of partial melt being progressively removed from a single source underlying Mount Berlin.

Abstract A combination of aerogeophysics, seismic observations and direct observation from ice cores, and subglacial sampling, has revealed at least 21 sites under the West Antarctic Ice Sheet consistent with active volcanism (where active is defined as volcanism that has interacted with the current manifestation of the West Antarctic Ice Sheet). Coverage of these datasets is heterogeneous, potentially biasing the apparent distribution of these features. Also, the products of volcanic activity under thinner ice characterized by relatively fast flow are more prone to erosion and removal by the ice sheet, and therefore potentially under-represented. Unsurprisingly, the sites of active subglacial volcanism that we have identified often overlap with areas of relatively thick ice and slow ice surface flow, both of which are critical conditions for the preservation of volcanic records. Overall, we find the majority of active subglacial volcanic sites in West Antarctica concentrate strongly along the crustal-thickness gradients bounding the central West Antarctic Rift System, complemented by intra-rift sites associated with the Amundsen Sea–Siple Coast lithospheric transition.