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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Africa
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Madagascar (1)
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Asia
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Far East
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China
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Guizhou China (2)
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Primary terms
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Africa
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Asia
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Far East
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China
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Guizhou China (2)
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Canada
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carbon
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Cenozoic
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Tertiary
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IPOD
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Alps
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Balkan Peninsula (1)
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Central Europe
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Poland (1)
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Binnental (9)
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Jura Mountains
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Murmansk Russian Federation
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Kola Peninsula (3)
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Lovozero Massif (1)
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Southern Europe
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Italy
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Apennines
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Ivrea-Verbano Zone (1)
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Piemonte Italy (1)
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Sicily Italy
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Lipari Islands
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Vulcano (2)
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Tuscany Italy
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Apuane Alps (6)
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Macedonia (3)
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Vardar Zone (1)
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Western Europe
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geochemistry (7)
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hydrogen
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igneous rocks
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diabase (1)
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granites (2)
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pegmatite (2)
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syenites
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nepheline syenite (1)
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ultramafics
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peridotites
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dunite (1)
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pyroxenite
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clinopyroxenite (1)
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orthopyroxenite (1)
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websterite (1)
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volcanic rocks
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andesites (1)
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pyroclastics (2)
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inclusions
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fluid inclusions (2)
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Indian Ocean Islands
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Integrated Ocean Drilling Program
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intrusions (3)
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isotopes
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radioactive isotopes
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stable isotopes
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C-13/C-12 (2)
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D/H (1)
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Fe-56/Fe-54 (1)
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O-18/O-16 (2)
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Sr-87/Sr-86 (1)
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magmas (2)
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mantle (2)
-
Mesozoic
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Cretaceous
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Lower Cretaceous
-
Albian (1)
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Aptian (1)
-
-
-
Jurassic
-
Middle Jurassic (1)
-
-
Triassic (2)
-
-
metal ores
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antimony ores (2)
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arsenic ores (2)
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copper ores (2)
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gold ores (7)
-
IOCG deposits (1)
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iron ores (1)
-
lead ores (2)
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lead-zinc deposits (1)
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mercury ores (1)
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platinum ores (3)
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polymetallic ores (1)
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silver ores (3)
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zinc ores (2)
-
-
metals
-
actinides
-
thorium (1)
-
uranium (4)
-
-
alkali metals
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cesium
-
Cs-137 (1)
-
-
lithium (1)
-
potassium
-
K-40 (3)
-
-
rubidium (4)
-
sodium (1)
-
-
alkaline earth metals
-
barium (1)
-
strontium
-
Sr-87/Sr-86 (1)
-
-
-
antimony (11)
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arsenic (24)
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bismuth (8)
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cadmium (6)
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chromium (1)
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cobalt (1)
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copper (7)
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gallium (3)
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germanium (1)
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gold (6)
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hafnium (1)
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indium (1)
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iron
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Fe-56/Fe-54 (1)
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lead (11)
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manganese (3)
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mercury (8)
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silver (11)
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tin (1)
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metamorphic rocks
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metacarbonate rocks (1)
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metamorphism (2)
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mineral deposits, genesis (7)
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mineral exploration (2)
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mineralogy (2)
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minerals (1)
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noble gases
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radon (1)
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North America
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Lake of the Woods (1)
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Canadian Cordillera (1)
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Ocean Drilling Program
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ODP Site 801 (1)
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ocean floors (1)
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orogeny (2)
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oxygen
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O-18/O-16 (2)
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Pacific Ocean
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Northeast Pacific
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Juan de Fuca Ridge
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Endeavour Ridge (1)
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Equatorial Pacific (1)
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North Pacific
-
Northeast Pacific
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Juan de Fuca Ridge
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Endeavour Ridge (1)
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-
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Northwest Pacific
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Pigafetta Basin (1)
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West Pacific
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Northwest Pacific
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Pigafetta Basin (1)
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paleoclimatology (1)
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Paleozoic
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lower Paleozoic (1)
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phase equilibria (1)
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Plantae (1)
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plate tectonics (1)
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Precambrian
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upper Precambrian
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Proterozoic (1)
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sedimentary rocks
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dolostone (4)
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clastic rocks
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thallium
Crystallographic insights into monovalent thallium incorporation: Exploring hydropyrochlore structure for environmental remediation
Kalithallite, K 3 Tl 3+ Cl 6 ⋅2H 2 O, a new mineral with trivalent thallium from the Tolbachik volcano, Kamchatka, Russia
Orbitally paced global oceanic deoxygenation decoupled from volcanic CO 2 emission during the middle Cretaceous Oceanic Anoxic Event 1b (Aptian-Albian transition)
Palladothallite, Pd 3 Tl, a new mineral from the Monchetundra layered intrusion, Kola Peninsula, Russia
Thalliomelane, TIMn 7.5 4 + Cu 0.5 2 + O 16 , a new member of the coronadite group from the preglacial oxidation zone at Zalas, southern Poland
Forming Earth’s Continental Crust: A Nontraditional Stable Isotope Perspective
Application of molybdenum and thallium isotopes as indicators of paleoredox conditions and genesis of hyper-enriched black shale deposits, Peel River, Yukon, Canada
Carbonate Replacement as the Principal Ore Formation Process in the Proterozoic McArthur River (HYC) Sediment-Hosted Zn-Pb Deposit, Australia
Thunderbayite, TlAg 3 Au 3 Sb 7 S 6 , a new gold-bearing mineral from the Hemlo gold deposit, Marathon, Ontario, Canada
Biagioniite, Tl 2 SbS 2 , from the Hemlo gold deposit, Marathon, Ontario, Canada: occurrence and crystal structure
Parapierrotite from the Monte Arsiccio mine (Apuan Alps, Tuscany, Italy): occurrence and new data on its crystal-chemistry
Distinguishing Ore Deposit Type and Barren Sedimentary Pyrite Using Laser Ablation-Inductively Coupled Plasma-Mass Spectrometry Trace Element Data and Statistical Analysis of Large Data Sets
Distinguishing High- from Low-Temperature Platinum Nuggets Through Their Trace-Element Pattern
Evidence for syngenetic micro-inclusions of As 3+ - and As 5+ -containing Cu sulfides in hydrothermal pyrite
Secondary Fe–As–Tl mineralization in soils near Buus in the Swiss Jura Mountains
Liberation of selenium from alteration of the Bowland Shale Formation: evidence from the Mam Tor landslide
The distribution of lead and thallium in mantle rocks: Insights from the Balmuccia peridotite massif (Italian Alps)
Comparison of the Allchar Au-As-Sb-Tl Deposit, Republic of Macedonia, with Carlin-Type Gold Deposits
Abstract The Allchar Au-As-Sb-Tl deposit is situated in the western part of the Vardar zone, the main suture zone along the contact between the Adriatic and the Eurasian tectonic plates. It is spatially and temporally associated with a Pliocene (~5 Ma) postcollisional high-K calc-alkaline to shoshonitic volcano-plutonic center. The Allchar deposit shares many distinctive features with Carlin-type gold deposits in Nevada, including its location near a terrain-bounding fault in an area of low-magnitude extension and intense magmatism. The mineralization is mostly hosted in calcareous sedimentary rocks at intersections of high-angle faults in permeable stratigraphy. The alteration types (carbonate dissolution, silicification, and argillization), ore mineralogy (auriferous arsenian pyrite and marcasite, stibnite, realgar, orpiment, and lorandite), high Au/Ag ratios, and low base metal contents are also typical of Carlin-type gold deposits in Nevada. However, the Allchar deposit differs from Nevada Carlin-type gold deposits as follows: it is an isolated Au prospect with a close spatial and temporal relationship to a shoshonitic volcano-plutonic center in a mineral belt dominated by intrusion-related Cu-Au porphyry, skarn, and hydrothermal polymetallic deposits. The deposit is clearly zoned (proximal Au-Sb to distal As-Tl), it has a significantly higher Tl content, trace elements in pyrite and marcasite are homogeneously distributed, and synore dolomitization is a widespread alteration type. Gold mineralization is most abundant in the southern part of the deposit. It occurs mostly as invisible Au in disseminated pyrite or marcasite and as rare native Au grains. Gold mineralization is accompanied by intense decarbonatization and silicification. Fluid inclusions and the hydrothermal alteration mineral assemblage indicate that Au was deposited from hot (>200°C), saline (up to ~21 wt % NaCl equiv), moderately acidic (pH <5) fluids that carried traces of magmatic H 2 S and CO 2 . In the calcareous host rocks, mixing of such fluids with cool, dilute, near-neutral groundwater triggered deposition of Au and Fe sulfides. In Tertiary tuff, isocon analysis shows that sulfidation of preexisting Fe minerals was a critical factor for deposition of Au and Fe sulfides. Antimony mineralization prevails in the central part of the deposit, and it is mostly associated with dark-gray to black jasperoid. Stibnite, the most common Sb mineral in the Allchar deposit, occurs as fine-grained disseminations in jasperoid and as fine- to coarsely crystalline masses that fill vugs and fracture zones lined with drusy quartz. Fluid inclusions entrapped by stibnite-bearing jasperoid, quartz, and calcite crystals suggest that stibnite was deposited from more dilute and cooled fluids (aqueous-carbonic fluid inclusions: 6.0–3.5 wt % NaCl equiv, T h = 102°−125°C; aqueous fluid inclusions: 14.5 and 17.1 wt % NaCl equiv, T h = 120°−165°C). In contrast to stibnite, As sulfides (orpiment and realgar) and Tl mineralization are associated with argillic alteration. Fluid inclusions hosted by realgar, orpiment, dolomite, and lorandite record deposition from more dilute (2.6–6.9 wt % NaCl equiv) and relatively cold fluids (T H = 120°−152°C) enriched in K. Isocon diagrams show a tight link between Tl and the low-temperature argillic alteration as well as a significant correlation between Tl and K. The spatial relationship of Tl mineralization with dolomite suggests that Tl deposition was also promoted by neutralization of acidic fluids. The δ D and δ 18 O data obtained from gangue minerals and fluid inclusions indicate that magmatic fluid mixed with exchanged meteoric water at deep levels and with unexchanged meteoric water at shallow levels in the system. The δ 13 C and δ 18 O values of carbonate minerals and extracted fluid inclusions suggest mixing of carbonate rock buffered fluids with magmatic and atmospheric CO 2 . The sulfur isotope values of early disseminated pyrite and marcasite show that H 2 S was initially derived from diagenetic pyrite in sedimentary rocks. In contrast, Sb and As mineralization indicate a strong input of magmatic H 2 S during the main mineralization stage. Late-stage botryoidal pyrite and marcasite are depleted in 34 S, which indicates a diminishing magmatic influence and predominance of sulfur from sedimentary sources during the late-mineralization stage. Fractionation of isotopically light sulfide species from isotopically heavy sulfates due to oxidation under increased oxygen fugacity cannot be excluded.