Abstract Radon ( 222 Rn) is a natural radioactive gas that occurs in rocks and soils and can only be detected with special equipment. Radon is a major cause of lung cancer. Therefore, early detection is essential. The British Geological Survey and Public Health England have produced a series of maps showing radon affected areas based on underlying geology and indoor radon measurements, which help to identify radon-affected buildings. Many factors influence how much radon accumulates in buildings. Remedial work can be undertaken to reduce its passage into homes and workplaces and new buildings can be built with radon preventative measures.

Abstract This volume draws together the final outputs of the five-year UNESCO / IUGS / IGCP Project 571 and presents new data on radon in the built and natural environments, radon as a diagnostic tool of geophysical phenomena, reflections and recommendations on the future of radon research and a critique of radon's asserted use as a therapy. In recent years there has been an increasing interest in radon from a range of different aspects and we would suggest that radon science has the potential to be a useful tool in understanding our environment as well as its impacts on human health.

Abstract Radon ( 222 Rn) has been highlighted by a number of authors as a significant public health concern. For example, it is the second most significant cause of lung cancer after tobacco smoking ( c. 1000–2000 and 21 000 deaths per year in the UK and USA, respectively), yet a very high proportion of the general public appears to be unaware of the risk. This chapter deals with topical radon issues, such as: radon in the workplace; radon in homes; exposure to radon during leisure activities; radon and water; measurement and monitoring; seasonal correction; remediation; cancer risks; cost–benefit analysis and cost-effectiveness; mapping; future policies; and further research. This assessment of the state of radon research is focused on the UK as an example of a country where radon has been on the governmental agenda since the late 1970s, but also highlights radon issues throughout the world in, for example, the USA, Europe and Asia.

Abstract Radon is generally regarded as a naturally occurring radiological hazard but we report here measurements of significant, hazardous radon concentrations that arise from man-made sources: for example, radium-dial watches. This study is an examination and assessment of health risks from radium and uranium found in historical artefacts, and the radon that emanates from them. This includes radium-dial watches, the main focus, plus clocks, aircraft instruments, and ornaments and artefacts made of uranium glass/uranium-glazed. Such objects were very popular in the 1930s and 1940s, and are still readily available today. A collection of 30 radium-dial pocket and wrist watches was measured and shown to be capable of giving rise to radon concentrations two orders of magnitude greater than the UK Domestic Action Level of 200 Bq m −3 in unventilated or poorly ventilated rooms. Furthermore, individual watches are capable of giving rise to radon concentrations in excess of the UK Domestic Action Level. We also highlight a gap in remediation protocols, which are focused on preventing radon entering buildings from outside, with regard to internally generated radon hazards. Radon as arising from man-made objects, such as radium-dial watches, should be considered appropriately in radon protocols and guidelines.

Abstract In 2014, the Geological Survey of Austria (GBA) published – in cooperation with further national institutions – an overview map on radionuclides in groundwater, rocks and stream sediments at a scale of 1:500 000 with explanatory notes. In the frame of this activity, the uranium, 228 Ra, 226 Ra, 222 Rn, 210 Pb and 210 Po analyses in groundwater studies made by the Austrian Agency for Health and Food Safety (AGES) and Environment Agency of Austria (Umweltbundesamt), as well as the uranium and thorium analyses of stream sediments of the GBA and whole-rock analyses from different sources, were evaluated statistically. Furthermore, the GBA’s comprehensive airborne radiometric data were exploited. The aim of this study was to work out typical spectra of the radionuclide content in the groundwater and aquifers of different geological settings. It appeared that the concentration of 222 Rn in groundwater depends significantly on the uranium content of the aquifer. In contrast to this, the other radionuclides in groundwater did not show a clear correlation with uranium and thorium in the subsurface geology. Concerning 228 Ra, 226 Ra, 210 Pb and 210 Po, the lack of relationship to the subsurface composition seems to be a result of the low concentrations in groundwater. With respect to uranium in groundwater, there is a mixed situation: on the one hand, high uranium concentrations in groundwater can be observed in the Alps in regions with uranium bearing orthogneisses. On the other hand, in sediment basins of NE Austria where the underlying geology contains little uranium. Whether this is caused by special geological features combined with the given low precipitation or by the extensive agriculture (uranium from phosphate fertilizer) is under examination. Concerning the threshold values of the radionuclides in groundwater (radiation), no exceedance could be observed. In spite of this, the concentration of the heavy metal uranium sometimes exceeded the threshold value of 15 µg l −1 : this is especially true for the regions mentioned above. In addition, an attempt was made to compare the Austrian values with data from neighbouring countries. It became clear that only a few published datasets exist that are comparable. Radon analyses of soil gas in the Czech Republic and Bavaria show the same geological patterns as the Austrian radon analyses of the groundwater. In addition, to enable the reader to compare the Austrian data with datasets from other countries, additional tables are included here for all types of data. They show the statistic distributions of different geological classes in a coordinated way. Supplementary material: An Austrian map and explanation notes showing the uranium content of the underground and radionuclides in ground water are available at https://doi.org/10.6084/m9.figshare.c.3780170

Abstract A total of 2143 dissolved radon-222 and radium-226 activity concentrations measured together in water samples was compiled from the literature. To date, the use of such a large database is the first attempt to establish a relationship for the 226 Ra– 222 Rn couple. Over the whole dataset, radon and radium concentrations range over more than nine and six orders of magnitude, respectively. Geometric means yield 9.82±0.73 Bq l −1 for radon and 54.6±2.7 mBq l −1 for radium. Only a few waters are in 226 Ra– 222 Rn radioactive equilibrium, with most of them being far from equilibrium; the geometric mean of the radium concentration in water/radon concentration in water ( C Ra / C Rn ) ratio is estimated to be 0.0056±0.0004. Significant differences in radon and radium concentrations are observed between groundwaters and surface waters, on the one hand, and between hot springs and cold springs, on the other. Within water types, typical ranges of radon and radium concentrations can be associated with subgroups of waters. While the radium concentration characterizes the geochemistry of the groundwater–rock interaction, the radon concentration, in most cases, is a signal of non-mobile radium embedded in the encasing rocks. Thus, the 226 Ra– 222 Rn couple can be a useful tool for the characterization of water and for the identification of water source rocks, shedding light on the various water–rock interaction processes taking place in the environment. Supplementary material: The database is available as a table at https://doi.org/10.6084/m9.figshare.c.3582131

Abstract Understanding the behaviour of fluids in hydrothermal systems is a key factor in volcano monitoring. Measuring gas emissions in volcanic areas is strategic for detecting and interpreting precursory signals of variations in volcanic activity. The role of radon as a potential precursor of earthquakes has been extensively debated. However, radon anomalies appear to be better suited to forecast eruptive episodes as we know the loci of volcanic eruptions and we can follow the evolution of volcanic activity. Radon mapping is an effective tool in assessing diffuse and concentrated degassing at the surface. We hereby summarize the in-soil radon emissions collected worldwide and further discuss a collection of data on our key targets. These are closed-conduit and open-conduit volcanoes: Vesuvius (Italy) and La Soufrière (Guadeloupe, Lesser Antilles), Stromboli (Italy) and Villarrica (Chile), respectively. In all the above volcanoes, faults and fracture systems control radon degassing. Automatic and real-time measurements help us to detect major changes in volcanic activity. We present and discuss the radon time series associated with the last effusive eruption at Stromboli. Spectral analyses reveal diurnal and semi-diurnal cycles being probably modulated by atmospheric variations. Multiple linear regression (MLR) analyses have been performed by filtering the radon signals from the effects of local environmental parameters. The residuals do not show particular variations or precursory peaks as the gases have been released from this open-conduit volcano before the onset of the effusive phase (7 August 2014). It is finally emphasized that radon is not the sole precursor, and we should also rely on other geochemical and geophysical parameters. In this perspective, we propose a methodological procedure that can contribute to improving volcano surveillance in an attempt to mitigate volcanic risk.

Abstract This paper presents selected issues related to the use of 222 Rn in therapeutic treatments. Radon is a radioactive element whose usage in medicine for more than 100 years is based on the radiation hormesis theory. However, owing to the radioactive character of this element and the fact that its alpha-radioactive decay is the source of other radionuclides, its therapeutic application has been raising serious doubts. The author points to potential sources and carriers of radon in the environment that could supply radon for use in a variety of therapies. Except for centuries-long tradition of using radon groundwaters, and later also the air in caves and underground workings, the author would also like to focus on soil air, which is still underestimated as a source of radon. The text presents different methods of obtaining this radioactive gas from groundwaters, the air in caves, mining galleries and soil air, and it presents new possibilities in this field. The author also discusses problems related to the transportation and storage of radon obtained from the environment. Within radon-prone areas, it is often necessary to de-radon groundwaters that are intended for human consumption and household usage. Also, dry radon wells are used to prevent radon migration from the ground into residential buildings. The author proposes using radon released from radon groundwaters and amassed in dry radon wells for radonotherapy treatments. Thanks to this, it is possible to reduce the cost of radiological protection of people within radon-prone areas while still exploiting the 222 Rn obtained for a variety of therapies. With regard to the ongoing and still unsettled dispute concerning the beneficial or detrimental impact of radon on the human organism, the author puts special emphasis on the necessity of strictly monitoring both the activity concentration of 222 Rn in media used for therapeutic treatments and of its radioactive decay products. Monitoring should be also extended to the environments in which such treatments are delivered (inhalatoriums, baths, saunas, showers, pools and other facilities), as well as to the patients – during and after the radonotherapy treatments. It is also essential to monitor the dose of radon and its daughters that is received by persons undergoing radon therapy. This should facilitate the assessment of the effectiveness of these treatments, which may contribute to a fuller understanding of the mechanisms of radon impact, and ionizing radiation in general, on the human organism. This will make it easier to ultimately confirm or reject the radiation hormesis theory. It is also essential to monitor the effective dose that is received by medical and technical staff employed to deliver the radonotherapy treatments.

Abstract Determining the timescales of magma degassing is essential for understanding the mechanisms controlling the eruption style and the dynamics of magmatic systems. Towards this end, we measured 210 Pb– 226 Ra disequilibria in andesite lavas erupted from Volcán de Colima between 1998 and 2010. ( 210 Pb/ 226 Ra) 0 activity ratios range from 0.86 to 1.09, and are best explained in terms of 222 Rn degassing and accumulation. The range in 210 Pb deficits indicates that the timescales of 222 Rn degassing did not exceed 11 years. 210 Pb excesses are rare and small (<10%), which signifies that 222 Rn degassing is more effective than 210 Pb accumulation in this intermediate system despite the relatively low gas output at the surface. The absence of significant 210 Pb excesses strongly suggests that the volcanic activity results from episodic ascent of small magma batches through the vapour-saturated section of the magmatic system. Overall, the degassing models based on 210 Pb– 226 Ra disequilibrium suggest an open and complex subvolcanic magmatic system comprising several conduits in which multiple magma batches reside for up to 10 years. Shifts from effusive to explosive Vulcanian eruptive phases are not related to changes in degassing mode on timescales resolvable using 210 Pb– 226 Ra disequilibria.