This study shows examples of how fundamental relationships between pore shape, porosity, permeability, and acoustic response differ in carbonate mudrocks with micro- to picoporosity (<62 μm diameter) compared to conventional carbonates with primarily macroporosity (256-4 mm diameter). Quantitative data show that some positive correlations exist between porosity and permeability, similar to those observed in conventional carbonates. However, several expected relationships between properties, such as pore shape and laboratory-measured porosity and permeability, are not readily apparent and appear to be complicated by the internal pore architecture coupled with diagenetic alterations and a multiscale fracture network. Additionally, there is a significant shift in measured sonic velocity relative to values calculated from empirically derived equations that are applicable to conventional carbonates. Deviations from expected quantitative data trends can be partially explained through qualitative observations of the pore types and internal pore geometries. Visual observations show how diagenesis can increase the complexity of the internal pore network by nonsystematically subdividing the pores. When correlated to facies, the internal pore geometry partially clarifies deviations to expected relationships between quantitative pore architecture measurements, porosity, and permeability. Although there is an added level of complexity in the pore architecture of carbonate mudrocks, this study shows there are fundamental relationships that exist between the pore architecture, pore shape, porosity, permeability, acoustic response, facies, and sequence stratigraphic framework with variable levels of predictability that, when used as an integrated data set, can be used to enhance the predictability of key petrophysical properties within these types of reservoir systems.

The paper focuses on the Romanche transform margin on the African side of the Equatorial Atlantic, and draws from thermomechanical numerical modelling and subsequent GIS-based thermal history grid processing.Our modelling indicates that the early post-break-up thermal history of the transform margin is controlled by the cooling patterns of the adjacent pull-apart terrains, the pre-rift heat-flow regime, laterally passing seafloor spreading centres, and cooling of the newly accreted oceanic crust in two corridors located in front of and behind the spreading centres.The pre-rift thermal regime controls the background heat flow on top of which the thermal transients develop. If it is cold, the transient anomalies are very distinct on this background. If it is warm, the transient anomalies tend to blend in with background heat flow much better. The most prominent anomalies are related to thinning in the pull-apart terrains located between transforms. They are up to three times wider than anomalies related to the laterally passing spreading centre, the anomaly of which becomes no wider than 20–25 km. Together with oceanic crust accreted in corridors in front of and behind the passing centre, its heat transfer into the transform margin tends to slow down the cooling of the syn-break-up anomalies developed in the pull-apart terrains by rifting.

Residual sludge from dimension-stone working plants, both from gangue saws with abrasive shot and frame saws, is classified as waste and presents a number of problems for the stone industry. These problems include a fine size distribution, heavy metals and total petroleum hydrocarbon (TPH) content, all of which impede recovery and reuse. Residual sludge, management of which is administered in accordance with the Italian Legislative Decree 152/06, can be used in waste form for environmental restoration or for cement plants. However, it is also possible that sludge applications could go beyond these limited uses with incorporation of systematic treatment for the production of secondary raw materials (SRM), for example, filler, or for ‘new products’, for example, artificial loam. Such new products or SRM have to be certified not only on the basis of their technical and physical characteristics but also by means of appropriate chemical analyses to guarantee that the products are not contaminated.This paper outlines the results from laboratory and in situ characterization of residual sludge. In particular, three potential applications of sludge either by itself or mixed with other materials were evaluated: landfill waterproofing material, filler material for civil works and artificial soil for land rehabilitation.

Earth construction is the oldest building material known, with documented cases of the use of earth bricks since Mesopotamia around 10 000 BC. Earth construction exists throughout most of the world in different cultures, and for some countries it continues to be the main process of construction. Around 30% of the world’s population lives in buildings made from earth materials. Earthen construction is an environmentally friendly technique with a social and cultural contribution; this advantage is increased when this type of construction is applied in developing countries where the material costs counterbalance the labour costs, and where other materials and techniques are not available. Studies of material characteristics are required in order to understand the composition and specific properties of earth buildings, their heterogeneity and their degradation mechanisms. Results from two different types of adobes that represent these material characteristics in Aveiro district are shown, owing to the importance of determining and acknowledging the main characteristics of adobe buildings in order to have sufficient information to initiate conservation and rehabilitation actions.

The knowledge that societies have of their geological environment and of the materials used in their heritage is of great importance for the sustainable use and conservation of traditional natural stone architecture. Similar weathering mechanisms occur in natural environments and the built environment and, in both cases, weathering may endanger both natural and built heritage. The Sierra de Guadarrama (Spanish Central System) is a privileged area in which natural and built heritage coexist. This paper describes an area of particular monumental and geological interest on the northern slopes of the Sierra de Guadarrama; its main aim is to propose an itinerary for members of the public, presented as a route through the area around Segovia, in which architecture/cultural heritage and an Earth sciences approach are brought together with an educational purpose. To this end, some connections are established between weathering forms in natural and built environments, as well as between the lithological characteristics of the rocks used in construction of ancient monuments in the area and the distribution of stresses and loads of walls.

The Pays rémois in the eastern Paris Basin is an administrative area of 1394 km2; in the surroundings of Reims (France). Two main geological substrata are separated by the Île-de-France cuesta: the Tertiary substratum in the western part is composed of various types of geomaterials (clay, sandstone, limestone, burrstone), whereas the substratum in the eastern part is composed only of Cretaceous Chalk. A field survey in each commune of the Pays rémois identified 26 building materials documented in a Geographic Information System database (GIS-database) that includes information about them (lithology, petrographical and petrophysical data, weathering) and the corresponding buildings (e.g. town, georeferenced data, building type, position on the façade). The spatial analysis of the building materials’ distribution (Standard Deviational Ellipse) with GIS identifies their uses and the criteria established for the selection of the materials: availability, efficiency, workability and durability. Some lithologies were preferred for particular buildings or selected for their efficiency in specific positions. The study also defines the relation between the stones’ origin (local and non-local stones) and their application. This database is useful to establish stone replacement strategies in the Pays rémois.

All types of stones have been used as building stones, depending on their durability, visual harmony with the intended construction and availability. In the Hellenistic period, as in other periods, tuff was preferred as a building stone due to its convenience – it was easy to extract, transport and use for building. In the present study, three ancient quarries that were the possible tuff sources for the Apollon Smintheus Temple in Çanakkale are investigated by comparing the durability properties of stones in the temple and in the quarries. These properties are determined using physical and physico-mechanical tests, comparing fresh and artificially weathered samples. Microstructural and elemental correlations were found using optical microscopy, stereomicroscopy, X-ray diffraction, scanning electron microscopy, methylene blue adsorption and X-ray fluorescence analyses. The results indicate that temple tuffs and two of three quarries have similar geological engineering and microstructural properties with the strong claim that those two quarries could have been the source of building stone for the temple.

Natural stone was the primary building material in Cyprus in the past. Nowadays, its use is mostly confined to decorative purposes and restoration projects. This study represents the first thorough and systematic investigation of the characteristics of local carbonate stone. The variety of the results recorded highlights the complexity of this natural geomaterial and, hence, the particular attention needed before selecting the appropriate lithotype in construction practice. Stones coming from the same geological formation exhibit significant variations in their physico-mechanical properties. The materials’ durability against salt crystallization is explained with reference to their pore structure and flexural strength, revealing that, in many cases, small differences may have a significant impact on stone performance. The study also investigates the use of novel microdestructive techniques in the prediction of the mechanical properties of the stones under study. These techniques can be especially useful in the characterization of monumental stone, where sampling is limited, or when in situ characterization of stone is required.

The Netherlands, with only scarce occurrences of outcropping or shallow buried natural stone, has over centuries imported huge quantities of Early Cretaceous Bentheim Sandstone and Obernkirchen Sandstone from Germany. The present paper provides an overview of their distribution and properties relevant to their use as building stone, and their mutual differences and comparative weathering. Evidence in Dutch architecture for the onset of quarrying of the Bentheim Sandstone is presented, and an overview is given of the use of Bentheim Sandstone and Obernkirchen Sandstone in the Netherlands and Belgium.

Highly porous and soft calcarenites, often called ‘calcareous tuffs’, are commonly found throughout Southern Italy and are traditionally used as building materials. The petrophysical features of some of them were determined, focusing on the microstructure (fabric and porosimetric characteristics) and on the properties related to water absorption, drying and water vapour permeability; the compressive strength was also measured. The mineralogical composition was analysed and a variable presence of clay minerals was found for the different varieties. Diverse levels of damage under a salt crystallization test were related to the mineralogical, petrographic and porosimetric features, the latter being a source of the heterogeneity of the investigated stones. Results of laboratory tests and observations of decay in the field suggest protection against water penetration as the primary requirement for slowing down the decay of such highly porous and soft stones. Some water-repellent products were tested for effectiveness in reducing water absorption and for compatibility with the original stones’ properties. Their use in the presence of salts was taken into account, including the performances of the treated stones under the salt crystallization test. Treatment issues were found to be strongly influenced by the porosimetric characteristics of the studied materials.

Most buildings of architectural heritage in Paris and its surroundings are built with Lutetian limestone. Several historic buildings of the ‘Vexin Normand’ region show Lutetian limestone in the upper parts of their walls, while the lower parts are built with a chalk known as ‘Pierre de Vernon’. The ‘Pierre de Vernon’ appears up to the first metre, although in exceptional cases it can reach the middle height of a building. Commonly, chalks exhibit low durability due to their high porosity. However, ‘Pierre de Vernon’ is supposed to have greater durability than other chalks because of its historic use for basement construction.The objective of this research was to understand the use of the ‘Pierre de Vernon’ in the lower part of the constructions. A petrophysical characterization of Vernon chalk and Lutetian limestone was carried out, focusing mainly on the differences in porosity and water uptake. Salt crystallization tests were done to contrast their response to decay. Colour and roughness measurements and scanning electron microscope observations were performed.Results show that the different porous networks of these two limestones lead to a high contrast in their hydric properties and responses to decay, and the use of Vernon chalk in the lower sections of buildings has been found to be appropriate.

This study gives an example of the steps that a repair work must include to be successful. It deals with a specific building, repair material (lime mortar) and application (render), but also with the study of the repair mortar in the laboratory and on site. Firstly, the original materials of the wall were characterized to ensure compatibility with the new repair mortars. Secondly, the suitability of different mortar mixes, made with lime and calcareous aggregate, was assessed by characterizing their properties after 15 months. At the same time, the repair mortars were applied in testing panels, and their behaviour under environmental conditions was studied and compared with that of the laboratory mortars. Mortar properties (shrinkage, adhesion, mineralogy, microstructure and texture) developed differently according to the curing conditions. The carbonation degree was higher in mortars cured on site (especially those with higher aggregate content), although in both cases it depended on mortar porosity. Testing the type of application on site was helpful to define the best performance of the designed mixes and to choose the most suitable one among them, which was found to be the 1:6 binder-to-sand ratio mortar applied in both layers of the render.

LavaSIM is a lava -flow simulator to carry out three-dimensional (3D) analysis of solid–liquid two-phase lava flows. Heat transfer between molten lava and solidified crust into the air, water and ground is calculated using radiation equations, so we can simulate not only the lava-flow distribution but also its physical characteristics: for instance, the internal convectional structure. Lava viscosity can be treated as a function of temperature, and is associated with the percentage of crystallization. The stop condition for the lava flow is determined by calculating the minimum spreading thickness, taking into consideration the yield strength. This paper also discusses whether LavaSIM, the deterministic lava-flow simulation, can be applied to basaltic lava flows and allow lava-flow characteristics, such as inundated area, temperature distribution, crust–melt distribution, velocity and pressure field, to be quantitatively evaluated.

A new shallow-depth approximation model for lava flow advance and cooling on a quantized topography is presented in this paper. To apply the model, lava rheology is described using a non-isothermal three-dimensional viscoplastic fluid in which the rheological properties are assumed to be temperature dependent. Asymptotic analysis allows a three-dimensional flow scenario to be reduced to a two-dimensional problem using depth-averaged equations. These equations are numerically approximated by an autoadaptive finite element method, based on the Rheolef C++ library, which allows economy of computational time. Here, the proposed approach is first evaluated by comparing numerical output with non-isothermal experimental results for a flow of silicon oil. Finally, the December 2010 eruption of Piton de la Fournaise (La Réunion Island) is numerically reproduced and compared with available data.

Large-volume, high-crystallinity, chemically homogeneous ignimbrites, dubbed ‘monotonous intermediates’, provide a unique opportunity to investigate the evolution of crustal magmatic reservoirs. We present the results of hydrothermal experiments on a dacite from Fish Canyon Tuff (FCT) in Colorado (USA), a classic example of a monotonous intermediate deposit, in order to characterize the variations in chemical and physical properties of hydrous dacite magmas as a function of temperature. The experiments (200 MPa, 720–1100°C) span the inferred pre-eruptive conditions of FCT magmas, and are shown to provide the best match to the chemical and physical properties of the erupted magmas at 790±10°C under conditions at or close to water-saturation. The results show the important effect of water content in controlling the chemical and physical evolution of magma, and the contrasted behaviour of water-saturated v. water-undersaturated magmas. In both cases, however, there is a broad interval of temperature (200°C) over which crystal fraction changes little. By recasting this behaviour in terms of enthalpy, rather than temperature, as the independent variable we show that this interval corresponds to a minimum in the change in crystallinity per unit of energy added or subtracted from the system, such that small perturbations to the heat content of the system (e.g. by cooling or new magma injections) results in very little change in magma properties. The crystal content in this interval is 55–65 wt%, which is close to the phenocryst content (40–55 wt%) of monotonous intermediates. We propose that crystal-rich magmas tend to settle in this ‘petrological trap’, changing little in physical and chemical properties over time as the system grows. Petrological trapping enables very large volumes of intermediate magma to accumulate in the shallow crust until such time as the net buoyancy force of these crystal-rich magma is sufficient to overcome the strength of the roof rocks, leading to a potentially very large eruption.

The Arran Field contains gas-condensate accumulated within the Paleocene Forties Sandstone Member of the Sele Formation. It is located along the margin of the medial Forties turbidite depositional system, on the eastern flank of the Central Graben's Eastern Trough. The field comprises a low-relief southern extension (Arran South) from a high-relief northern closure (Arran North) around a salt diapir. The eastern margin of the field represents the pinch-out of the Forties Sandstone Member against the Jaeren High. As part of the field development planning, a comprehensive re-evaluation of subsurface data was undertaken. A thorough understanding of the reservoir distribution and turbidite architectures was vital to ensure that the appropriate elements were captured within the reservoir model. This was achieved through a thorough integration and multidisciplinary interpretation of all available data including seismic, core, petrophysical and analogue data. These data indicate that the best quality Forties Sandstone Member reservoir consists of stacked, elongate, amalgamated and non-amalgamated fairway sandstone bodies. These thick-bedded and sand-dominated reservoir units pass laterally into, and are extensively interbedded with, linked debrites, heterolithic low-density turbidite lobe fringe deposits, slumps, and debris flows, along with hemipelagic and turbiditic shales. A seismic shale volume (Vshale), derived from inverted pre-SDM data, together with reflection seismic data, were used to identify and map intra-reservoir depositional lobe geometries. These show large-scale, lobe-like depositional bodies which migrated laterally over time and onlapped on to the Jaeren High to the east. Within these, smaller-scale elongated lobe bodies, generally derived from the NW, are interpreted from layer-parallel extractions of the seismic Vshale volume. Possible slump units were also identified, predominantly derived from the edges of the Arran North salt diapir, suggesting that the basin floor topography was mobile during deposition. The seismic Vshale volume was used to condition the static facies model, utilizing probability relationships between the seismic data and core facies at the wells, providing a soft linkage between the data and models developed. Core, analogue data and facies interpretations from the seismic data were utilized to ensure that appropriate reservoir body geometries and spatial relationships were maintained in the static model and allowed key reservoir heterogeneities to be captured. This integrated approach also supported analysis of reservoir uncertainties, with specific focus on the vertical and lateral reservoir connectivity within this lobe-dominated reservoir.

The Fram discovery, located in the UK Central North Sea, comprises the Paleocene-aged Forties Sandstone Member with an oil rim and primary gas-cap trapped within a four-way dip closure around a pierced salt diapir. The Forties Sandstone Member reservoir at Fram is characterized by very-fine- to fine-grained sandstones interbedded with shales with post-depositional small-scale slumping and sand injection, interpreted to be the product of high-density turbidity currents and debris flows. Deposition was in an overall distal and marginal, basin-floor lobe environment. The Forties reservoir interval is considered to comprise a series of offset-stacked, turbidite lobes characterized by a systematic variation from axial amalgamated sandstone facies to more distal, marginal and thinner-bedded heterolithic sandstone facies, producing an overall sheet-like reservoir architecture. The Forties reservoir at Fram is thinner and poorer when compared with more proximal parts of the Forties submarine fan system, and reservoir quality is strongly controlled by sedimentary facies. The architecture of the reservoir is expected to result in poorer vertical, but greater lateral, stratigraphic continuity when compared with more channelized Forties reservoirs such as the Nelson and Forties fields further to the north. A key step in understanding and characterizing the Fram reservoir was the appraisal drilling in 2009, which included coring, comprehensive wireline logging, formation pressure data acquisition and a drill stem production test. This paper provides an overview of the Fram reservoir geology and demonstrates how integration of data acquired in the 2009 29/3c-8,8z appraisal wells with 3D seismic datasets, existing E&A wells and analogues has helped to improve reservoir characterization and identify the major subsurface uncertainties needing to be addressed during the field-development planning.