ABSTRACT Karst aquifers have hydrogeologic characteristics that render them uniquely vulnerable to contamination from emerging contaminants (ECs). ECs comprise numerous chemical groups, including pharmaceuticals, personal-care products, flame retardants, perfluorinated and polyfluorinated compounds, nanoparticles, and microplastics. Many ECs have sources, transport pathways, and chemical characteristics that facilitate their infiltration into groundwater, either indirectly from surface water or directly from sources such as landfill leachate and septic systems. What little is known about the occurrence, fate, and transport of ECs in the Edwards (Balcones Fault Zone) Aquifer indicates that the aquifer might be increasingly vulnerable to this type of contamination. The natural physical characteristics of this karst aquifer and anthropogenic sources of ECs associated with increased urbanization in central Texas contribute to this vulnerability. In this chapter, we review groups of ECs and their sources, occurrence of ECs in groundwater and karst, and current knowledge about the occurrence of ECs in the Edwards Aquifer. We conclude by discussing specific factors, such as rapid flow and contaminant sources, that contribute to the vulnerability of the Edwards Aquifer to contamination by ECs.

Abstract Following an adventitious oil flow into a coal mine in 1847 in the Riddings area of the county of Derbyshire in the English Midlands, the young Scottish chemist James Young carried out seminal work into the development of oil refining technology. In Derbyshire, by the end of 1848, he set up an early refinery to exploit this oil commercially by distillation, producing both lighting and lubrication fractions which he sold directly to end customers. His findings in Derbyshire led him to move on to investigate production and refining of oil from coal by destructive distillation, technology for which he gained his global reputation; Young’s patented technology was adopted by the commercial refineries that were to follow in many countries as the world’s oil fields sprang to life.

Although mineral hazards are generally not well established in the public consciousness compared to other natural hazards, they can adversely affect public health and safety and the environment. The term “mineral hazards,” as used here, includes certain naturally occurring earth materials and sites of man-made activities related to them, such as mining and oil drilling. Since the 1990s, the California Geological Survey has conducted many studies of mineral hazards in California in response to an increasing number of requests from government agencies, private industry, and the public. These studies have focused mostly on naturally occurring asbestos, radon, and various metals, such as mercury and cadmium. The mineral-hazard maps and companion reports produced from these studies are typically at statewide and regional scales. They are designed for use by nongeoscientists and geoscientists alike in an effort to educate these groups about mineral hazards and to help in mitigation of those hazards. These products indicate the likelihood of the occurrence of a mineral hazard at a given location, but not the associated health risk. Geographic information systems (GIS) are used to manage and analyze data, and to design the maps. The variety of products developed ranges from traditional paper maps to thematic digital layers for use in a GIS. This range of products increases the likelihood that a greater number of people will use the information. The maps and reports have been used in many applications, and additional applications await development as awareness of mineral hazards and the need for mitigation of them increase.