Abstract In this chapter, we analyse the influence of the Carpathian Mountains on the variability of stable isotopes in precipitation by employing a combination of observed and model data. Overall, the mean value of the stable isotopes in precipitation over the Carpathian Mountains, based on observational data, was −9.8‰ for δ 18 O and −68.6‰ for δ 2 H. The local meteoric line, using all samples from the study sites, was δ 2 H = 7.65 × δ 18 O + 5.82. The simulated δ 18 O, based on the ECHAM5-wiso isotopes enable model, showed good agreement with the observed isotopic data. By comparing all the monthly values of the observed isotopic data from all analysed stations and the corresponding model data, a correlation coefficient of 0.76 ( n = 455, p < 0.001) was obtained. The spatial distribution of the simulated δ 18 O values in precipitation had the lowest values over the Romanian Carpathian Mountains and the highest values over the extra-Carpathian area, with the maximum in southeastern Romania. This pattern was strongly influenced by the Carpathian Mountains orography. Using the simulated δ 18 O data, we show that the spatial distribution of the δ 18 O values increases with temperature and decreases with altitude and latitude (−0.5‰ for δ 18 O per degree of latitude). The continental gradient is characterized by a polynomial trend of the second degree in the form of a large-open ‘U’ shape, and the general pattern of the δ 18 O values follows the spatial distribution of the Carpathian Mountains.

Abstract Water, the vital element of the environment, considered for long time an inexhaustible and renewable resource, can have a limiting or favourable potential in the socioeconomic development of a region. Given that Romania's NE (Eastern Carpathians and the northwestern part of the Moldova Plateau) is undergoing increased competition for water resources, triggered by the intensification of agriculture and industrial development, better knowledge of the hydrological processes and the quality of surface water is required. The main purpose of the present study was to identify the hydrological processes determining the quality of surface waters based on analyses of the stable isotopic composition of water from precipitation, rivers and lakes and its quality parameters. For this, water samples were collected from 29 river sections, two lakes and a precipitation monitoring point over a period of 12 months (January to December 2019). The results show that the changes in the isotopic composition of precipitation and surface water are mainly controlled by air temperature, which, in turn, is influenced by the large-scale atmospheric circulation and other factors (e.g. precipitation amount, season, altitude). At the same time, the chemical analyses indicate that the water resources of the study area are predominantly characterized by a good chemical and ecological state, except for two sampling points with a moderate state and three with a poor ecological state.

Abstract We describe a time series of meteorological parameters and surface energy balance components of a seasonal snow cover from an automatic weather station (4863 m a.s.l., 32.28° N, 77.58° E), for a winter season from 1 December 2012 to 30 March 2013, located on a moraine close to the equilibrium line altitude of Chhota Shigri glacier, Himachal Pradesh, India. The analysis shows that for over 80% of the time in winter, the snow surface was at a cooling phase. During late winter however, the surface had some positive residual energy which induced some melt during peak hours of the day. The net all-wave radiation was mostly negative during winter because of the high reflective property of snow and reduced incoming longwave radiation due to low cloud. The sensible heat flux heats the surface at night and enhances the cooling during day. The latent heat flux is always negative, showing that the surface is losing mass through sublimation processes (−0.83 mm w.e./day). A correlation between the energy fluxes and temperature shows a distinct relationship between fluxes. A comparison between the two studies performed on- and off-glacier reveals a significant difference in some parameters. A higher value (−1.08 mm/day) of sublimation rate at 4863 m a.s.l. shows that a large amount of energy available at the surface was used in sublimation processes. A comparatively lower albedo, relative humidity and net longwave radiation and higher latent heat flux, wind speed and net shortwave radiation yield a distinctive surface energy balance, highlighting the need for a large number of stations at different zones to achieve a coherent picture of energy balance in the region.