ABSTRACT Formation of the Central European tektites, known as moldavites, has been associated with a large meteorite impact in southern Germany 14.8 m.y. ago. The geochemical link between moldavites and their source materials, and the processes of their possible chemical differentiation still remain uncertain. Some differences in chemical composition between moldavites and sediments of corresponding age from the surroundings of the Ries crater could be explained by a hypothesis according to which biomass covering the pre-impact area contributed to the source materials. In a comparison of the geochemical compositions of a large representative set of moldavites and suitable Ries sediments, enrichment in elements K, Ca, Mg, and Mn and depletion of Na in moldavites, similar to redistribution of these elements during their transfer from soil to plants, could indicate the unconventional biogenic component in moldavite source materials. Simple mixing calculations of the most suitable Ries sediments and a model biogenic component represented by burned biomass residue are presented. The plausibility of the estimated biomass contribution considering reconstructions of the middle Miocene paleoenvironment in the pre-impact Ries area is discussed. No significant vapor fractionation is required to explain the observed variability of moldavite chemical composition.

ABSTRACT Australasian tektites represent the largest group of tektites on Earth, and their strewn field covers up to one sixth of Earth’s surface. After several decades of fruitless quest for a parent crater for Australasian tektites, mostly in the main part of the strewn field in Indochina, the crater remains undiscovered. We elaborate upon a recently suggested original hypothesis for the impact in the Alashan Desert in Northwest China. Evidence from geochemical and isotopic compositions of potential source materials, gravity data, and geographic, paleoenvironmental, and ballistic considerations support a possible impact site in the Badain Jaran part of the Alashan Desert. In further support of an impact location in China, glassy microspherules recovered from Chinese loess may be the right age to relate to the Australasian tektite event, perhaps as part of the impacting body. The most serious shortcomings of the commonly accepted Indochina impact location include signs of little chemical weathering of source materials of Australasian tektites, unlike highly weathered sedimentary targets in Indochina, and questionable assumptions about transport of distal ejecta.

ABSTRACT This thesis embraces and expands upon a century of research into disparate geological enigmas, offering a unifying catastrophic explanation for events occurring during the enigmatic mid-Pleistocene transition. Billions of tons of “Australasian tektites” were dispatched as distal ejecta from a target mass of continental sediments during a cosmic impact occurring ca. 788 ka. The accepted signatures of a hypervelocity impact encompass an excavated astrobleme and attendant proximal, medial, and distal ejecta distributions. Enigmatically, the distal tektites remain the only accepted evidence of this impact’s reality. A protracted 50 yr search fixated on impact sites in Southeast Asia—the location of the tektites—has failed to identify the requisite additional impact signatures. We postulate the missing astrobleme and proximal/medial ejecta signatures are instead located antipodal to Southeast Asia. A review of the gradualistic theories for the genesis and age of the “Carolina bay” landforms of North America finds those models incapable of addressing all the facts we observe. Research into 57,000 of those oriented basins informs our speculation that they represent cavitation-derived ovoid basins within energetically delivered geophysical mass surge flows emanating from a cosmic impact. Those flows are seen as repaving regions of North America under blankets of hydrated impact regolith. Our precisely measured Carolina bay orientations indicate an impact site within the Laurentide ice sheet. There, we invoke a grazing regime impact into hydrated early Mesozoic to late Paleozoic continental sediments, similar in composition to the expected Australasian tektites’ parent target. We observe that continental ice shielded the target at ca. 788 ka, a scenario understood to produce anomalous astroblemes. The ensuing excavation allowed the Saginaw glacial lobe’s distinctive and unique passage through the Marshall Sandstone cuesta, which encircles and elsewhere protects the central region of the intracratonic Michigan Basin. Subsequent erosion by multiple ice-age transgressions has obfuscated impact evidence, forming Michigan’s “Thumb” as an enduring event signature. Comprehensive suborbital modeling supports the distribution of distal ejecta to the Australasian tektite strewn field from Michigan’s Lower Peninsula. The mid-Pleistocene transition impact hypothesis unifies the Carolina bays with those tektites as products of an impact into the Saginaw Bay area of Lake Huron, USA. The hypothesis will be falsified if cosmogenic nuclide burial dating of Carolina bay subjacent stratigraphic contacts disallows a coeval regolith emplacement ca. 788 ka across North America. We offer observations, interdisciplinary insights, and informed speculations fitting for an embryonic concept involving a planetary-scale extraterrestrial impact.

The iron oxidation state and coordination number have been determined by Fe K-edge X-ray absorption–near edge spectroscopy (XANES) for six tektites from the North American tektite strewn field (four bediasites and two georgiaites) and a tektite fragment from the Deep Sea Drilling Project (DSDP) Site 612, which is part of the North American tektite strewn field. All tektite samples display a pre-edge peak, the components of which are consistent with the presence of divalent Fe. Comparison of pre-edge peak data (integrated intensity and centroid energy) with those of Fe model compounds allows us to quantitatively determine the Fe oxidation state and coordination number. The Fe 3+ /(Fe 2+ + Fe 3+ ) ratio is close to 0.05 (±0.03), consistent with tektites from all the other strewn fields. The average Fe coordination number is intermediate between 4 and 5. Accurate determination of this value is hindered by the scatter of pre-edge peak intensity of all the Fe model compounds; [4] Fe/( [4] Fe + [5] Fe) is estimated to be 0.26 ± 0.15. In contrast to North American microtektites, for which iron oxidation state and coordination numbers display significant variations across the North American strewn field, no significant variations in the Fe oxidation state and coordination number were found between the georgiaites, bediasites, and the DSDP 612 tektite fragment. It is remarkable that the tektite fragment from the DSDP 612 site showed no sign of oxidation despite the long burial period in marine sediments.

We studied the oxidation state of Fe in silicate glasses produced during the first atomic bomb blast at the Trinity test site (New Mexico) by X-ray absorption–near edge spectroscopy (XANES). The sample consists of green glass resulting from melting of the quartz-bearing sand present at the test site; some relict unmelted sand is still fused to the bottom of the sample. Comparison of the pre-edge peak data with model compounds of known Fe oxidation state and coordination number shows that in the Trinity glass sample, Fe is in the divalent state and, on average, in a mixture of 4- and 5-fold coordination. XANES spectra collected at various heights of the sample, from the bottom of the sample up to the exposed surface, show no variation of the pre-edge peak and, thus, of the Fe oxidation state with the distance from the sand-glass interface. However, XANES analysis of a portion of the sand at the bottom of the sample shows Fe to be a mixture of Fe 2+ and Fe 3+ , with a Fe 3+ /(Fe 2+ + Fe 3+ ) ratio close to 0.5. This demonstrates that during the nuclear explosion, the ground rock was instantaneously reduced, transforming all the iron from mostly trivalent state to almost exclusively divalent. Pre-edge peak features (intensity and energy) are consistent with those of tektites from the Ivory Coast studied here and with literature data of tektites from all the other known strewn fields (Australasian, Central European, and North American). The reduction of Fe to divalent state during Trinity glass formation, the homogeneity of the Fe oxidation state within the glass, and the Fe structural role suggest that this glass represents a good analog of tektite glass.