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NARROW
GeoRef Subject
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all geography including DSDP/ODP Sites and Legs
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Africa
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Central Africa
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Gabon
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Oklo (1)
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East Africa
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Tanzania
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Southern Africa
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ring silicates
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Primary terms
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absolute age (1)
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Africa
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Invertebrata
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Mesozoic
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Cretaceous
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Lower Cretaceous
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Upper Cretaceous
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Jurassic
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Triassic
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metal ores
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North America
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Pacific Ocean
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North Pacific
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South Pacific
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paleontology (1)
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Paleozoic
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Permian
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Podzols (1)
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In-situ and ex-situ experimental investigation on the chalcopyrite replacement in saline solution at 310–365 °C and 15–25 MPa
Viscoelastic Oil Displacement System of Modified Silica Nanoparticles/Zwitterionic Surfactant for High Salinity Reservoir
Mitigation of liquefaction triggering due to bio-gas-induced desaturation using element tests and the strain energy approach
Isotope-Geochemical Features of Apoultrabasic Metasomatites of the Sayan–Baikal Folded Area
Formation pathway of norsethite dominated by solution chemistry under ambient conditions
Nanoscale Structure and Dynamics in Geochemical Systems
Hydrothermal Properties of Geologic Fluids
Solubility of Na 2 SO 4 in silica-saturated solutions: Implications for REE mineralization
Experimental determination of the solubility constant of kurnakovite, MgB 3 O 3 (OH) 5 ·5H 2 O
The local structure of Ta(v) aqua ions in high temperature fluoride- and chloride-bearing solutions: Implications for Ta transport in granite-related postmagmatic fluids
PO 4 adsorption on the calcite surface modulates calcite formation and crystal size
Zinc transport in hydrothermal fluids: On the roles of pressure and sulfur vs. chlorine complexing
Porosity In Microbial Carbonate Reservoirs in the Middle Triassic Leikoupo Formation (Anisian Stage), Sichuan Basin, China
Microbial carbonates developed in the Middle Triassic (Leikoupo Formation, Anisian Stage) of the western Sichuan Basin. The microbial components have been identified and include Renaclis-resembling , Rivularia lissaviensis , Carpathocodium anae , Hedstroemia moldavica , Bacinellacodium calcareus , and Paraortonella getica . These form stromatolitic, laminitic, thrombolitic, spongiostromata stones, dendrolites, and oncolitic structures. Microbial carbonate reservoirs occur in submember unit (SMU) 3-3 in the Zhongba area of the northern segment and SMU 4-3 in the middle segment of the western Sichuan Basin, both of which are of low porosity and permeability. Core descriptions and thin-section analysis show that reservoir porosity is mostly microbial coelom pores, framework pores, fenestral pores, and inter- and intraclot dissolved pores, within which the pores of ≥200 μm in diameter and throat of (40~50) μm are the most important. The SMU 4-3 microbial carbonate reservoirs are more thoroughly studied because of recent exploration activities, including the identification of three reservoir intervals. The middle reservoir interval, composed of thrombolitic and stromatolitic dolostone, hosts the reservoir of best quality. However, this high-quality interval loses effective porosity and thins to the northeast. It is proposed that extreme geological conditions, dolomitization, and burial dissolution influenced the development and distribution of the microbial carbonate reservoirs. The dolomitization process is thought to be penecontemporaneous to very early postdeposition. This early dolomitization contributed significantly to porosity of the microbial carbonate reservoirs and was likely enhanced through burial dissolution.
Oil and gas reside in reservoirs within peritidal and shallow subtidal lagoonal carbonate sediments across the globe. This is a zone of facies heterogeneity, controlled by changes in depositional energy, water depth, clastic influx, and evapotranspiration. Close proximity to evaporitic brine pools means that it is also an environment with the potential for dolomitization during shallow burial. As a result, the original pore system of carbonate sediment can become drastically altered prior to burial, such that reservoir properties may not be predictable from facies models alone. The Miocene Santanyí Limestone Formation, Mallorca, Spain, is well exposed and has undergone minimal burial and therefore presents an excellent opportunity to integrate sedimentology, facies architecture, and diagenesis to determine how porosity evolves within individual facies in the shallow subsurface. From here, the impact on pore type, pore volume, pore connectivity, and petrophysical anisotropy can be assessed. The Santanyí Limestone consists of pale mudstones and wackestones, rooted wacke-packstones, stratiform laminites, and skeletal and oolitic, cross-bedded grainstone. Thin-section analysis reveals a paragenetic pathway of grain micritization, followed by dissolution of aragonite, possibly by meteoric fluids associated with karstification. Subsequently, the unit underwent fracturing, compaction, recrystallization, cementation, dolomitization, and matrix dissolution to form vugs. Petrophysical analyses of 2.54-cm-diameter plugs indicate that these complex diagenetic pathways created petrophysical anisotropy [mean horizontal permeability (Kh)/vertical permeability (Kv) of whole formation = 3.4] and that measured parameters cannot be related directly to either geological facies or pore type. Instead, petrophysical data can be grouped according to the diagenetic pathways that were followed after deposition. The best reservoir quality (i.e., typical porosity 15 to >40% and permeability >100 mD) is associated with pale mudstones, stratiform laminites, and skeletal and oolitic grainstone that have undergone pervasive recrystallization or dolomitization. These rocks have the some of the lowest formation resistivity factor (FRF) values (<200) and thus the simplest pore system. The poorest reservoir properties ( k <10 mD) occur in mudstones and wackestones that have not been recrystallized and, hence, are dominated by a simple network of micropores (FRF <101). Skeletal and oolitic grainstones and rooted and brecciated wacke-packstones that have undergone some cementation and partial recrystallization have moderate reservoir properties and a high FRF (>>1000), reflecting a complex pore system of biomolds, vugs, and microporosity. Consequently, reservoir properties can be predicted based on their primary rock properties and the diagenetic pathway that they followed after deposition.
Petrophysical characterization and understanding of pore systems and producibility in unconventional reservoirs remains challenging when evaluating reservoir potential. This study’s main objective is to identify and evaluate the controls on petrophysical rock types in unconventional low porosity, low permeability carbonate reservoirs in Mississippian-aged rocks of the southern Midcontinent. Representative samples selected from cores in the study area are calcareous siltstones and grain-rich packstones to grainstones. Rock fabric, pore types, and pore structure of 23 samples were investigated using multiscale image analysis of optical micrographs and scanning electron microscope (SEM) mosaics. Petrographic observations and quantified pore parameters were correlated with nuclear magnetic resonance (NMR) plug measurements of transverse relaxation times ( T 2 ), pore size distribution, and porosity. Results indicate that pore structure, permeability, and NMR response are closely linked to the dominant pore types, pore sizes, and mineralogy, which are distinctive for specific rocks—allowing for petrophysical rock type (PRT) grouping. NMR signature geometry is distinct in each of these rock type groups. Complex mixed mineralogies in these rocks homogenizes porosity and permeability relationships among rocks of different depositional facies, making it difficult to define clear-cut correlative relationships between pore architecture, rock fabric, and petrophysical response. Petrographic assessment indicates that the primary cause of pore-scale heterogeneity and varying petrophysical response is related to postdepositional diagenesis, such as silicification, cementation, dissolution, and mineralization along pores and pore throats, which produce complicated pore systems and affects matrix permeability. These observations confirm that incorporating geologic information such as mineralogy, diagenesis, and pore types/pore architecture into rock typing workflows in carbonate mudrock reservoirs is critical to understanding petrophysical response. Additionally, the distinct geometries in each petrophysical rock type group establishes the viability of using NMR as a rock typing tool based on the correlative relationships between NMR response, pore types, and facies.
Automated scanning electron microscopy image collection from geological polished thin sections, in conjunction with autonomous stitching, can be used to construct high-resolution (micron- to submicron-resolution) image montages over areas up to several square centimeters. The technique is here applied to an oolitic limestone and a carbonate laminite to illustrate its application as a tool to study carbonate porosity and diagenesis. Montages constructed from backscattered images are ideally suited to the extraction of data on microporosity, with possibilities including the construction of contoured maps to illustrate the spatial variation in porosity; the construction of porosity logs to illustrate trends in porosity across thin sections; and stochastic construction of digital rock models, for subsequent permeability calculation. Montages taken with a gaseous secondary electron detector in low-vacuum mode can utilize charge contrast imaging (CCI) at a variety of scales and were used here in examining the evolution of carbonate cementation. One example is oolitic limestone, illustrating the formation of grain-lining and pore-occluding cements, as well as recrystallization of the depositional fabric. CCI montages commonly suffer from a variety of contrast and brightness artifacts due to variation in charge distribution across the individual scanned image tiles. Several remedies are discussed that can reduce these artifacts, making it easier to apply image analysis techniques across such montages.