Abstract: Constraining basin thermal history is a key part of reservoir characterization in carbonate rocks. Conventional palaeothermometric approaches cannot always be used: fluid inclusions may be reset or not present, while δ 18 O palaeothermometry requires an assumption on the parent fluid composition. The clumped isotope palaeothermometer, however, is a promising technique for constraining the thermal history of basins. In this study, we test if clumped isotopes record temperatures of recrystallization in deeply-buried dolomitic reservoirs, through comparison with fluid-inclusion data. The studied reservoir is the Cretaceous Pinda Formation, offshore Angola, a deeply-buried dolomitized sedimentary carbonate hydrocarbon reservoir. It provides an ideal test case as samples from industry wells are available over a relatively wide burial depth range of c. 2000–4000 m below seafloor (mbsf) and the constituent dolomites are relatively homogeneous. Across this depth range, fluid-inclusion homogenization temperatures for the Pinda Formation record a range of temperatures from c. 110 to 170°C, increasing with depth. These closely match present-day ambient well temperatures, indicating recent resetting of the fluid inclusions. Clumped isotopes, however, record temperatures significantly ( c. 20–60°C) below fluid-inclusion and well temperatures for the seven samples analysed. The deepest five samples ( c. 2800–3700 mbsf) record clumped isotope temperatures of around 100–120°C, interpreted to represent a deep burial recrystallization event responsible for a massive (re)dolomitization of the reservoir. The lower clumped isotope temperatures (65 and 82°C) of the shallower (2055 and 2740 mbsf) samples are interpreted to represent physical mixing of two dolomite generations due to incomplete burial recrystallization of an early shallow dolomite. Determination of temperature through clumped isotopes allows calculation of the parent fluid δ 18 O values. In the five deepest samples, the fluid δ 18 O values of 3.7–6.5‰ cluster around the modern-day porewater composition (5‰), suggesting that burial dolomitization occurred in the presence of evolved brine. Mineral δ 18 O values of c . −7 to −4.5‰ are lower than pristine Cretaceous marine dolomite and are in accordance with burial recrystallization. Clumped isotopes are therefore interpreted to record temperatures corresponding to open-system burial recrystallization events. This study shows that clumped isotopes are a valuable tool in characterizing the thermal history of deeply-buried (>2000 m) carbonate hydrocarbon reservoirs. Supplementary material: All standard and sample data are available at https://doi.org/10.6084/m9.figshare.c.3945184

Abstract This study presents a new experimental chamber, which builds upon previous methods of testing salt weathering. This method is based on capillary rising in samples, as this corresponds to the actual imbibition process in building stone. This set-up allows control in setting both a specific thermal regime and cycling temperatures. Some of the significant additions of this experimental set-up are: continuous flow of the saline solution, as the samples will be fed with a constant concentration throughout the experiments; and continuous monitoring of environmental temperature, relative humidity and sample weights. Recorded results in this research belong to limestone samples from Mokattam, Cairo. Results are also considered as a proof to the practical advantages of the experimental chamber in salt-weathering studies and its environmental controls.

Abstract Using two hypothetical effusive events in the Chaîne des Puys (Auvergne, France), we tested two geographical information systems (GISs) set up to allow loss assessment during an effusive crisis. The first was a local system that drew on all immediately available data for population, land use, communications, utility and building type. The second was an experimental add-on to the Global Disaster Alert and Coordination System (GDACS) global warning system maintained by the Joint Research Centre (JRC) that draws information from open-access global data. After defining lava-flow model source terms (vent location, effusion rate, lava chemistry, temperature, crystallinity and vesicularity), we ran all available lava-flow emplacement models to produce a projection for the likelihood of impact for all pixels within the GIS. Next, inundation maps and damage reports for impacted zones were produced, with those produced by both the local system and by GDACS being in good agreement. The exercise identified several shortcomings of the systems, but also indicated that the generation of a GDACS-type global response system for effusive crises that uses rapid-response model projections for lava inundation driven by real-time satellite hotspot detection – and open-access datasets – is within the current capabilities of the community.

Abstract Earth construction is the oldest building material known, with documented cases of the use of earth bricks since Mesopotamia around 10 000 BC. Earth construction exists throughout most of the world in different cultures, and for some countries it continues to be the main process of construction. Around 30% of the world’s population lives in buildings made from earth materials. Earthen construction is an environmentally friendly technique with a social and cultural contribution; this advantage is increased when this type of construction is applied in developing countries where the material costs counterbalance the labour costs, and where other materials and techniques are not available. Studies of material characteristics are required in order to understand the composition and specific properties of earth buildings, their heterogeneity and their degradation mechanisms. Results from two different types of adobes that represent these material characteristics in Aveiro district are shown, owing to the importance of determining and acknowledging the main characteristics of adobe buildings in order to have sufficient information to initiate conservation and rehabilitation actions.

Abstract All types of stones have been used as building stones, depending on their durability, visual harmony with the intended construction and availability. In the Hellenistic period, as in other periods, tuff was preferred as a building stone due to its convenience – it was easy to extract, transport and use for building. In the present study, three ancient quarries that were the possible tuff sources for the Apollon Smintheus Temple in Çanakkale are investigated by comparing the durability properties of stones in the temple and in the quarries. These properties are determined using physical and physico-mechanical tests, comparing fresh and artificially weathered samples. Microstructural and elemental correlations were found using optical microscopy, stereomicroscopy, X-ray diffraction, scanning electron microscopy, methylene blue adsorption and X-ray fluorescence analyses. The results indicate that temple tuffs and two of three quarries have similar geological engineering and microstructural properties with the strong claim that those two quarries could have been the source of building stone for the temple.

Abstract Residual sludge from dimension-stone working plants, both from gangue saws with abrasive shot and frame saws, is classified as waste and presents a number of problems for the stone industry. These problems include a fine size distribution, heavy metals and total petroleum hydrocarbon (TPH) content, all of which impede recovery and reuse. Residual sludge, management of which is administered in accordance with the Italian Legislative Decree 152/06, can be used in waste form for environmental restoration or for cement plants. However, it is also possible that sludge applications could go beyond these limited uses with incorporation of systematic treatment for the production of secondary raw materials (SRM), for example, filler, or for ‘new products’, for example, artificial loam. Such new products or SRM have to be certified not only on the basis of their technical and physical characteristics but also by means of appropriate chemical analyses to guarantee that the products are not contaminated. This paper outlines the results from laboratory and in situ characterization of residual sludge. In particular, three potential applications of sludge either by itself or mixed with other materials were evaluated: landfill waterproofing material, filler material for civil works and artificial soil for land rehabilitation.

Abstract Natural stone was the primary building material in Cyprus in the past. Nowadays, its use is mostly confined to decorative purposes and restoration projects. This study represents the first thorough and systematic investigation of the characteristics of local carbonate stone. The variety of the results recorded highlights the complexity of this natural geomaterial and, hence, the particular attention needed before selecting the appropriate lithotype in construction practice. Stones coming from the same geological formation exhibit significant variations in their physico-mechanical properties. The materials’ durability against salt crystallization is explained with reference to their pore structure and flexural strength, revealing that, in many cases, small differences may have a significant impact on stone performance. The study also investigates the use of novel microdestructive techniques in the prediction of the mechanical properties of the stones under study. These techniques can be especially useful in the characterization of monumental stone, where sampling is limited, or when in situ characterization of stone is required.

Abstract Most buildings of architectural heritage in Paris and its surroundings are built with Lutetian limestone. Several historic buildings of the ‘Vexin Normand’ region show Lutetian limestone in the upper parts of their walls, while the lower parts are built with a chalk known as ‘Pierre de Vernon’. The ‘Pierre de Vernon’ appears up to the first metre, although in exceptional cases it can reach the middle height of a building. Commonly, chalks exhibit low durability due to their high porosity. However, ‘Pierre de Vernon’ is supposed to have greater durability than other chalks because of its historic use for basement construction. The objective of this research was to understand the use of the ‘Pierre de Vernon’ in the lower part of the constructions. A petrophysical characterization of Vernon chalk and Lutetian limestone was carried out, focusing mainly on the differences in porosity and water uptake. Salt crystallization tests were done to contrast their response to decay. Colour and roughness measurements and scanning electron microscope observations were performed. Results show that the different porous networks of these two limestones lead to a high contrast in their hydric properties and responses to decay, and the use of Vernon chalk in the lower sections of buildings has been found to be appropriate.

Abstract This study gives an example of the steps that a repair work must include to be successful. It deals with a specific building, repair material (lime mortar) and application (render), but also with the study of the repair mortar in the laboratory and on site. Firstly, the original materials of the wall were characterized to ensure compatibility with the new repair mortars. Secondly, the suitability of different mortar mixes, made with lime and calcareous aggregate, was assessed by characterizing their properties after 15 months. At the same time, the repair mortars were applied in testing panels, and their behaviour under environmental conditions was studied and compared with that of the laboratory mortars. Mortar properties (shrinkage, adhesion, mineralogy, microstructure and texture) developed differently according to the curing conditions. The carbonation degree was higher in mortars cured on site (especially those with higher aggregate content), although in both cases it depended on mortar porosity. Testing the type of application on site was helpful to define the best performance of the designed mixes and to choose the most suitable one among them, which was found to be the 1:6 binder-to-sand ratio mortar applied in both layers of the render.

Abstract Airborne dust suppression is of critical importance to military operations conducted in desert environments. Airborne dust is commonly generated in the desert by surface and near-surface operations during operational, testing, and training missions. Currently, there is no standardized procedure for testing dust suppressants, and the U.S. military lacks a specific test operations procedure (TOP) designed to provide realistic testing of the performance and durability of commercial products sold for dust abatement. The primary purpose of this study is to provide recommendations for the future development of a TOP for testing dust suppressants applied to desert soils. Recommendations were developed from the evaluation of a polyvinyl-based synthetic polymer as a dust suppressant, which was tested at four test intervals over a 19–week period in the late spring and summer of 2008 at the U.S. Army Yuma Proving Ground. The dust suppressant was applied at three separate test sites having different surface characteristics and soil properties ranging from loose, sandy gravel to gravelly sand, alluvial-fan soils to soft, sandy-silt, alluvial-plain soils. Each test site was subjected to a variety of traffic impact types consisting of an increasing number of cumulative passes by different vehicle types—including a low-flying helicopter, a light-weight armored tracked vehicle, and heavy-, medium-, and lightweight wheeled vehicles, plus pedestrian foot traffic. In addition to the sites of traffic impact, three types of control plots were concurrently tested to act as reference sites, as well as to evaluate the longevity of the suppressant, which included: disturbed and static (undisturbed) baseline plots and a static benchline plot. Surface soil and dust-suppressant physical properties were measured following each traffic impact in the form of shear strength and bearing capacity, plus dust-emission flux as measured by a Portable In Situ Wind ERosion Laboratory (PI-SWERL). Results from this study show that dust-emission flux and surface-strength measurements from a layout of control and traffic impact test plots provide a quantifiable and repeatable approach in measuring the efficacy of a dust suppressant for a TOP used by the U.S. Army.

Abstract Department of Defense military land use of the desert southwest includes a wide spectrum of military weapons testing, force-on-force training, and various types of flight training. The desert southwest provides a critical asset for the U.S. military— open space. Installations in the desert southwest tend to be much larger than installations in other regions of the nation, with several exceeding 400,000 ha. This open-space asset has allowed the military to historically establish large training areas and ranges on installations and to define expansive air maneuver regions above these ranges and above the vast public lands of other agencies. It also offers critical training and testing areas that are analogs to similar worldwide environments where the military operates. Training and testing activities are conducted in the three-dimensional land and air space that replicates the modern battle space. Land and air space use is highly variable among installations depending on mission requirements. Natural resource management challenges include the large spatial extent of lands and air space under Department of Defense management, highly variable military land-use requirements, significant endangered species regulatory and conservation requirements, encroachment and Base Realignment and Closure requirements, competition for water resources, and climate change. Department of Defense natural resource managers attempt to meet these challenges through interagency cooperative agreements, integrated natural resource management plans, and Department of Defense sustainable range programs.

Soil liquefaction takes place during and/or after the occurrence of an earthquake and is a major contributor to urban seismic risk. Geologists use a technique called the cone penetration test (CPT) to determine the properties of soils, including liquefaction levels, which yields large amounts of soil data. The analysis of such massive amounts of data requires high-performance computing resources. In this paper, we present GQO (Grid Query Optimizer), a distributed algorithm that enables the analysis of large CPT data sets efficiently on a grid cyberinfrastructure.

The Mojave-Sonora megashear model, which implies left-lateral strike-slip motion of northern México in Jurassic time, remains one of the most influential ideas concerning the geology of México. A comprehensive review of the literature related to this topic does not yet allow resolution of the controversy over the validity of this hypothesis. A clear conclusion is that the original hypothesis was based on a relatively simplistic model of the geology of Sonora, as the basement of the Caborca terrane is not simply a fragment of the Mojave Precambrian basement province of eastern California. Attempts to use quantitative techniques in testing the model have yielded results contrary to the hypothesis, such as clockwise rotations indicated by paleomagnetic data, and the diversity and complexity of the basement of Caborca indicated by geochemical and geochronological data. Other quantitative methods such as zircon provenance studies in quartzites of the sedimentary cover yield inconclusive results. The main conclusion of the studies of detrital zircons is that Grenvillean zircons are relatively abundant, but that their presence cannot be attributed solely to sources in the Grenville province in a fixist model. Stratigraphic correlations of upper Paleozoic and Mesozoic rocks in Caborca with similar sequences in California and Nevada do not provide convincing arguments of large displacement, but should be evaluated in more detail. Elements that have the potential to test the hypothesis with greater certainty include detailed studies of basement rocks, a refined stratigraphy of the Jurassic volcanic and volcaniclastic arc rocks south of the inferred fault trace, and an increased understanding of depositional trends in the miogeoclinal sequence. Structural studies are sparse in this region. It is particularly important to gain a better understanding of the effects in time and space of Late Cretaceous–Tertiary contractional deformation. A tectonic evolution model that does not conflict with the existing data is the proposal that displacement of a para-autochthonous Caborca terrane may have occurred in the late Paleozoic. Nonetheless, available data and geologic relations in the Caborca region do not require Late Jurassic slip of several hundred kilometers. El modelo de la megacizalla Mojave-Sonora, el cual implica desplazamiento lateral izquierdo en el norte de México durante el Jurásico, permanece como una de las ideas más influyentes en la geología del país. Una revisión general de la literatura relacionada con el tema no permite aún resolver la controversia sobre la validez de la hipótesis, pero una conclusión clara es que la hipótesis original estaba basada en un modelo relativamente simplista de la geología de Sonora, ya que el basamento del terreno Caborca no es un simple fragmento de la corteza Mojave del este de California. Intentos de utilizar métodos cuantitativos han dado resultados contrarios a la hipótesis, como el de las rotaciones horarias indicadas por el paleomagnetismo y la diversidad de basamentos en Caborca que sugieren la geocronología y geoquímica; otros métodos producen resultados indeterminados, como la proveniencia de circones en las cuarcitas de la cobertura del terreno Caborca. La conclusión más relevante de esos estudios es la abundancia de circones de edad Grenvilleana, pero su presencia no puede simplemente atribuirse a fuentes en la Provincia Grenville en un modelo fijista. Las correlaciones estratigráficas entre secuencias Paleozoico tardío y Mesozoico en Caborca y secuencias similares en California y Nevada no producen argumentos convincentes a favor de grandes desplazamientos, pero deben considerarse con datos más detallados. Elementos que podrían evaluar la hipótesis con mayor contundencia son estudios más detallados del basamento, una estratigrafía fina del arco volcánico Jurásico y de las rocas volcanoclásticas al sur de la traza inferida de la falla y un mejor conocimiento de la secuencia miogeosinclinal. Son pocos los estudios estructurales en la región y en particular un problema importante es resolver en tiempo y espacio los efectos de la deformación compresional Cretácico-Terciario. Un modelo que no entra en conflicto con la evidencia existente es la propuesta de que el desplazamiento del terreno parautóctono Caborca haya ocurrido en el Paleozoico tardío. Sin embargo, los datos existentes y las relaciones geológicas en la región de Caborca, no requieren de un desplazamiento de cientos de kilómetros en el Jurásico Tardío.

The central questions of karst hydrology concern (1) recharge, storage, and flow of groundwater in contemporary aquifers, (2) identification of geologic constraints on groundwater storage and flow paths, and (3) understanding of how aquifers evolve through time and the relation of this evolution to the evolution of interconnected surface-water basins. Karst aquifers generally display matrix, fracture, and conduit permeability with contrasts in effective hydraulic conductivity of many orders of magnitude. Dispersed recharge into the matrix and fracture permeability provides most of the storage and a slow-response flow system, while point recharge into the conduit system provides quick flow and little storage. A current question is how to describe these components of permeability and the interchange of groundwater between them. Groundwater basins can be delineated by tracer studies and geologic boundary conditions. Progress is being made on the quantitative, fluid mechanics description of conduit flow. The evolution of karst aquifers is a mainly chemical process, with some transport of insoluble clastics by high-velocity conduit waters. The equilibrium carbonate chemistry has been well established for a long time, including accurate values for equilibrium constants. Conduits, shafts, and solutionally modified fractures are the result of differential dissolution rates. Geochemically satisfactory descriptions of dissolution kinetics have been established, so that the evolution of karst aquifers through time can be accurately described. Overall, a comprehensive model for karst aquifer behavior seems to be within sight.