Abstract Microanalysis can provide rapid, quantitative characterization of mineral systems that complements the field- and core-scale observations traditionally made in ore deposits. We review recent innovations in microanalytical procedures and their application to studies of ore deposits. Case studies are presented examining how microanalysis can provide constraints on macroscopic processes within mineral systems. Synchrotron X-ray fluorescence shows centimetre-scale chemical variations associated with proximity to mineralization in samples from Sunrise Dam Gold Mine, Western Australia. Pseudomorphs of igneous plagioclase and chemically driven recrystallization interpreted from electron backscatter diffraction suggest that the system was dominated by fluid-driven brecciation with very little shearing. Both the fluid chemistry and fluid pressure evolved during a protracted sequence of vein formation and alteration accompanying gold mineralization. A second case study of sulphide mineralogy at the Mt Keith nickel sulphide deposit, Western Australia demonstrates how X-ray computed tomography combined with trace element mapping can constrain the chemistry and dynamics of magmatic systems. Large-scale interaction between silicate and sulphide melts, shown by homogenous palladium enrichment in pentlandite, leads to a large proportion of globular ores with a high nickel content. Increasing use of microanalysis in ore deposit geology is resulting in the constant reassessment of established models for ore genesis though a combination of micro- and macroscale datasets.

Abstract This study investigates the Late Aptian–earliest Albian platform carbonates of the Benicàssim area (Maestrat Basin, Spain) in order to assess the relationship between bed-parallel stylolites and the flow of diagenetic fluids during dolomitization and subsequent hydrothermal alteration. Dolostones and burial dolomite and calcite cements were studied by a combination of field geology and standard petrographic and isotope analysis. Field data indicate that dolostones are closely associated with seismic-scale synsedimentary faults, preferentially replace grain-dominated facies and typically show wavy dolomitizing fronts that mostly correspond to bed-parallel stylolites. The dolostones are corroded and contain bed-parallel pores that are filled with hydrothermal saddle dolomite and blocky calcite cements. This late calcite cement frequently engulfs clasts of the host dolostones, suggesting that hydraulic brecciation likely associated with overpressured fluid occurred. Results indicate that stylolites play a key role in the distribution of dolostones and subsequent hydrothermal mineralization. During the replacement stage, stylolites acted as baffles for the dolomitzing fluids controlling lateral fluid flow and resulting in the stratabound dolostone distribution. During the post-dolomitization stage, stylolites became preferred pathways for overpressured hydrothermal corrosive and mineralizing fluids that likely came from the underlying basement, and increased bed-parallel stylolitic porosity and probably also permeability.

Abstract: Salt is mechanically weaker than other sedimentary rocks in rift basins. It commonly acts as a strain localizer, and decouples supra- and sub-salt deformation. In the rift basins discussed in this paper, sub-salt faults commonly form wide and deep ramp synclines controlled by the thickness and strength of the overlying salt section, as well as by the shapes of the extensional faults, and the magnitudes and slip rates along the faults. Upon inversion of these rift basins, the inherited extensional architectures, and particularly the continuity of the salt section, significantly controls the later contractional deformation. This paper utilizes scaled sandbox models to analyse the interplay between sub-salt structures and supra-salt units during both extension and inversion. Series 1 experiments involved baseline models run using isotropic sand packs for simple and ramp-flat listric faults, as well as for simple planar and kinked planar faults. Series 2 experiments involved the same fault geometries but also included a pre-extension polymer layer to simulate salt in the stratigraphy. In these experiments, the polymer layer decoupled the extensional and contractional strains, and inhibited the upwards propagation of sub-polymer faults. In all Series 2 experiments, the extension produced a synclinal hanging-wall basin above the polymer layer as a result of polymer migration during the deformation. During inversion, the supra-polymer synclinal basin was uplifted, folded and detached above the polymer layer. Changes in thickness of the polymer layer during the inversion produced primary welds and these permitted the sub-polymer deformation to propagate upwards into the supra-salt layers. The experimental results are compared with examples from the Parentis Basin (Bay of Biscay), the Broad Fourteens Basin (southern North Sea), the Feda Graben (central North Sea) and the Cameros Basin (Iberian Range, Spain).