ABSTRACT Formation of the Central European tektites, known as moldavites, has been associated with a large meteorite impact in southern Germany 14.8 m.y. ago. The geochemical link between moldavites and their source materials, and the processes of their possible chemical differentiation still remain uncertain. Some differences in chemical composition between moldavites and sediments of corresponding age from the surroundings of the Ries crater could be explained by a hypothesis according to which biomass covering the pre-impact area contributed to the source materials. In a comparison of the geochemical compositions of a large representative set of moldavites and suitable Ries sediments, enrichment in elements K, Ca, Mg, and Mn and depletion of Na in moldavites, similar to redistribution of these elements during their transfer from soil to plants, could indicate the unconventional biogenic component in moldavite source materials. Simple mixing calculations of the most suitable Ries sediments and a model biogenic component represented by burned biomass residue are presented. The plausibility of the estimated biomass contribution considering reconstructions of the middle Miocene paleoenvironment in the pre-impact Ries area is discussed. No significant vapor fractionation is required to explain the observed variability of moldavite chemical composition.

ABSTRACT Australasian tektites represent the largest group of tektites on Earth, and their strewn field covers up to one sixth of Earth’s surface. After several decades of fruitless quest for a parent crater for Australasian tektites, mostly in the main part of the strewn field in Indochina, the crater remains undiscovered. We elaborate upon a recently suggested original hypothesis for the impact in the Alashan Desert in Northwest China. Evidence from geochemical and isotopic compositions of potential source materials, gravity data, and geographic, paleoenvironmental, and ballistic considerations support a possible impact site in the Badain Jaran part of the Alashan Desert. In further support of an impact location in China, glassy microspherules recovered from Chinese loess may be the right age to relate to the Australasian tektite event, perhaps as part of the impacting body. The most serious shortcomings of the commonly accepted Indochina impact location include signs of little chemical weathering of source materials of Australasian tektites, unlike highly weathered sedimentary targets in Indochina, and questionable assumptions about transport of distal ejecta.

ABSTRACT This thesis embraces and expands upon a century of research into disparate geological enigmas, offering a unifying catastrophic explanation for events occurring during the enigmatic mid-Pleistocene transition. Billions of tons of “Australasian tektites” were dispatched as distal ejecta from a target mass of continental sediments during a cosmic impact occurring ca. 788 ka. The accepted signatures of a hypervelocity impact encompass an excavated astrobleme and attendant proximal, medial, and distal ejecta distributions. Enigmatically, the distal tektites remain the only accepted evidence of this impact’s reality. A protracted 50 yr search fixated on impact sites in Southeast Asia—the location of the tektites—has failed to identify the requisite additional impact signatures. We postulate the missing astrobleme and proximal/medial ejecta signatures are instead located antipodal to Southeast Asia. A review of the gradualistic theories for the genesis and age of the “Carolina bay” landforms of North America finds those models incapable of addressing all the facts we observe. Research into 57,000 of those oriented basins informs our speculation that they represent cavitation-derived ovoid basins within energetically delivered geophysical mass surge flows emanating from a cosmic impact. Those flows are seen as repaving regions of North America under blankets of hydrated impact regolith. Our precisely measured Carolina bay orientations indicate an impact site within the Laurentide ice sheet. There, we invoke a grazing regime impact into hydrated early Mesozoic to late Paleozoic continental sediments, similar in composition to the expected Australasian tektites’ parent target. We observe that continental ice shielded the target at ca. 788 ka, a scenario understood to produce anomalous astroblemes. The ensuing excavation allowed the Saginaw glacial lobe’s distinctive and unique passage through the Marshall Sandstone cuesta, which encircles and elsewhere protects the central region of the intracratonic Michigan Basin. Subsequent erosion by multiple ice-age transgressions has obfuscated impact evidence, forming Michigan’s “Thumb” as an enduring event signature. Comprehensive suborbital modeling supports the distribution of distal ejecta to the Australasian tektite strewn field from Michigan’s Lower Peninsula. The mid-Pleistocene transition impact hypothesis unifies the Carolina bays with those tektites as products of an impact into the Saginaw Bay area of Lake Huron, USA. The hypothesis will be falsified if cosmogenic nuclide burial dating of Carolina bay subjacent stratigraphic contacts disallows a coeval regolith emplacement ca. 788 ka across North America. We offer observations, interdisciplinary insights, and informed speculations fitting for an embryonic concept involving a planetary-scale extraterrestrial impact.

ABSTRACT The Popigai (100 km in diameter) and the Chesapeake Bay (40–85 km diameter) impact structures formed within ~10–20 k.y. in the late Eocene during a 2 m.y. period with enhanced flux of 3 He-rich interplanetary dust to Earth. Ejecta from the Siberian Popigai impact structure have been found in late Eocene marine sediments at numerous deep-sea drilling sites around the globe and also in a few marine sections outcropped on land, like the Massignano section near Ancona in Italy. In the Massignano section, the Popigai layer is associated with an iridium anomaly, shocked quartz, and abundant clinopyroxene-bearing (cpx) spherules, altered to smectite and flattened to “pancake spherules.” The ejecta are also associated with a significant enrichment of H-chondritic chromite grains (>63 μm), likely representing unmelted fragments of the impactor. The Massignano section also contains abundant terrestrial chrome-spinel grains, making reconstructions of the micrometeorite flux very difficult. We therefore searched for an alternative section that would be more useful for these types of studies. Here, we report the discovery of such a section, and also the first discovery of the Popigai ejecta in another locality in Italy, the Monte Vaccaro section, 90 km west of Ancona. The Monte Vaccaro section biostratigraphy was established based on calcareous nannoplankton, which allowed the identification of a sequence of distinct bioevents showing a good correlation with the Massignano section. In both the Monte Vaccaro and Massignano sections, the Popigai ejecta layer occurs in calcareous nannofossil zone CNE 19. The ejecta layer in the Monte Vaccaro section contains shocked quartz, abundant pancake spherules, and an iridium anomaly of 700 ppt, which is three times higher than the peak Ir measured in the ejecta layer at Massignano. In a 105-kg-size sample from just above the ejecta layer at Monte Vaccaro, we also found an enrichment of H-chondritic chromite grains. Because of its condensed nature and low content of terrestrial spinel grains, the Monte Vaccaro section holds great potential for reconstructions of the micrometeorite flux to Earth during the late Eocene using spinels.

ABSTRACT Two late Eocene impact spherule layers are known: the North America microtektite layer (from the Chesapeake Bay crater) and the slightly older clinopyroxene (cpx) spherule layer (from Popigai crater). Positive Ir anomalies occur at 5.61 m and 6.19 m above the base of a late Eocene section at Massignano, Italy. The age difference between the two anomalies is ~65 ± 20 k.y. The older Ir anomaly at 5.61 m appears to be associated with the cpx spherule layer. Although no impact spherules or shocked-mineral grains have been found associated with the upper Ir anomaly at 6.19 m, it has been proposed that it may be from the Chesapeake Bay impact. Comparison with other distal ejecta layers suggests that microtektites, but not shocked-mineral grains, from the Chesapeake Bay crater could have been thrown as far as Massignano. However, their absence neither supports nor disproves the hypothesis that the Ir anomaly at 6.19 m is from the Chesapeake Bay impact. On the other hand, the North American microtektite layer is not associated with an Ir anomaly. Furthermore, the average age difference between the cpx spherule layer and the North American microtektite layer appears to be ~18 ± 11 k.y., which is nearly one quarter the age difference between the two Ir anomalies at Massignano. This indicates that the Ir anomaly at 6.19 m is too young to be from the Chesapeake Bay impact, and thus is most likely not from the Chesapeake Bay impact.

ABSTRACT We measured stratigraphic sections and collected samples from Oceanic suite outcrops at Gay’s Cove and Bath Cliffs, Barbados, in order to restudy the late Eocene microtektite layer(s) and provide new geological context. We disaggregated and processed samples into separates of microfossils, microtektites, and heavy minerals, and we present up-to-date glass geochemistry, biostratigraphic analysis, and detrital zircon U-Pb analysis. Results from the new Barbadian microtektite glass chemistry analysis (Gay’s Cove) compare well with those from other published microtektite analyses, as well as those from the correlative North American strewn field. Micropaleontology confirms a late Eocene age for the Oceanic microtektite horizon at Gay’s Cove. Using U-Pb, we dated 24 Tertiary zircon grains, probably from volcanic ash-fall events, which at Gay’s Cove yielded a preliminary, poorly defined, and incorrect depositional age for the microtektite layer (≤31.84 ± 0.85 Ma; weighted mean of only three grains). Three additional new U-Pb depositional ages (≤38.52 ± 1.0 Ma, ≤39.23 ± 0.3 Ma, ≤35.25 ± 0.82 Ma) were obtained from bottom to top in the 24 m section at Bath Cliffs. We also dated 46 Paleozoic–Proterozoic zircon grains using U-Pb and discuss whether these “old” grains represent recycled (subducted and extruded) volcanic grains or windblown silt/sand from Africa.

ABSTRACT The late Eocene was marked by multiple impact events, possibly related to a comet or asteroid shower. Marine sediments worldwide contain evidence for at least two closely spaced impactoclastic layers. The upper layer might be correlated with the North American tektite-strewn field (with the 85-km-diameter Chesapeake Bay impact structure [USA] as its source crater), although this is debated, whereas the lower, microkrystite layer (with clinopyroxene [cpx]-bearing spherules) was most likely derived from the 100-km-diameter Popigai impact crater (Russia). The Eocene-Oligocene global stratotype section and point is located at Massignano, Italy, and below the boundary, in the late Eocene, at the 5.61 m level, shocked quartz and pancake-shaped smectite spherules that contain (Ni- and Cr-rich) magnesioferrite spinel crystals are found. These are associated with a positive Ir anomaly in deposits with the same age as the Popigai-derived cpx spherule layer. This layer is overlain by another Ir-rich layer, likely due to another large impact event. From a large amount of “pancake-bearing” rock, we isolated a few hundred milligrams of this spinel-rich material. The tungsten isotopic composition of this material shows more or less a terrestrial composition. However, the spinel-rich materials have excess 54 Cr values (expressed as ε 54 Cr, which is the per ten thousand deviation of the 54 Cr/ 52 Cr ratio from a terrestrial standard) of around –0.4 to –0.5 ε 54 Cr, which distinctly point to an ordinary chondritic impactor. This result supports the asteroid impact interpretation but not the comet impact hypothesis.