ABSTRACT Detailed diagenetic studies of the late Cambrian Alum Shale in southern Sweden were undertaken across an interval that includes the peak Steptoean Positive Carbon Isotope Excursion (SPICE) event to evaluate the pyrite mineralization history in the formation. Samples were collected from the Andrarum-3 core (Scania, Sweden); here the Alum was deposited in the distal, siliciclastic mudstone-rich end of a shelf system. Abundant cryptobioturbation is observed in the Alum, which points to oxic–dysoxic conditions prevailing during deposition. Petrographic examination of polished thin sections ( n = 65) reveals the presence of numerous texturally distinct types of pyrite, including matrix framboids, two different types of framboid concretions (those with rims of iron-dolomite and those lacking rims), disseminated euhedral pyrite crystals, concretions of euhedral pyrite crystals, overgrowths of pyrite on these different pyrite generations, anhedral pyrite intergrown with bedding parallel mineralized fractures (i.e., “beef”), and massive vertical/subvertical accumulations of pyrite. Paragenetic relationships outline the relative timing of formation of the texturally distinct pyrite. Framboids and framboid concretions formed prior to precipitation of any euhedral pyrite crystals, and these pyrite generations precipitated prior to the pyrite overgrowths on them. As Alum Shale sediments are all distorted by these texturally different pyrite generations, they are likely to have formed early in the postdepositional history of the formation. In contrast, pyrite associated with “beef” is likely temporally related to the onset of hydrocarbon generation, which in this part of Sweden is thought to have been many tens of millions of years after deposition. Because vertical/subvertical massive pyrite features distort “beef,” they clearly postdate it. Of all these pyrite textures, only framboid concretions appear to be restricted to the SPICE interval. The texturally distinct nature of the pyrite generations, along with evidence of their formation at different times in the postdepositional history of the Alum Shale, is the key outcome of this petrographic study. Because the petrographic data presented herein point to a postdeposition origin for all generations of pyrite, diagenetic processes—not those processes associated with deposition—were responsible for the complex pyritization history observed in the Alum, in the Andrarum-3 core.

Diligent reservoir characterization is the key to successful production in most unconventional plays. Unconventional resource plays require one to adapt to the scale of observation (1 nm to 1 μm) and to use special imagery techniques (e.g., scanning electron microscope [SEM], ion-milled SEM) to characterize the nature and classes of the pore system. For the Duvernay Formation, a quantitative approach to porosity typing and measurement was conducted on two- and three-dimensional focused ion beam SEM images. These images showed that between 69% and 85% of the porosity is kerogen porosity, with an average of 75% for the studied wells. It is important to recognize that although organic porosity is also developed in the less mature wells, the biggest pores were found in the most mature areas. These results indicate that there is a positive correlation between liquid yield and pore size, as well as a positive correlation between thermal maturity and pore size. The pore volume and/or the number of accessible pores increase (i.e., hydrocarbon in the pore volume and, thus, permeability) following the same trend as the mean pore size. It is concluded that the matrix porosity and, more importantly, the matrix permeability are primarily the result of thermal maturation of the kerogen. These results were not observed in previous studies due to an erroneous estimation of maturity using vitrinite reflectance, or a lack of appropriate diversity and quality of samples collected throughout the maturation phase windows to obtain statistically representative results. Subsurface data (wells, seismic), outcrop work from literature, and public domain production data from the West Shale Basin were integrated at the regional scale with this nanoscale pore-system characterization to define the hydrocarbon production potential of the Duvernay Formation.

Abstract The Marigold Au deposits are located in the Battle Mountain mining district at the northern end of Nevada’s Battle Mountain-Eureka trend. The Marigold deposits currently make up the second largest Au accumulation in the district with over 320 tonnes (10.35 Moz) of Au in oxidized rock in a N-trending series of mineralized zones approximately 7.5 km long. Ore is hosted primarily in oxidized Paleozoic siliciclastic rocks between the Roberts Mountain and Golconda thrusts. Most of the ore occurs in quartzite of the Ordovician Valmy Formation. Higher grades but lower tonnages of ore are present in the overlying Pennsylvanian-Permian Antler sequence, including the Battle Formation conglomerate, the Antler Peak Limestone, and debris flows and siltstone of the Edna Mountain Formation. Sedimentary rocks at Marigold are crosscut by a series of WNW- to N-striking quartz monzonite dikes (zircon U-Pb chemical abrasion-thermal ionization mass spectrometry ages 97.63 ± 0.05–92.22 ± 0.05 Ma) and a lamprophyre (biotite 40 Ar/ 39 Ar age 160.7 ± 0.1 Ma). Marigold displays many classic Carlin-type characteristics although the deposits are predominantly hosted in relatively unreactive, carbonate-poor siliciclastic rocks. Sulfidation, minor silicification, and possibly pyritization occurred in association with Au mineralization in quartzite and argillite. Chemically reactive but volumetrically minor carbonate rocks also display these alteration styles as well as significant decarbonatization. Argillic alteration occurred proximal to faults in mudstone and siltstone and at the margins of intrusions. Gold, As, Sb, and Tl are enriched along high-angle structures and structural intersections in the sedimentary host rocks and in faulted dike margins. Gold is present in Au-, As-, and Sb-rich pyrite overgrowths on pre-gold stage trace element-poor pyrite grains. Oxidation extends to depths of 150 to 500 m below surface, and above the redox boundary Au is present natively with iron oxides in voids and fractures. In the cores and margins of the Cretaceous dikes and fault zones, a distinct geochemical association of base metal and Ag minerals is identifiable, characterized by Ag-bearing tetrahedrite-tennantite, chalcopyrite, gersdorffite, pyrite, sphalerite, stannite, and galena. Sericite 40 Ar/ 39 Ar ages of 88.0 ± 0.46 and 79.59 ± 0.16 Ma indicate that hydrothermal alteration occurred along the dike margins at least 4 m.y. after emplacement. On the basis of similarities to other deposits in the district, the base metal and Ag mineralization may have occurred at this time. The Au mineralization occurred sometime after the base metal and Ag event, possibly in conjunction with the Eocene magmatism that occurred elsewhere in the district, although this study found no definitive evidence for a magmatic-hydrothermal origin of the Au.