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pumpellyite group
ABSTRACT The Franciscan Complex of California, the type example of an exhumed accretionary complex, records a protracted history of voluminous subduction accretion along the western margin of North America. Recent geochronological work has improved our knowledge of the timing of accretion, but the details of the accretionary history are disputed, in part, due to uncertainties in regional-scale correlations of different units. We present new detrital zircon U-Pb ages from two sites on opposite sides of San Francisco Bay in central California that confirm previously proposed correlations. Both sites are characterized by a structurally higher blueschist-facies unit (Angel Island unit) underlain by a prehnite-pumpellyite-facies unit (Alcatraz unit). The Angel Island unit yields maximum depositional ages (MDAs) ranging from 112 ± 1 Ma to 114 ± 1 Ma (±2σ), and the Alcatraz unit yields MDAs between 94 ± 2 Ma and 99 ± 1 Ma. Restoration of post-subduction dextral displacement suggests these sites were originally 44–78 km apart and much closer to other Franciscan units that are now exposed farther south in the Diablo Range. Comparison with detrital zircon dates from the Diablo Range supports correlations of the Bay Area units with certain units in the Diablo Range. In contrast, correlations with Franciscan units in the northern Coast Ranges of California are not robust: some units are clearly older than those in the Bay Area whereas others exhibit distinct differences in provenance. Integration of age data from throughout the Franciscan Complex indicates long-lived and episodic accretion from the Early Cretaceous to Paleogene. Although minor, sporadic accretion began earlier, significant accretion occurred during the interval 123–80 Ma and was followed by minor accretion at ca. 53–49 Ma. Periods of accretion and non-accretion were associated with arc magmatism in the Sierra Nevada–Klamath region, cessation of arc activity, and reorganization of paleodrainage systems, which implicates plate dynamics and sediment availability as major controls on the development of the Franciscan Complex.
Crystal chemistry of shuiskite and chromian pumpellyite-(Mg)
Crystal chemistry of julgoldite, a mineral series of the pumpellyite group: re-investigation of Fe distribution and hydrogen-bonding
Vibrational spectroscopy of epidote, pumpellyite and prehnite applied to low-grade regional metabasites
Metamorphic evolution of blueschists, greenschists, and metagreywackes in the Cretaceous Mt. Hibernia Complex (SE Jamaica)
RHENIUM DISTRIBUTION IN MOLYBDENITE FROM THE VOSNESENSK PORPHYRY Cu ± (Mo,Au) DEPOSIT (SOUTHERN URALS, RUSSIA)
Retrograde strontium metasomatism in serpentinite mélange of the Kurosegawa Zone in central Kyushu, Japan
LOW-TEMPERATURE HYDROTHERMAL METAMORPHIC MINERALIZATION OF ISLAND-ARC VOLCANICS, SOUTH APUSENI MOUNTAINS, ROMANIA
Crystal chemistry of chromian pumpellyite from Osayama, Okayama Prefecture, Japan
The hydrogen-bond system in pumpellyite
PUMPELLYITE AND COEXISTING MINERALS IN METAPELITES AND VEINS FROM THE FEDERICO UNITS IN THE INTERNAL ZONE OF THE RIF, SPAIN
Sursassite: Hydrogen bonding, cation order, and pumpellyite intergrowth
Crystal chemistry of macfallite: Relationships to sursassite and pumpellyite
Phase relations and dehydration behaviour of psammopelite and mid-ocean ridge basalt at very-low-grade to low-grade metamorphic conditions
New Mineral Names
THE DISTRIBUTION OF CHROMIUM IN CHROMIAN PUMPELLYITE FROM SARANI, URALS, RUSSIA: A TOF NEUTRON AND X-RAY RIETVELD STUDY
Pumpellyite-(Al), a new mineral from Bertrix, Belgian Ardennes
Poppiite, the V 3+ end-member of the pumpellyite group: Description and crystal structure
Early Cretaceous lawsonite eclogites and related high-pressure rocks occur as tectonic inclusions within serpentinite mélange south of the Motagua fault zone, Guatemala. Petrologic and microtextural analyses of mafic high-pressure rocks reveal three metamorphic stages linked to several deformational textures. The prograde stage represents an incipient eclogitization and is preserved in prograde garnet, along with an older S 1 –S 2 foliation. The prograde assemblage is garnet ( X Mg = ∼0.22) + omphacite (∼52 mol% jadeite) or jadeite (∼83 mol % jadeite) + lawsonite + chlorite + rutile + quartz ± phengite (3.6 Si p.f.u.); some rocks also have ilmenite and rare ferro-glaucophane. Lawsonite in garnet of some lawsonite eclogites contains rare pumpellyite inclusions. The presence of synmetamorphic brittle deformation, inclusions of pumpellyite, Fe 2+ -Mg distribution coefficients between omphacite inclusions and adjacent garnet with Ln( K D ) = 2.7–4.5, and garnet-clinopyroxene-phengite thermobarometry suggest that eclogitization initiated at temperature ( T ) = ∼300 °C and pressure ( P ) > 1.1 GPa, and continued to T = ∼480 °C and P = ∼2.6 GPa. In contrast, the retrograde eclogite-facies assemblage is characterized by reversely zoned garnet rims and omphacite ± glaucophane + lawsonite + rutile + quartz ± phengite (3.5 Si p.f.u.) along the S 3 foliation. Garnet-phengite-clinopyroxene thermobarometry yields P = ∼1.8 GPa and T = ∼400 °C. The youngest, blueschist-facies assemblage (glauco-phane + lawsonite + chlorite + titanite + quartz ± phengite) locally replaces earlier mineral assemblages along S 4 crenulations. The inferred prograde P - T trajectory lies near a geotherm of ∼5 °C km −1 , comparable to the calculated thermal and petrologic structure of the NE Japan subduction zone. These petrologic characteristics indicate: (1) the basalt-eclogite transformation may occur at T = ∼300 °C in cold subduction zones, (2) glaucophane-bearing prograde assemblages are rare during incipient eclogitization in cold subduction zones, and (3) the chlorite-consuming reactions that form Fe-Mg-Mn garnet are more effective than the lawsonite-consuming reaction that forms a grossular component. At depths of ∼100 km in cold subduction zones, dehydration embrittlement may be caused by such chlorite-consuming reactions.